Electrolyte solution, method for producing electrolyte solution, and electrochemical device

Patent metadata

Field	Value
Publication number	US-9541516-B2
Application number	US-201314034157-A
Country	US
Kind code	B2
Filing date	Sep 23, 2013
Priority date	Sep 28, 2012
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

There is provided an electrolyte solution including a solvent formed from a sulfone, and a magnesium salt dissolved in the solvent.

First claim

What is claimed is:

1. An electrolyte solution comprising:
a solvent formed from a sulfone; and
a magnesium salt dissolved in the solvent,
wherein a molar ratio of the sulfone based on the magnesium salt in the electrolyte solution is 4 or more to 35 or less.

2. The electrolyte solution according to claim 1 , wherein the electrolyte solution includes a magnesium complex having a four-coordinate dimer structure in which the sulfone is coordinated to magnesium.

3. The electrolyte solution according to claim 2 , wherein the sulfone is an alkyl sulfone or an alkyl sulfone derivative represented by R 1 R 2 SO 2 (wherein R 1 and R 2 represent an alkyl group).

4. The electrolyte solution according to claim 3 , wherein the alkyl sulfone is at least one selected from the group consisting of dimethyl sulfone, methyl ethyl sulfone, methyl-n-propyl sulfone, methyl-i-propyl sulfone, methyl-n-butyl sulfone, methyl-i-butyl sulfone, methyl-s-butyl sulfone, methyl-t-butyl sulfone, ethyl methyl sulfone, diethyl sulfone, ethyl-n-propyl sulfone, ethyl-i-propyl sulfone, ethyl-n-butyl sulfone, ethyl-i-butyl sulfone, ethyl-s-butyl sulfone, ethyl-t-butyl sulfone, di-n-propyl sulfone, di-i-propyl sulfone, n-propyl-n-butyl sulfone, n-butyl ethyl sulfone, i-butyl ethyl sulfone, s-butyl ethyl sulfone, and di-n-butyl sulfone, and the alkyl sulfone derivative is ethyl phenyl sulfone.

5. The electrolyte solution according to claim 4 , wherein the magnesium salt includes at least one selected from the group consisting of magnesium chloride, magnesium bromide, magnesium iodide, magnesium perchlorate, magnesium tetrafluoroborate, magnesium hexafluorophosphate, magnesium hexafluoroarsenate, magnesium perfluoroalkyl sulfonate, and magnesium perfluoroalkylsulfonyl imidate.

6. The electrolyte solution according to claim 5 , further comprising:
a salt formed from a cation in which a metal ion is at least one atom or group of atoms selected from the group consisting of aluminum, beryllium, boron, gallium, indium, silicon, tin, titanium, chromium, iron, cobalt, and lanthanum, or a salt formed from at least one atom, organic group, or anion selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an aryl group, a benzyl group, an amide group, a fluoride ion, a chloride ion, a bromide ion, an iodide ion, a perchlorate ion, a tetrafluoroborate ion, a hexafluorophosphate ion, a hexafluoroarsenate ion, a perfluoroalkyl sulfonate ion, and a perfluoroalkylsulfonyl imide ion.

7. A method for producing an electrolyte solution, the method comprising:
dissolving a magnesium salt in a low-boiling-point solvent capable of dissolving a magnesium salt;
dissolving a sulfone in a solution in which the magnesium salt is dissolved in the low-boiling-point solvent; and
removing the low-boiling-point solvent from the solution in which the sulfone is dissolved.

8. The method for producing an electrolyte solution according to claim 7 , wherein the low-boiling-point solvent is an alcohol.

9. An electrolyte solution comprising:
a solvent formed from a sulfone and a non-polar solvent; and
a magnesium salt dissolved in the solvent,
wherein a molar ratio of the sulfone based on the magnesium salt in the electrolyte solution is 4 or more to 20 or less.

10. The electrolyte solution according to claim 9 , wherein the non-polar solvent is a non-aqueous solvent having a permittivity and a donor number that are both 20 and less.

11. The electrolyte solution according to claim 10 , wherein the non-polar solvent is at least one selected from the group consisting of an aromatic hydrocarbon, an ether, a ketone, an ester, and a chain carbonate.

12. The electrolyte solution according to claim 11 , wherein the aromatic hydrocarbon is toluene, benzene, o-xylene, m-xylene, p-xylene, or 1-methyl naphthalene, the ether is diethyl ether or tetrahydrofuran, the ketone is 4-methyl-2-pentanone, the ester is methyl acetate or ethyl acetate, and the chain carbonate is dimethyl carbonate, diethyl carbonate, or ethyl methyl carbonate.

13. A method for producing an electrolyte solution, the method comprising:
dissolving a magnesium salt in a low-boiling-point solvent capable of dissolving a magnesium salt;
dissolving a sulfone in a solution in which the magnesium salt is dissolved in the low-boiling-point solvent;
removing the low-boiling-point solvent from the solution in which the sulfone is dissolved; and
mixing a non-polar solvent in the solution from which the low-boiling-point solvent was removed.

14. The method for producing an electrolyte solution according to claim 13 , wherein the low-boiling-point solvent is an alcohol.

15. An electrochemical device comprising:
an electrolyte solution,
wherein the electrolyte solution is
a solution including a solvent formed from a sulfone and a magnesium salt dissolved in the solvent, wherein a molar ratio of the sulfone based on the magnesium salt in the electrolyte solution is 4 or more to 35 or less, or
a solution including a solvent formed from a sulfone and a non-polar solvent, and a magnesium salt dissolved in the solvent, wherein a molar ratio of the sulfone based on the magnesium salt in the electrolyte solution is 4 or more to 20 or less.

16. The electrochemical device according to claim 15 , wherein the electrochemical device is a magnesium-using battery, capacitor, sensor, or magnesium ion filter.

17. The electrochemical device according to claim 16 , wherein the magnesium-using battery is a secondary battery, an air battery, or a fuel cell.

18. The electrochemical device according to claim 17 , wherein the secondary battery is a magnesium ion battery that has the electrolyte solution as an electrolyte layer.

Assignees

• Sony Corp

Inventors

• Nakayama Yuri
• Kawasaki Hideki
• Morioka Hiroyuki

Classifications

• H01M10/054 Primary

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01G9/035

  Liquid electrolytes, e.g. impregnating materials (H01G11/54 takes precedence) · CPC title

• H01M10/0569

  characterised by the solvents · CPC title