Electrochemical synthesis of ammonia in alkaline media

Patent metadata

Field	Value
Publication number	US-9540737-B2
Application number	US-201414778627-A
Country	US
Kind code	B2
Filing date	Mar 26, 2014
Priority date	Mar 26, 2013
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

A method is provided for an electrochemical synthesis of ammonia in alkaline media. The method electrolytically converts N 2 and H 2 to NH 3 in an electrochemical cell comprising an anode, a cathode, and an alkaline electrolyte. The method includes exposing an anode to a H 2 -containing fluid, wherein the anode is active toward adsorption and oxidation of H 2 ; exposing a cathode to a N 2 -containing fluid, wherein the cathode is active toward adsorption and reduction of N 2 to form NH 3 ; and applying a voltage between the anode and the cathode so as to facilitate adsorption of hydrogen onto the anode and adsorption of nitrogen onto the cathode; wherein the voltage is sufficient to simultaneously oxidize the H 2 and reduce the N 2 . The electrolytic method is performed with the H 2 and N 2 pressures from about 10 atmospheres (atm) to about 1 atm; and at temperatures from about 25° C. to about 205° C.

First claim

What is claimed is:

1. A method for electrolytically converting molecular nitrogen (N 2 ) to ammonia (NH 3 ) in an electrochemical cell comprising an anode, a cathode, and an alkaline electrolyte, the method comprising:
exposing an anode comprising a first conducting component to a molecular hydrogen (H 2 ) containing fluid at a first pressure and first temperature, wherein the first conducting component is active toward adsorption and oxidation of H 2 ;
exposing a cathode comprising a second conducting component to a molecular nitrogen (N 2 ) containing fluid at a second pressure and second temperature, wherein the second conducting component is active toward adsorption and reduction of N 2 to form NH 3 ; and
applying a voltage between the anode exposed to the H 2 -containing fluid and the cathode exposed to the molecular N 2 -containing fluid so as to facilitate adsorption of hydrogen onto the anode and adsorption of nitrogen onto the cathode; wherein the voltage is sufficient to simultaneously oxidize the H 2 and reduce the N 2 ; wherein the first and second pressures are independently equal to or less than about 10 atmospheres (atm) to about 1 atm; and wherein the first and second temperatures are greater than about 25° C. and less than about 205° C.

2. A method according to claim 1 , further comprising maintaining the voltage equal or more negative than a temperature dependent thermodynamics voltage for the production of ammonia.

3. The method of claim 1 , wherein the voltage is applied as a constant voltage.

4. The method of claim 1 , wherein the first conducting component of the anode comprises a metal selected from platinum, iridium, ruthenium, palladium, rhodium, nickel, iron, or a combination thereof.

5. The method of claim 4 , wherein the first conducting component of the anode comprises a combination of the metals, which are co-deposited as alloys or deposited by layers.

6. The method of claim 1 , wherein the second conducting component of the cathode comprises a metal selected from platinum, iridium, ruthenium, palladium, rhodium, nickel, iron, copper, or a combination thereof.

7. The method of claim 6 , wherein the second conducting component of the cathode comprises a combination of the metals, which are co-deposited as alloys or deposited by layers.

8. The method of claim 1 , wherein the alkaline electrolyte has a pH equal to or greater than about 8.

9. The method of claim 1 , wherein the alkaline electrolyte comprises a hydroxide salt.

10. The method of claim 1 , wherein the alkaline electrolyte comprises an alkali metal or alkaline earth metal salt of a hydroxide.

11. The method of claim 1 , wherein the alkaline electrolyte has a hydroxide concentration from 0.1 M to about 9 M.

12. The method of claim 1 , wherein the alkaline electrolyte contains potassium hydroxide in a concentration from about 0.1 M to about 9 M.

13. The method of claim 9 , wherein the alkaline electrolyte further comprises a polymeric gel.

14. The method of claim 13 , wherein the polymeric gel comprises a polyacrylic acid.

15. The method of claim 1 , wherein the electrochemical cell further comprises a separator.

16. The method of claim 15 , wherein separator comprises an anion exchange membrane.

Assignees

• Univ Ohio

Inventors

• Botte Gerardine G

Classifications

• C25B11/04

  characterised by the material · CPC title

• C25B9/08

  Chemistry & Metallurgy · mapped topic

• C25B13/00

  Diaphragms; Spacing elements · CPC title

• C25B1/00 Primary

  Electrolytic production of inorganic compounds or non-metals · CPC title

• C25B11/091

  consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds · CPC title