Stabilized blends containing friction modifiers

Patent metadata

Field	Value
Publication number	US-9540581-B2
Application number	US-201214114616-A
Country	US
Kind code	B2
Filing date	May 21, 2012
Priority date	May 26, 2011
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

The present invention relates to functional fluid compositions containing friction modifiers, and specifically stable compositions containing friction modifiers with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and friction modifiers derived from hydroxy-carboxylic acids, where the friction modifier is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.

First claim

We claim:

1. A composition comprising:
(a) a medium comprising a solvent, a functional fluid, an additive concentrate or combinations thereof; and
(b) a friction modifier component comprising a derivative of a hydroxy-carboxylic acid, which comprises an imide, di-ester, di-amide, or ester-amide derivative of tartaric acid, citric acid, or mixtures thereof, in an amount of more than 0.5 and up to about 3 weight percent such that it is not fully soluble in the medium; and
(c) a stabilizing component that is soluble in (a) and that interacts with (b) such that (b)'s solubility in (a) is improved, said stabilizing component comprising:
about 2 to about 4 weight percent of a poly(hydroxycarboxylic acid) amide salt derivative represented by the formula [Y—CO[O-A-CO] n —Z r —R + ] m pX q− wherein Y is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group, A is a divalent hydrocarbyl group, n is from 1 to 100, m is from 1 to 4, q is from 1 to 4 and p is an integer such that pq=m, Z is a divalent bridging group which is attached to the carbonyl group through a nitrogen atom, r is 1, R + is an ammonium group and X q− is an anion; wherein the poly(hydroxycarboxyl acid) is a condensation product of 12-hydroxystearic acid, ricinoleic acid, 12-hydroxy dodecanoic acid, 5-hydroxy dodecanoic acid, 5-hydroxy decanoic acid, 4-hydroxy decanoic acid, 10-hydroxy undecanoic acid or combinations thereof and the —Z r —R + group is —NH-alkylene-N + (alkyl) 3 ;

wherein components (b) and (c), or (b) alone, are present in component (a) in the form of dispersed particles having an average diameter of less than 10 microns.

2. The composition of claim 1 wherein the turbidity of the overall composition is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

3. The composition of claim 1 wherein the friction modifier component further comprises an amide of an aliphatic carboxylic acid where the carboxylic acid comprises stearic acid, oleic acid, or combinations thereof.

4. A process of preparing a clear and stable composition comprising:
(a) a medium comprising a solvent, a functional fluid, an additive concentrate, or combinations thereof; and
(b) a friction modifier component comprising a derivative of a hydroxy-carboxylic acid which comprises an imide, di-ester, di-amide, or ester-amide derivative of tartaric acid, citric acid, or mixtures thereof, in an amount-such that it is not fully soluble in the medium; and
(c) about 2 to about 4 weight percent of a stabilizing component that is soluble in (a) and that interacts with (b) such that (b)'s solubility in (a) is improved;
said method comprising the steps of:
I. adding components (b) and (c) to component (a) wherein component (b) is present in the overall composition at a level of more than 0.5 and up to about 3 percent by weight;
II. mixing the components so that components (b) are present in component (a) in the form of dispersed particles having an average diameter of less than 10 microns; and
said stabilizing component comprising:
a poly(hydroxycarboxylic acid) amide salt derivative represented by the formula [Y—CO[O-A-CO] n —Z r —R + ] m pX q− wherein Y is hydrogen, a hydrocarbyl group or a substituted hydrocarbyl group, A is a divalent hydrocarbyl group, n is from 1 to 100, m is from 1 to 4, q is from 1 to 4 and p is an integer such that pq=m, Z is a divalent bridging group which is attached to the carbonyl group through a nitrogen atom, r is 0 or 1, R + is an ammonium group and X q− is an anion wherein the poly(hydroxycarboxyl acid) is a condensation product of 12-hydroxystearic acid, ricinoleic acid, 12-hydroxy dodecanoic acid, 5-hydroxy decanoic acid, 5-hydroxy decanoic acid, 4-hydroxy decanoic acid, 10-hydroxy undecanoic acid, or combinations thereof and the —Z r —R + group is —NH-alkylene-N + (alkyl) 3 .

5. The process of claim 4 wherein the clarity of the resulting mixture is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

6. The composition of claim 1 wherein (b), the friction modifier, comprises an alkyl tartrimide.

7. The composition of claim 1 wherein (b), the friction modifier, comprises an alkyl tartrate ester.

8. The composition of claim 1 wherein (c), the stabilizing component, comprises a poly(hydroxycarboxylic acid) amide salt derivative prepared by quaternizing the reaction product of a dialkylamino alkylamine and a polyhydroxystearic acid containing about 5 to 6 monomer units, with dimethyl sulfate.

9. The composition of claim 1 wherein (b) the friction modifier comprises oleyl tartrimide, stearyl tartrimide, 2-ethylhexyl tartrimide, an alkyl tartrate ester, or combinations thereof, and (c) the stabilizing component comprises a product of a polyricinoleic acid or a poly-12-hydroxystearic acid, such polyacid having about 5 to 6 monomer units, condensed with a diamine of the structure H 2 N—R 5 —N(CH 3 ) 2 where R 5 is an alkylene group of 2 or 3 carbon atoms, said —N(CH 3 ) 2 group being further alkylated to form a quaternary ammonium group.

Assignees

• Bartley Stuart L
• Mosier Patrick E
• Burrington James D
• Arters David C
• Lubrizol Corp

Inventors

• Bartley Stuart L
• Mosier Patrick E
• Burrington James D
• Arters David C

Classifications

• C10L10/18

  use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16 · CPC title

• C10M2203/1006

  used as base material · CPC title

• C10M2215/26

  Amines · CPC title

• C10M161/00

  Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential · CPC title

• C10M2207/128

  containing hydroxy groups; Ethers thereof · CPC title