Hydrocracking process with feed/bottoms treatment

Patent metadata

Field	Value
Publication number	US-9534179-B2
Application number	US-201414469905-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Jan 24, 2011
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A hydrocracking process is provided for treating a first heavy hydrocarbon feedstream and a second heavy hydrocarbon feedstream, in which the first heavy hydrocarbon feedstream contains undesired nitrogen-containing compounds, sulfur-containing compounds and poly-nuclear aromatic compounds. The first heavy hydrocarbon feedstream is contacted with adsorbent material to produce a treated heavy hydrocarbon stream. The second heavy hydrocarbon feedstream is combined with the treated heavy hydrocarbon stream, and this combined stream is charged to a hydrocracking reaction unit. The hydrocracked effluent is fractioned to recover hydrocracked products and a bottoms stream containing heavy poly-nuclear aromatic compounds. Fractionator bottoms are also contacted with adsorbent material to produce an adsorbent-treated fractionator bottoms stream having a reduced content of heavy poly-nuclear aromatic compounds, and are recycled to the hydrocracking reaction unit.

First claim

I claim:

1. A hydrocracking process for treating a first heavy hydrocarbon feedstream and a second heavy hydrocarbon feedstream, the first heavy hydrocarbon feedstream contains undesired nitrogen-containing compounds and poly-nuclear aromatic compounds, the process comprising:
a. contacting the first heavy hydrocarbon feedstream and elution solvent with an effective amount of adsorbent material to produce an effluent comprising solvent and an adsorbent-treated heavy hydrocarbon stream having a reduced content of nitrogen-containing and poly-nuclear aromatic compounds, and recovering solvent from the effluent;
b. combining the second heavy hydrocarbon feedstream with the adsorbent-treated heavy hydrocarbon stream;
c. introducing the combined stream and an effective amount of hydrogen into a hydrocracking reaction unit that contains an effective amount of hydrocracking catalyst to produce a hydrocracked effluent stream;
d. fractionating the remainder of the hydrocracked effluent stream to recover hydrocracked products and a bottoms stream containing heavy poly-nuclear aromatic compounds;
e. contacting the fractionator bottoms stream with an effective amount of adsorbent material to produce an adsorbent-treated fractionator bottoms stream having a reduced content of heavy poly-nuclear aromatic compounds;
f. integrating the adsorbent-treated fractionator bottoms stream with the combined stream of steps (b); and
g. introducing the combined stream into the hydrocracking reaction unit.

2. The process of claim 1 , further comprising removing any excess hydrogen from the hydrocracked effluent stream and recycling it back to the hydrocracking reaction zone.

3. The process of claim 1 , wherein the adsorbent material in step (a) is the same as the adsorbent material in step (e), which are both maintained in an adsorption zone.

4. The process of claim 3 , wherein the fractionator bottoms and the first liquid hydrocarbon feedstream are combined upstream of the adsorption zone.

5. The process of claim 1 , wherein the adsorbent material in step (a) is different from the adsorbent material in step (e), which are maintained in separate adsorption zones.

6. The process of claim 1 , wherein the first heavy hydrocarbon feedstream is selected from the group consisting of de-metalized oil, de-asphalted oil, coker gas oils, heavy cycle oils, and visbroken oils.

7. The process of claim 1 , wherein the second heavy hydrocarbon feedstream is vacuum gas oil.

8. The process of claim 1 , wherein the adsorbent material in step (a), step (e) or both steps (a) and (e) is packed into the at least one fixed bed column and is in the form of pellets, spheres, extrudates or natural shapes and the size is in the range of 4 mesh to 60 mesh.

9. The process of claim 1 , wherein the adsorbent material in step (a), step (e) or both steps (a) and (e) is selected from the group consisting of attapulgus clay, alumina, silica gel, activated carbon, fresh catalyst and spent catalyst.

10. The process of claim 4 which further comprise:
h. passing the fractionator bottoms and the first liquid hydrocarbon feedstream through a first of two packed columns;
i. transferring the fractionator bottoms and the first liquid hydrocarbon feedstream from the first column to the second column while discontinuing passage through the first column;
j. desorbing and removing nitrogen-containing compounds, poly-nuclear aromatic compounds and heavy poly-nuclear aromatic compounds from the adsorbent material in the first column to thereby regenerate the adsorbent material;
j. transferring the fractionator bottoms and the first liquid hydrocarbon feedstream from the second column to the first column while discontinuing the flow through the second column;
l. desorbing and removing nitrogen-containing compounds, poly-nuclear aromatic compounds and heavy poly-nuclear aromatic compounds from the adsorbent material in the second column to thereby regenerate the adsorbent material; and
m. repeating steps (h)-(l), whereby the processing of the fractionator bottoms and the first liquid hydrocarbon feedstream is continuous.

11. The process of claim 5 which further comprises:
h. passing the first liquid hydrocarbon feedstream through a first of two packed columns;
i. transferring the first liquid hydrocarbon feedstream from the first column to the second column while discontinuing passage through the first column;
j. desorbing and removing nitrogen-containing compounds and poly-nuclear aromatic compounds from the adsorbent material in the first column to thereby regenerate the adsorbent material;
k. transferring the first liquid hydrocarbon feedstream from the second column to the first column while discontinuing the flow through the second column;
l. desorbing and removing nitrogen-containing compounds and poly-nuclear aromatic compounds from the adsorbent material in the second column to thereby regenerate the adsorbent material; and
m. repeating steps (h)-(l), whereby the processing of the first liquid hydrocarbon feedstream is continuous.

12. The process of claim 5 which further comprises:
h. passing the fractionator bottoms through a first of two packed columns;
i. transferring the fractionator bottoms from the first column to the second column while discontinuing passage through the first column;
j. desorbing and removing heavy poly-nuclear aromatic compounds from the adsorbent material in the first column to thereby regenerate the adsorbent material;
k. transferring the fractionator bottoms from the second column to the first column while discontinuing the flow through the second column;
l. desorbing and removing heavy poly-nuclear aromatic compounds from the adsorbent material in the second column to thereby regenerate the adsorbent material; and
m. repeating steps (h)-(l), whereby the processing of the fractionator bottoms is continuous.

13. The process of claim 1 , further in which the first heavy hydrocarbon feedstream is mixed with solvent prior to contacting in step (a).

14. The process of claim 1 , further in which the fractionator bottoms stream is mixed with solvent prior to contacting in step (e).

15. The process of claim 4 , further in which the combined fractionator bottoms and the first liquid hydrocarbon feedstream is mixed with the elution solvent prior to contacting with adsorbent material.

16. The process of claim 1 , further comprising removing a portion of the fractionator bottoms stream as a bleed stream, and contacting the remainder of the fractionator bottoms stream as in step (e).

17. The process of claim 1 , wherein the elution solvent comprises naphtha.

18. The process of claim 1 , wherein the elution solvent comprises naphtha derived from hydrocracked products recovered in step (d).

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa

Classifications

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G67/14 Primary

  including at least two different refining steps in the absence of hydrogen · CPC title

• C10G2300/701

  Use of spent catalysts · CPC title

• C10G2300/44

  Solvents · CPC title

• C10G2300/4081

  Recycling aspects · CPC title