Ion chromatograph

Patent metadata

Field	Value
Publication number	US-9535034-B2
Application number	US-201214363027-A
Country	US
Kind code	B2
Filing date	Oct 15, 2012
Priority date	Dec 16, 2011
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A suppressor is structured by an ion exchange section being structured by an eluate path forming member forming an eluate path and a regenerant path forming member forming a regenerant path being stacked across an ion exchange film, and a heat-conductive heat block covering the outside of the ion exchange section. A separation column, the suppressor, and an electrical conductivity meter are accommodated in a common constant temperature bath. The inside of the constant temperature bath is feedback-controlled by a temperature control section so as to be maintained at constant temperature.

First claim

The invention claimed is:

1. An ion chromatograph comprising:
a separation path including a separation column for performing separation of an ion component in a sample;
a measurement path including an electrical conductivity meter for measuring electrical conductivity; and
a suppressor including an eluate path, connecting between the separation path and the measurement path, for passing an eluate from the separation column, a regenerant path, arranged facing the eluate path, for passing a regenerant, and an ion exchange film, interposed between the eluate path and the regenerant path, for causing ion exchange to be performed between the paths, the suppressor being for suppressing background electrical conductivity of the eluate from the separation column,
wherein the suppressor is structured by an ion exchange section structured by an eluate path forming member forming the eluate path, the ion exchange film, and a regenerant path forming member forming the regenerant path being stacked with one another, and a heat-conductive heat block covering the ion exchange section,
wherein the electrical conductivity meter and the suppressor are accommodated in a common constant temperature bath, and
wherein the ion chromatograph further comprising a suppressor temperature adjustment mechanism, having a heater to heat the suppressor, attached to the suppressor and accommodated in the common constant temperature bath, for adjusting temperature of the suppressor to constant temperature same as temperature in the constant temperature bath.

2. The ion chromatograph according to claim 1 , wherein a thickness of the ion exchange section in a stacking direction is 2 mm or less.

3. The ion chromatograph according to claim 1 , wherein the eluate path forming member and the regenerant path forming member are formed of polyether ether ketone resin, and the temperature in the constant temperature bath is controlled to constant temperature of 40° C. or higher and 100° C. or lower.

4. The ion chromatograph according to claim 1 , wherein the electrical conductivity meter is provided integrally with the heat block.

5. The ion chromatograph according to claim 1 , wherein the eluate path and the regenerant path are each 500 μm or less in width, 100 μm or less in depth, and 3000 mm or less in length.

6. The ion chromatograph according to claim 1 , wherein the constant temperature bath is adhered to, and covers, outer surface of the heat block.

Assignees

• Shimadzu Corp

Inventors

• Sakamoto Katsumasa
• Oikawa Yukio
• Horiike Shigeyoshi

Classifications

• G01N27/62 Primary

  by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode · CPC title

• G01N2030/965

  suppressor columns · CPC title

• G01N30/96 Primary

  using ion-exchange (G01N30/02, G01N30/90 take precedence) · CPC title

• G01N2030/645

  electrical conductivity detectors · CPC title

• G01N2030/3038

  temperature control of column exit, e.g. of restrictors · CPC title