Metal organic framework-derived carbon aerogel, preparation method thereof and application in lithium ion batteries
US-12183924-B2 · Dec 31, 2024 · US
US9543568B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9543568-B2 |
| Application number | US-201313856049-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 3, 2013 |
| Priority date | May 2, 2011 |
| Publication date | Jan 10, 2017 |
| Grant date | Jan 10, 2017 |
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The present invention relates to an electrode comprising multi-layered electrode active material layer and a secondary battery comprising the same. According to the embodiments of the present invention comprises electrode having multi-layered electrode active material layer, wherein the content of the active materials which forms the electrode active material layers is equally maintained and the loading amounts at each layer are either the same or different from each other, thereby solving the problem of performance deterioration caused by an increase in battery resistance due to non-uniform dispersion of a binder or the like.
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The invention claimed is: 1. An electrode, comprising: a multi-layered electrode active material layer comprising an electrode active material, a binder, and a conductive material, wherein the electrode active material in each layer of the multi-layered electrode active material layer comprises different electrode active material components, wherein a loading amount of the electrode active material in each layer is different, wherein the loading amount of the electrode active material increases as the layers of the multi-layered electrode active material layer move in a direction away from an electrode collector, and wherein the electrode active material and binder are uniformly dispersed in each layer of the multi-layered electrode active material layer. 2. The electrode of claim 1 , wherein the electrode active material in a layer of the multi-layered electrode active material layer in contact with an electrode collector has a higher electric conductivity than the electrode active material in other layers of the multi-layered electrode active material layer. 3. The electrode of claim 1 , wherein the electrode active material in a layer of the multi-layered electrode active material layer that is a surface layer of an electrode has a higher electric conductivity than the electrode active material in other layers of the multi-layered electrode active material layer. 4. The electrode of claim 1 , wherein the electrode active material in a layer of the multi-layered electrode active material layer in contact with an electrode collector includes more amounts of the conductive material than the electrode active material in other layers of the multi-layered electrode material layer. 5. The electrode of claim 1 , wherein the electrode active material in a layer of the multi-layered electrode active material layer that is a surface layer of the electrode includes more amounts of the conductive material than the electrode active material in other layers of the multi-layered electrode material layer. 6. The electrode of claim 1 , wherein the electrode is a positive electrode. 7. The electrode of claim 6 , wherein a total loading amount of a multi-layered positive electrode active material constituting the positive electrode is 540 mg/25 cm 2 to 650 mg/25 cm 2 . 8. The electrode of claim 1 , wherein the electrode is a negative electrode. 9. The electrode of claim 8 , wherein a total loading amount of a multi-layered negative electrode active material constituting the negative electrode is 280 mg/25 cm 2 to 340 mg/25 cm 2 . 10. A lithium secondary battery comprising the electrode according to claim 1 . 11. The lithium secondary battery of claim 10 , wherein the lithium secondary battery includes a positive electrode and a negative electrode, both the positive electrode and the negative electrode comprising the electrode of claim 1 .
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