Polyglycolic acid resin short fibers for use in well treatment fluid

Patent metadata

Field	Value
Publication number	US-9534163-B2
Application number	US-201314386624-A
Country	US
Kind code	B2
Filing date	Apr 22, 2013
Priority date	Apr 27, 2012
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

Polyglycolic acid resin short fibers for a well treatment fluid, the fibers having the following characteristics of (a) to (e): (a) an outside diameter of 5 to 300 μm; (b) a fiber length of 1 to 30 mm; (c) fineness of 0.1 to 25 D; (d) strength of 1 to 20 gf/D; and (e) a ratio of an area of the polyglycolic acid resin with respect to an area of a circle circumscribing a cross section of the fibers being from 10 to 95%; and a well treatment fluid containing the polyglycolic acid resin short fibers for a well treatment fluid.

First claim

The invention claimed is:

1. Polyglycolic acid resin short fibers for a well treatment fluid, the fibers having the following characteristics of (a) to (e):
(a) an outside diameter of 5 to 300 μm;
(b) a fiber length of 1 to 30 mm;
(c) fineness of 0.1 to 25 D;
(d) strength of 1 to 20 gf/D; and
(e) a ratio of an area of the polyglycolic acid resin with respect to an area of a circle circumscribing a cross section of the fibers being from 10 to 95%.

2. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 1 , wherein the polyglycolic acid resin have at least 50 mass % of glycolic acid repeating units.

3. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 1 , wherein the polyglycolic acid resin short fibers formed from a polyglycolic acid resin having (i) a weight average molecular weight (Mw) of 10,000 to 800,000, (ii) a melt viscosity (measured at a temperature of 240° C. and a shear rate of 122 sec −1 ) of 20 to 5,000 Pa·s, and (iii) a terminal carboxyl group concentration of 0.05 to 300 eq/10 6 g.

4. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 1 comprising: from 50 to 100 mass % of a polyglycolic acid resin, and from 0 to 50 mass % of a resin other than a polyglycolic acid resin having water degradability, biodegradability, or both water degradability and biodegradability.

5. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 1 , wherein the polyglycolic acid resin short fibers are at least one type selected from the group consisting of heteromorphic cross section short fibers, porous short fibers, hollow short fibers, and composite short fibers.

6. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 5 , wherein a cross section of the heteromorphic cross section short fibers is star-shaped, four-leaf clover-shaped, three-leaf clover-shaped, elliptical, or polygonal.

7. The polyglycolic acid resin short fibers for a well treatment fluid according to claim 1 obtained by crimping.

8. A well treatment fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 .

9. The well treatment fluid according to claim 8 comprising the polyglycolic acid resin short fibers for a well treatment fluid at a concentration of 0.05 to 100 g/L.

10. The well treatment fluid according to claim 8 , wherein the well treatment fluid is at least one type selected from the group consisting of a drilling fluid, a fracturing fluid, a cementing fluid, a temporary plug fluid, and a completion fluid.

11. A drilling fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 and having a function of preventing lost circulation.

12. A drilling fluid which is a well treatment fluid having the function of preventing lost circulation described in claim 11 , the drilling fluid having a function of preventing lost circulation for preventing infiltration of the drilling fluid into subterranean formation for at least 3 hours in a well at a temperature less than 150° C.

13. A drilling fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , and a self-collapsing cake layer.

14. A well treatment fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , wherein the polyglycolic acid resin short fibers degrade and gradually release an acidic substance inside a well.

15. The well treatment fluid according to claim 14 , wherein the well treatment fluid has a function to reduce a fluid viscosity prior to degradation by at least 10% by degrading the polyglycolic acid resin short fibers in the well and gradually releasing an acidic substance so as to change a pH of the fluid to 1 to 5.

16. The well treatment fluid according to claim 14 , wherein the well treatment fluid is at least one type selected from the group consisting of a drilling fluid, a fracturing fluid, a cementing fluid, a temporary plug fluid, and a completion fluid.

17. A fracturing fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , the fracturing fluid having a function to suppress the settleability of a proppant by forming a network structure between the polyglycolic acid resin short fibers and the proppant.

18. The fracturing fluid according to claim 17 in which the settleability of a proppant is suppressed, wherein the polyglycolic acid resin short fibers for a well treatment fluid and the proppant are mixed and stirred, and, when 1 hour has passed after being left to stand in a supply tank, at least part of the proppant is present at a height of at least half the height of the supply tank liquid surface.

19. The fracturing fluid according to claim 17 , wherein the polyglycolic acid resin short fibers for a well treatment fluid degrade by the time of production of petroleum or gas so as to avoid decreasing flow paths inside fractures.

20. A temporary plug fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , wherein the temporary plug fluid temporarily plugs naturally-existing fractures and created bore holes, and the polyglycolic acid resin short fibers for a well treatment fluid degrade and collapse by the time of production of petroleum or gas so as to avoid decreasing recovery efficiency of a product.

21. A temporary plug fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , wherein the temporary plug fluid prevents a fluid from preferentially flowing into subterranean formation of high permeability having naturally-existing fractures and temporarily plugs the subterranean formation of high permeability in order to make the fluid flow uniform.

22. The temporary plug fluid according to claim 21 comprising at least one type selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, and fluorine acid.

23. A cementing fluid comprising the polyglycolic acid resin short fibers for a well treatment fluid described in claim 1 , wherein at least some of the polyglycolic acid resin short fibers degrade after a certain amount of time has passed so as to facilitate removal of cement.

Assignees

• Kureha Corp

Inventors

• Abe Shunsuke
• Yamazaki Masahiro
• Takahashi Takeo
• Sato Hiroyuki
• Suzuki Kenichi

Classifications

• C09K8/905

  Biopolymers · CPC title

• C09K8/68

  containing organic compounds · CPC title

• C09K8/885

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• D01D5/253

  with a non-circular cross section; Spinnerette packs therefor (D01D5/38 takes precedence) · CPC title

• C09K8/487

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title