Method for manufacturing cathode active material for lithium secondary battery

Patent metadata

Field	Value
Publication number	US-9543567-B2
Application number	US-201213613889-A
Country	US
Kind code	B2
Filing date	Sep 13, 2012
Priority date	Sep 16, 2011
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

The present invention relates to a method for manufacturing cathode active material for a lithium secondary battery. The manufacturing method according to the present invention is characterized by including: (1) an intermediate generation process, wherein an intermediate which is powder or a shaped object containing the first material compound which is a compound of the transition metal other than lithium, which constitutes said lithium composite oxide, is generated, (2) a lithium source compound addition process, wherein the second material compound which is a lithium compound is added so that the second material compound in the shape of film may adhere to the surface of said intermediate, and (3) a sintering process, wherein lithium composite oxide is generated by sintering said intermediate in the state where said second material compound has adhered to its surface.

First claim

The invention claimed is:

1. A method for manufacturing a cathode active material containing a lithium composite oxide for a lithium secondary battery, comprising:
an intermediate generation process, wherein an intermediate which is a powder or a shaped object containing a first material compound which is a compound of a transition metal other than lithium, which constitutes said lithium composite oxide, is generated,
a lithium source compound addition process, wherein a second material compound which is a lithium compound is added so that the second material compound in the shape of a film adheres to a surface of said intermediate generated by said intermediate generation process, and
a sintering process, wherein the lithium composite oxide is generated by sintering said intermediate in a state where said second material compound has adhered to said surface by said lithium source compound addition process,
wherein said lithium source compound addition process is a process in which said second material compound is dispersed or dissolved in a solvent, and the solvent containing said second material compound is added to said intermediate.

2. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 1 , wherein a coverage, which is a value showing an amount of a portion that said second material compound has adhered to said surface of said intermediate, in said surface of said intermediate which passed through said lithium source compound addition process is not less than 70%.

3. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 2 ,
wherein said amount is not less than 90%.

4. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 1 , wherein said solvent containing said second material compound is sprayed on said surface of the intermediate.

5. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 1 ,
wherein anhydrous lithium hydroxide is used as said second material compound.

6. A method for manufacturing a cathode active material containing a lithium composite oxide for a lithium secondary battery, comprising:
an intermediate generation process, wherein an intermediate which is a powder or a shaped object containing a first material compound which is a compound of a transition metal other than lithium, which constitutes said lithium composite oxide, is generated,
a lithium source compound addition process, wherein a second material compound which is a lithium compound is added so that the second material compound in the shape of a film adheres to a surface of said intermediate generated by said intermediate generation process, and
a sintering process, wherein the lithium composite oxide is generated by sintering said intermediate in a state where said second material compound has adhered to said surface by said lithium source compound addition process,
wherein said intermediate generation process includes a shaping step, in which a forming material containing said first material compound is shaped in a predetermined form, and
wherein said lithium source compound addition process is a process in which said second material compound is dispersed or dissolved in a solvent, and the solvent containing said second material compound is added to said intermediate.

7. A method for manufacturing a cathode active material containing a lithium composite oxide for a lithium secondary battery, comprising:
an intermediate generation process, wherein an intermediate which is a powder or a shaped object containing a first material compound which is a compound of a transition metal other than lithium, which constitutes said lithium composite oxide, is generated,
a lithium source compound addition process, wherein a second material compound which is a lithium compound is added so that the second material compound in the shape of a film adheres to a surface of said intermediate generated by said intermediate generation process, and
a sintering process, wherein the lithium composite oxide is generated by sintering said intermediate in a state where said second material compound has adhered to said surface by said lithium source compound addition process,
wherein said intermediate generation process includes a granulation process, wherein a granulated object of said first material compound is formed,
wherein said intermediate generation process includes a shaping step, wherein said granulated objects are shaped in a predetermined form, and
wherein said lithium source compound addition process is a process in which said second material compound is dispersed or dissolved in a solvent, and the solvent containing said second material compound is added to said intermediate.

8. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 7 ,
wherein said granulation process is a process of forming said granulated object by spray drying a slurry prepared by mixing the powder of a plurality of said first material compounds while wet grinding.

9. The method for manufacturing a cathode active material for a lithium secondary battery according to claim 7 ,
wherein said intermediate generation process includes a calcination process, in which said granulated object is heat-treated.

Assignees

• Ohira Naoto
• Sugiura Ryuta
• Yokoyama Shohei
• Endo Miho
• Kimura Koji
• Nanataki Tsutomu
• Ngk Insulators Ltd

Inventors

• Ohira Naoto
• Sugiura Ryuta
• Yokoyama Shohei
• Endo Miho
• Kimura Koji
• Nanataki Tsutomu

Classifications

• H01M4/0471 Primary

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• Y02P70/54

  Cross-Sectional Technologies · mapped topic

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M10/052

  Li-accumulators · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title