Non-hazardous water-based polyurethane dispersion
US-12110373-B2 · Oct 8, 2024 · US
US9534143B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9534143-B2 |
| Application number | US-201214353948-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 25, 2012 |
| Priority date | Oct 25, 2011 |
| Publication date | Jan 3, 2017 |
| Grant date | Jan 3, 2017 |
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Provided is a resin composition for an under coat of an UV coating layer and a coated steel sheet using the resin composition. The coated steel sheet comprises a material steel sheet; an under coat layer including a cured product of a resin composition for the under coat layer which contains a main resin and a metal powder, the under coat layer being formed on one side or both sides of the material steel sheet; and a top coat layer formed on the under coat layer and containing a radical compound, thereby providing a superior appearance, scratch resistance, corrosion resistance and superior weldability.
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The invention claimed is: 1. A coated steel sheet comprising: a material steel sheet; an under coat layer including a cured product of a resin composition for the under coat layer which contains a main resin and a metal powder and which satisfies a condition of the following formula 1, the under coat layer being formed on one side or both sides of the material steel sheet; and a top coat layer formed on the under coat layer and containing a radical compound: Tb/ 3≦ D 1 [Formula 1] wherein D1 means an average particle size of a major axis of the metal powder, and Tb means a thickness of the under coat layer formed by the cured product of the resin composition for the under coat layer, wherein the main resin is contained in a range of 20 volume parts to 90 volume parts on the basis of 100 volume parts of a solid content of the resin composition for the under coat layer, wherein the metal powder is contained in a range of 1 volume part to 30 volume parts on the basis of 100 volume parts of a solid content of the resin composition for the under coat layer, wherein the thickness of the under coat layer is 1 μm to 10 μm, wherein the top coat layer comprises a cured product of a UV curing paint composition containing an oligomer, a photo-polymerizable monomer, and a photo-initiator, wherein the UV curing paint composition contains 30 weight parts to 70 weight parts of the oligomer, 30 weight parts to 70 weight parts of the photo-polymerizable monomer, and 0.1 weight parts to 30 weight parts of the photo-initiator on the basis of 100 weight parts of the UV curing paint composition, and wherein a thickness of the top coat layer is 1 μm to 20 μm. 2. The coated steel sheet according to claim 1 , wherein the main resin is at least one selected from the group consisting of polyurethane resin, epoxy resin, phenoxy resin, ester resin, acrylic resin and olefin resin. 3. The coated steel sheet according to claim 1 , wherein the oligomer is at least one selected from the group consisting of urethane acrylate, epoxy acrylate and polyester acrylate. 4. The coated steel sheet according to claim 1 , wherein the photo-polymerizable monomer is monofunctional or multifunctional acrylate-based monomer. 5. The coated steel sheet according to claim 1 , wherein the photo-initiator is at least one selected from the group consisting of benzophenone-based compound, benzoin-based compound, benzoinether-based compound, benzyl ketal-based compound, acetophenone-based compound, antraquinone-based compound and thioxanthone-based compound. 6. The coated steel sheet according to claim 1 , wherein the UV curing paint composition further comprises 0.1 weight parts to 15 weight parts of an additive on the basis of 100 weight parts of the UV curing paint composition. 7. The coated steel sheet according to claim 6 , wherein the additive is at least one selected from the group consisting of antifoaming agent, leveling agent, adhesion promoter, antioxidant, photostabilizer, UV absorber, thermal polymerization prohibitor, lubricating agent, dispersing agent, anti-static agent, plasticizer, organic filler and mixture thereof. 8. The coated steel sheet according to claim 1 , wherein the coated steel sheet is used as a construction material.
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