Compositions comprising fluoroolefins and uses thereof

Patent metadata

Field	Value
Publication number	US-9540557-B2
Application number	US-201414539341-A
Country	US
Kind code	B2
Filing date	Nov 12, 2014
Priority date	Nov 1, 2005
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.

First claim

What is claimed is:

1. A process for heating said process comprising evaporating a composition comprising a refrigerant consisting of 1,1,1,4,4,4-hexafluoro-2-butene and thereafter condensing said composition in the vicinity of a body to be heated.

2. The method of claim 1 , wherein said composition further comprises a stabilizer selected from the group consisting of selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, organo phosphates, dialkylthiophosphate esters, terpenes, terpenoids, fullerenes, functionalized perfluoropolyethers, polyoxyalkylated aromatics, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, nitromethanes, alkylsilanes, benzophenone derivatives, arylsulfide, divinyl terephthalate, diphenyl terephthalate, alkylamines, hindered amine antioxidants, and phenols.

3. A method for producing heating in a heat pump apparatus, said method comprising introducing a heat transfer fluid composition into said apparatus having (a) a centrifugal compressor; (b) a multi-stage centrifugal compressor, or (c) a single slab/single pass heat exchanger; wherein said heat transfer fluid composition comprising a refrigerant consisting of 1,1,1,4,4,4-hexafluoro-2-butene.

4. The method of claim 3 wherein said method comprises compressing said refrigerant in a centrifugal compressor, condensing said composition, and thereafter evaporating said composition in the vicinity of a body to be heated.

5. The method of claim 3 , wherein said centrifugal compressor is a multi-stage centrifugal compressor.

6. The method of claim 3 , wherein said centrifugal compressor is a two-stage centrifugal compressor.

7. A method for reducing the GWP of an original refrigerant in a heat pump apparatus, wherein said original refrigerant or heat transfer fluid has a GWP of about 150 or higher; said method comprising introducing a second, lower GWP refrigerant consisting of 1,1,1,4,4,4-hexafluoro-2-butene into said heat pump apparatus.

8. The method of claim 7 further comprising removing the original refrigerant from said heat pump apparatus before the second, lower GWP refrigerant is introduced.

9. A method for replacing R11, R123, or R245fa in a heat pump apparatus comprising providing a composition comprising a refrigerant consisting of 1,1,1,4,4,4-hexafluoro-2-butene into said heat pump apparatus.

10. A heat pump apparatus containing a composition comprising a refrigerant consisting of 1,1,1,4,4,4-hexafluoro-2-butene.

11. The heat pump apparatus of claim 10 , wherein the composition further comprises a lubricant selected from the group consisting of mineral oils, paraffins, naphthenes, synthetic paraffins, alkylbenzenes, poly-alpha-olefins, polyalkylene glycols, polyvinyl ethers, polyol esters and mixtures thereof.

12. The heat pump apparatus of claim 10 , wherein the composition further comprises a stabilizer selected from the group consisting of selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, organo phosphates, dialkylthiophosphate esters, terpenes, terpenoids, fullerenes, functionalized perfluoropolyethers, polyoxyalkylated aromatics, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, nitromethanes, alkylsilanes, benzophenone derivatives, arylsulfide, divinyl terephthalate, diphenyl terephthalate, alkylamines, hindered amine antioxidants, and phenols.

Assignees

• Chemours Co Fc Llc
• Chemours Co Fc Llc

Inventors

• Nappa Mario Joseph
• Minor Barbara Haviland
• Sievert Allen Capron

Classifications

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• C09K2205/40

  Replacement mixtures · CPC title

• C09K5/04

  the change of state being from liquid to vapour or vice versa · CPC title

• F25B31/002

  Lubrication · CPC title

• F25B2400/121

  using R1234 · CPC title