Resin composition, resin pellet, method for producing resin pellet, and solar cell encapsulant
US-9460829-B2 · Oct 4, 2016 · US
US9540803B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9540803-B2 |
| Application number | US-201414572387-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 16, 2014 |
| Priority date | Dec 19, 2013 |
| Publication date | Jan 10, 2017 |
| Grant date | Jan 10, 2017 |
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A coating composition of: from 4 to 17 wt % of hollow microspheres having a thermal conductivity (designated lambda) below 0.1 W·m −1 ·K −1 , from 0.05 to 1 wt % of at least one linear alcohol whose hydrocarbon chain comprises at least 8 carbon atoms, from 5 to 25 wt % of at least one bonding agent selected from water-dispersible or water-soluble polymers, comprising a glass transition temperature (Tg) less than or equal to 65° C., from 25 to 50 wt % of a non-hydraulic binder that is mineral and metallic fillers: having an average particle size in the range from 5 to 100 μm, from 0.1 to 1 wt % of at least one thickener, water, Use thereof and the applications thereof as smoothing and/or heat-insulating coating for walls and ceilings.
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The invention claimed is: 1. A coating composition comprising: from 4 to 17 wt % of hollow microspheres having a thermal conductivity (designated lambda) below 0.1 W·m −1 ·K −1 , from 0.05 to 1 wt % of at least one linear alcohol whose hydrocarbon chain comprises at least 8 carbon atoms, from 5 to 25 wt % of at least one bonding agent that is a water-dispersible or water-soluble polymer having a glass transition temperature (Tg) less than or equal to 65° C., from 25 to 50 wt % of a non-hydraulic binder that is a mineral or metallic filler which is a carbonate of an alkaline-earth metal, alumina, silica, a silicate of aluminium, a silicate of an alkali metal, a silicate of an alkaline-earth metal, or a mixture thereof, said fillers having an average particle size of 5 to 100 μm, from 0.1 to 1 wt % of at least one thickener, and water, the percentages by weight being expressed in wt % of dry matter relative to the total weight of the coating composition. 2. The coating composition according to claim 1 , wherein the hollow microspheres have a real density of 0.05 to 0.5 g/cm 3 . 3. The coating composition according to claim 1 , wherein the hollow microspheres are hollow microspheres having an average particle size (D50) of 0.10 to 100 μm. 4. The coating composition according to claim 1 , wherein the hollow microspheres are hollow glass or polymer microspheres of sodium or calcium borosilicate, of aluminosilicate, or of vinylidene chloride/acrylonitrile. 5. The coating composition according to claim 1 , wherein the alcohol is a mixture of linear fatty alcohol(s) of formula ROH, where R is a linear hydrocarbon chain, saturated or unsaturated, having from 8 to 30 carbon atoms and of vinyl polyol(s), having a Tg of 75 to 95° C. 6. The coating composition according to claim 1 , wherein the water-dispersible or water-soluble polymer is a copolymer of styrene and (meth)acrylic acid, a copolymer of styrene and ester of (meth)acrylic acid, a copolymer of styrene and (meth)acrylamide, said copolymers optionally being silanized, a homopolymer or copolymer of butadiene, a vinyl polymer a polyurethane, or a mixture thereof. 7. The coating composition according to claim 1 , wherein the mineral filler is calcium carbonate or silica. 8. The coating composition according to claim 1 , wherein the thickener is clay, a polysaccharide thickener or mixture thereof, optionally in the presence of soda. 9. A method of applying a composition as defined in claim 1 , comprising at least the following: (i) applying said composition in one or more successive layers on a surface of a substrate using a roller and/or a smoothing tool, then (ii) drying said layer, then (iii) optionally applying, on said hardened coating layer a layer of a non-insulating material. 10. The method according to claim 9 , comprising at least the following: (i′) applying a first layer of a composition on a surface of a substrate using a roller, then (ii′) applying of a second layer of a composition on said first layer deposited using a smoothing tool, the time that passes between the first and second application of the composition being less than 30 minutes, or (ii″) smoothing of the surface using a smoothing tool without adding additional material, then (iii′) drying the coating composition, then (iv′) optionally applying, on said hardened coating layer, a layer of a non-insulating material. 11. The method according to claim 9 , comprising at least the following: (i′″) applying a layer of a composition on a surface of a substrate, using a smoothing tool, then (ii′″) drying the coating composition, then (iii′″) optionally applying, on said hardened coating layer, of a layer of a non-insulating material. 12. The method according to claim 9 , wherein the roller used in (i) is a honeycomb textured foam roller. 13. A substrate covered with a hardened layer of coating composition of thickness in the range from 0.5 to 3 millimeters obtainable by the method as defined in claim 9 . 14. A process for smoothing and/or heat-insulating interior walls and ceilings, comprising achieving heat insulation or smoothing on said wall or ceiling by applying a composition according to claim 1 . 15. The coating composition according to claim 6 , wherein the copolymer of butadiene is polybutadiene or polybutadiene styrene and the vinyl polymer is polyvinyl chloride or polyvinyl acetate. 16. The method according to claim 10 , wherein the roller used in (i′) is a honeycomb textured foam roller. 17. A substrate covered with a hardened layer of coating composition of thickness in the range from 0.5 to 3 millimeters obtained by the method as defined in claim 9 . 18. An interior wall or ceiling coated with a composition according to claim 1 .
Macromolecular compounds · CPC title
obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title
Macromolecular compounds · CPC title
characterised by shape, e.g. fibres, flakes or microspheres · CPC title
Homopolymers or copolymers of acrylamide or methacrylamide · CPC title
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