Polycarbonate resin composition and molded body

Patent metadata

Field	Value
Publication number	US-9540511-B2
Application number	US-201414770629-A
Country	US
Kind code	B2
Filing date	Mar 6, 2014
Priority date	Mar 6, 2013
Publication date	Jan 10, 2017
Grant date	Jan 10, 2017

Abstract

Provided is a polycarbonate resin composition, including: 100 parts by mass of (A) a resin mixture including a specific polycarbonate-polyorganosiloxane copolymer (A-1) and a specific polycarbonate-polyorganosiloxane copolymer (A-2), the component (A) having a content of the siloxane unit in the polycarbonate-polyorganosiloxane copolymer (A-1) of 1.0 mass % to 15.0 mass % and having a content of a siloxane unit in the polycarbonate-polyorganosiloxane copolymer (A-2) of 0.1 mass % to 2.8 mass %; and 0.01 to 0.08 part by mass of (B) at least one kind selected from an alkali metal salt of an organic sulfonic acid and an alkali earth metal salt of an organic sulfonic acid.

First claim

The invention claimed is:

1. A polycarbonate resin composition, comprising:
(A) 100 parts by mass of a resin mixture comprising
(A-1) a polycarbonate-polyorganosiloxane copolymer comprising, in a main chain thereof, a repeating unit represented by formula (I) and a repeating unit represented by formula (II), wherein n=30 to 55 and a content of the repeating unit represented by the formula (II) in the copolymer (A-1) ranges from 2.5 mass % to 6.0 mass %, and
(A-2) a polycarbonate-polyoranosiloxane copolymer comprising, in a main chain thereof, a repeating unit represented by the formula (I) and a repeating unit represented by the formula (II), wherein n=80 to 120 and a content of the repeating unit represented by the formula (II) in the copolymer (A-2) ranges from 0.3 mass % to 2.1 mass %; and

(B) 0.01 to 0.08 part by mass of at least one component selected from the group consisting of an alkali metal salt of an organic sulfonic acid and an alkali earth metal salt of an organic sulfonic acid:

wherein:
R 1 and R 2 each independently represent a halogen atom, an alkyl group comprising 1 to 6 carbon atoms, or an alkoxy group comprising 1 to 6 carbon atoms,
X represents a single bond, an alkylidene group comprising 1 to 8 carbon atoms, an alkylidene group comprising 2 to 8 carbon atoms, a cycloalkylene group comprising 5 to 15 carbon atoms, a cycloalkylidene group comprising 5 to 15 carbon atoms, a fluorenediyl group, an arylalkyl group comprising 7 to 15 carbon atoms, an arylalkylidene group comprising 7 to 15 carbon atoms, —S—, —SO—, —SO 2 —, —O—, or —CO—,
a and b each independently represent an integer of 0 to 4; and
R 3 and R 4 each independently represent a hydrogen atom, a halogen atom, an alkyl group comprising 1 to 6 carbon atoms, an alkoxy group comprising 1 to 6 carbon atoms, or an aryl group comprising 6 to 12 carbon atoms, and
n represents an average number of repetitions.

2. The polycarbonate resin composition according to claim 1 , wherein the component (B) comprises at least one component selected from the group consisting of an alkali metal salt of a perfluoroalkanesulfonic acid and an alkali earth metal salt of a perfluoroalkanesulfonic acid.

3. The polycarbonate resin composition according to claim 1 , wherein a molded body of the polycarbonate resin composition having a thickness of 3 mm has a total light transmittance measured based on ISO 13468 of 85% or more.

4. The polycarbonate resin composition according to claim 1 , wherein a molded body of the polycarbonate resin composition having a thickness of 2 mm is evaluated as V-0 by a UL94 flame test.

5. The polycarbonate resin composition according to claim 1 , wherein the polycarbonate resin composition is free of a bromine-based flame retardant.

6. A molded body, obtained by a process comprising molding the polycarbonate resin composition of claim 1 .

7. The polycarbonate resin composition according to claim 1 , wherein the amount of (A-1) ranges from 40 to 95 pads by mass and the amount of (A-2) as being 5 to 60 parts by mass.

8. The polycarbonate resin compositing according to claim 1 , wherein the amount of (A-1) ranges from 45 to 93 parts by mass and the amount of (A-2) as being 5 to 60 parts by mass.

9. The polycarbonate resin compositing according to claim 1 , wherein the amount of (A-1) ranges from 50 to 91 parts by mass and the amount of (A-2) as being 5 to 60 parts by mass.

10. The polycarbonate resin composition according to claim 1 , wherein the amount of (A-1) ranges from 60 to 95 parts by mass and the amount of (A-2) as being 5 to 60 parts by mass.

11. The polycarbonate resin composition according to claim 1 , wherein the amount of (A-1) ranges from 66 to 93 parts by mass and the amount of (A-2) as being 7 to 34 parts by mass.

12. The polycarbonate resin composition according to claim 1 , wherein the amount of (A-1) ranges from 66 to 91 parts by mass and the amount of (A-2) as being 9 to 34 parts by mass.

Assignees

• Idemitsu Kosan Co

Inventors

• Aoki Yusuke

Classifications

• C08K5/42 Primary

  Sulfonic acids; Derivatives thereof · CPC title

• C08L85/00

  Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers · CPC title

• C08L83/06 Primary

  containing silicon bound to oxygen-containing groups (C08L83/12 takes precedence) · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L83/10

  Block- or graft-copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00) · CPC title