Light-transmitting bismuth-substituted rare-earth iron garnet-type calcined material, and magneto-optical device

Patent metadata

Field	Value
Publication number	US-9533917-B2
Application number	US-201314650050-A
Country	US
Kind code	B2
Filing date	Dec 2, 2013
Priority date	Dec 6, 2012
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body expressed by R 3-x Bi x Ye 5 O 12 and having an average crystal particle diameter of 0.3-10 micrometers, and a magneto-optical device using said calcined body; wherein R is at least one kind of elements selected from a group consisting of Y and lanthanoids, and x is a number from 0.5 to 2.5.

First claim

The invention claimed is:

1. A magneto-optical device comprising a magneto-optical element which is a light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body expressed by the formula R 3-x Bi x Fe 5 O 12 and having an average crystal particle diameter of 0.3-10 micrometers; wherein R is at least one kind of elements selected from a group consisting of Y and lanthanoids, and x is a number from 0.5 to 2.5,
wherein, in response to a 1310-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an insertion loss of 1.0 dB or lower and an extinction ratio of 35 dB or higher.

2. The magneto-optical comprising a magneto-optical element which is a light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body expressed by the formula R 3-x Bi x Fe 5 O 12 and having an average crystal particle diameter of 0.3-10 micrometers; wherein R is at least one kind of elements selected from a group consisting of Y and lanthanoids, and x is a number from 0.5 to 2.5,
wherein, in response to a 1550-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an insertion loss of 1.0 dB or lower and an extinction ratio of 35 dB or higher.

3. A method for manufacturing the light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body comprising:
producing a calcined body expressed by the formula R 3-x Bi x Fe 5 O 12 , wherein R is at least one element selected from Y and lanthanoids and x is a number from 0.5 to 2.5, having an average crystal particle diameter of 0.3 to 10 μm, and
modifying a valence of Fe ion of said calcined body produced by (a) annealing the calcined body in a gaseous atmosphere, and/or (b) in producing said calcined body, initially adding at least one element which can suppress the change in the valence of the Fe ion in the calcined body.

4. The method for according to claim 3 , wherein, in response to a 1310 nm-wavelength light or a 1550 nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body expressed by the R 3-x Bi x Fe 5 O 12 causes the light, in a forward direction, to have an insertion loss of 1.0 dB or lower and an extinction ratio of 35 dB or higher.

5. The method for according to claim 3 , wherein a valence of Fe ion of said calcined body produced is modified by annealing said calcined body in a gaseous atmosphere.

6. The method for according to claim 3 , wherein a valence of Fe ion of said calcined body produced is modified by, in producing said calcined body, initially adding at least one element which can suppress the change in the valence of the Fe ion in the calcined body.

7. The method for according to claim 3 , wherein said calcined body is produced by cold isostatic pressing to form a body, then preliminarily calcining the body under vacuum at 1050 to 1200° C. for 20 to 40 hours, then subjecting the body to hot isostatic pressing at 1150-1460° C., and then subjecting the body to an additional heat calcination at 1200 to 1320° C. for 1 to 5 hours.

8. The method for according to claim 3 , wherein said calcined body is produced by cold isostatic pressing to form a body, then preliminarily calcining the body under vacuum at 1050 to 1200° C. for 20 to 40 hours, then subjecting the body to hot isostatic pressing at 1150-1460° C., and then subjecting the body to an additional heat calcination at 1200 for 1 to 15 hours.

9. The magneto-optical device as claimed in claim 1 , wherein R is Y, Eu, Gd, Tb, Ho, Yb, Lu, or a combination of Gd and Tb.

10. The magneto-optical device as claimed in claim 1 , wherein x is a number from 1.0 to 2.5.

11. The magneto-optical device as claimed in claim 1 , wherein x is a number from 1.0 to 2.0.

12. The magneto-optical device as claimed in claim 1 , wherein x is a number from 1.5 to 2.5.

13. The magneto-optical device as claimed in claim 1 , wherein, in response to a 1310-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an insertion loss of 1.0 dB or lower.

14. The magneto-optical device as claimed in claim 1 , wherein, in response to a 1310-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an extinction ratio of 35 dB or higher.

15. The magneto-optical device as claimed in claim 2 , wherein, in response to a 1550-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an insertion loss of 1.0 dB or lower.

16. The magneto-optical device as claimed in claim 2 , wherein, in response to a 1550-nm-wavelength light, said light-transmitting bismuth-substituted rare-earth iron garnet-type calcined body causes the light, in a forward direction, to have an extinction ratio of 35 dB or higher.

Assignees

• Shinetsu Chemical Co

Inventors

• Watanabe Toshiaki

Classifications

• C04B35/26

  based on ferrites · CPC title

• C04B2235/764

  Garnet structure A3B2(CO4)3 · CPC title

• C04B35/2675 Primary

  Other ferrites containing rare earth metals, e.g. rare earth ferrite garnets · CPC title

• C04B2235/785

  Submicron sized grains, i.e. from 0,1 to 1 micron · CPC title

• G02F1/0036

  Magneto-optical materials · CPC title