Method for fabricating ceramic material

Patent metadata

Field	Value
Publication number	US-9533918-B2
Application number	US-201113250084-A
Country	US
Kind code	B2
Filing date	Sep 30, 2011
Priority date	Sep 30, 2011
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A method for a fabricating a ceramic material includes providing a mixture of a reactive metallic filler material with a preceramic polysilazane material. The preceramic polysilazane material is then polymerized to form a green body. The green body is then thermally treated in an environment that is substantially free of oxygen to convert the polymerized preceramic polysilazane material into a ceramic material that includes at least one nitride phase that is a reaction product of the reactive metallic filler material and a preceramic polysilazane material.

First claim

What is claimed is:

1. A method for fabricating a ceramic material, the method comprising:
proving a mixture of a reactive filler with a preceramic polysilazanes material, wherein the reactive filler is selected from the group consisting of aluminum filler metal powder, titanium filler metal powder and combinations thereof; and wherein the mixture has an amount of up to 40 weight percent of reactive filler;
infiltrating the mixture into pores of a fibrous structure that has coated fibers, wherein the coating on the coated fibers has an coating thickness, represented as a variable t coating (nanometers) and the mixture has an amount, represented by a variable X (weight percent), of the reactive filler, and wherein X and t coating are selected such that a ratio of t coating /X (coating thickness in nanometers divided by weight percent of the reactive filler) is from 3.75 to 25;
polymerizing the preceramic polysilazanes material to form a green body; and thermally treating the green body in an environment that is substantially free of oxygen to convert the polymerized preceramic polysilazane material into a ceramic material including at least one nitride phase that is a reaction product of the reactive filler and the preceramic polysilazane material.

2. The method as recited in claim 1 , wherein the nitride phase includes aluminum nitride if the reactive filler includes the aluminum filler metal powder, and the nitride phase includes titanium nitride if the reactive filler includes the titanium filler metal powder.

3. The method as recited in claim 2 , wherein the thermal treating of the green body reacts the reactive filler with the preceramic polysilazane material to produce free silicon metal.

4. The method as recited in claim 1 , including infiltrating the mixture into pores of a fibrous structure.

5. The method as recited in claim 1 , including polymerizing the preceramic polysilazane material at a first temperature, and thermally treating the green body at a second, higher temperature.

6. The method recited in claim 1 , wherein the amount is 10-30 weight percent.

7. The method as recited in claim 1 , wherein the amount is 15-25 weight percent.

8. The method as recited in claim 1 , wherein the reactive filler is a powder that has an average particle size of 5-30 micrometers.

9. The method recited in claim 1 , wherein the fibrous structure has coated fibers and the coating includes a layer of silicon nitride that is in contact with the mixture upon filtration of the mixture into the pores, and a layer of boron nitride that is located between the layer of silicon nitride and the fibers.

10. A method for fabricating a ceramic material, the method comprising:
providing a mixture of a reactive filler with a preceramic polysilazane material, wherein the mixture has an amount, represented by a variable X, of up to 40 weight percent of the reactive filler;
infiltrating the mixture into pores of a fibrous structure that has coated fibers, wherein the coating on the coated fibers has a coating thickness represented by a variable t coating (nanometers);
selecting X and t coating such that a ratio of t coating /X (coating thickness in nanometers divided by weight percentage of reactive filler material) is from 3.75 to 25;
polymerizing the preceramic polysilazane material to form a green body; and
thermally treating the green body in an environment that is substantially free of oxygen to convert the polymerized preceramic polysilazane material into a ceramic material including at least one nitride phase that is a reaction product of the reactive filler and the preceramic polysilazane material.

11. The method as recited in claim 10 , wherein the ratio is from 10 to 20.

12. The method as recited in claim 11 , wherein the coating includes a layer of silicon nitride that is in contact with the mixture upon infiltration of the mixture into the pores, and the coating thickness is of the layer of silicon nitride.

13. The method as recited in claim 1 , wherein the reactive filler is the aluminum filler metal powder.

14. The method as recited in claim 1 , wherein the reactive filler is the titanium filler metal powder.

15. The method as recited in claim 10 , including controlling the effects of a reaction between the reactive filler and the coating on the fibers by selecting the ratio from 3.75 to 25.

Assignees

• Kmetz Michael A
• Coons Timothy P
• Reutenauer Justin W
• United Technologies Corp

Inventors

• Kmetz Michael A
• Coons Timothy P
• Reutenauer Justin W

Classifications

• C04B2235/404

  Refractory metals · CPC title

• C04B35/62894

  with more than one coating layer · CPC title

• C04B2235/3886

  Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride · CPC title

• C04B2235/3891

  Silicides, e.g. molybdenum disilicide, iron silicide · CPC title

• C04B35/589 Primary

  obtained from {Si-containing} polymer precursors {or organosilicon monomers} · CPC title