Non-carbon mixed-metal oxide electrocatalysts

Patent metadata

Field	Value
Publication number	US-9537155-B2
Application number	US-201514973882-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Jan 31, 2014
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

Electrocatalysts having non-corrosive, non-carbon support particles are provided as well as the method of making the electrocatalysts and the non-corrosive, non-carbon support particles. Embodiments of the non-corrosive, non-carbon support particle consists essentially of titanium dioxide and ruthenium dioxide. The electrocatalyst can be used in fuel cells, for example.

First claim

What is claimed is:

1. A method of preparing an electrocatalyst comprising: preparing non-carbon composite support particles comprising:
dispersing titanium dioxide particles in liquid and mixing;
depositing ruthenium nanoparticles onto the titanium dioxide particles in the liquid using a ruthenium precursor, wherein each of the titanium dioxide particles has a first particle size and each of the ruthenium nanoparticles have a second particle size, the first particle size being greater than the second particle size, wherein the first particle size is greater than 10 and less than or equal to 40 nanometers and the second particle size is greater or equal to 5 and less than 10 nanometers;
agglomerating ruthenium nanoparticles to produce agglomerated ruthenium particles with a particle size that is the same as the first particle size deposited onto the titanium dioxide particles, wherein the agglomerated ruthenium particles are discrete particles; and
oxidizing the agglomerated ruthenium particles to obtain ruthenium dioxide particles; and
depositing active catalyst particles directly on each of the titanium dioxide particles and the ruthenium dioxide particles.

2. The method of claim 1 , wherein the active catalyst particles are a platinum alloy.

3. The method of claim 1 , wherein the active catalyst particles are a multi-layer core shell.

4. The method of claim 1 , wherein the active catalyst particles are platinum nanoparticles, each of the platinum nanoparticles having a diameter between 3 nm and 6 nm.

5. The method of claim 1 , further comprising:
prior to depositing the active catalyst particles, modifying a surface of the titanium dioxide particles and the ruthenium dioxide particles with a chemical process configured to promote adhesion of the active catalyst particles.

6. The method of claim 1 , wherein the titanium dioxide particles are is a modified titanium dioxide particles, the method further comprising, prior to dispersing the titanium dioxide particles:
mixing a dopant with a titanium dioxide precursor; and
reacting the mixture to form the modified titanium dioxide particles.

7. The method of claim 6 , wherein the dopant is one of both of niobium and tantalum.

Assignees

• Nissan North America Inc

Inventors

• Dale Nilesh
• Niangar Ellazar
• Han Taehee
• Huang Kan
• Dileo Gregory

Classifications

• H01M4/9075

  Catalytic material supported on carriers, e.g. powder carriers (H01M4/8807, H01M4/881, H01M4/8814, H01M4/925 take precedence) · CPC title

• H01M4/925

  supported on carriers, e.g. powder carriers · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/9016

  Oxides, hydroxides or oxygenated metallic salts · CPC title

• H01M4/8657

  layered · CPC title