Method for production of hydrocarbons by increasing hydrocarbon chain length

Patent metadata

Field	Value
Publication number	US-9533291-B2
Application number	US-201214375733-A
Country	US
Kind code	B2
Filing date	Nov 1, 2012
Priority date	Jan 31, 2012
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

The present invention provides a method for increasing hydrocarbon chain length. The method comprises providing a feedstock comprising fatty acids and/or fatty acid esters with hydrocarbon chain length below C23 into a reaction zone in which ketonization is conducted in the presence of a hydrotreatment catalyst under hydrogen pressure. The obtained ketones have a hydrocarbon chain length of from C24 to C43. The present invention further provides a method for simultaneous production of base oil components and fuel components.

First claim

The invention claimed is:

1. A method for increasing hydrocarbon chain length, comprising the steps of:
(i) introducing a feedstock comprising fatty acids and/or fatty acid esters having hydrocarbon chain lengths below C23 into a ketonization reaction zone,
(ii) subjecting said feedstock to ketonization and hydrotreatment reactions in the presence of a hydrotreatment catalyst under hydrogen pressure to produce an effluent comprising ketones, and
(iii) obtaining ketones having hydrocarbon chain lengths of from C24 to C43 from said effluent.

2. The method according to claim 1 , wherein the obtained ketones are further hydrodeoxygenated in a final hydrodeoxygenation step to form linear hydrocarbons.

3. The method according to claim 2 , wherein the ketonization and final hydrodeoxygenation step are performed in the ketonization reaction zone.

4. The method according to claim 2 , wherein the final hydrodeoxygenation step is performed in a separate reaction zone from the ketonization reaction zone subsequent to the ketonization reaction.

5. The method according to claim 1 , wherein the pressure in the ketonization c on zone is less than 2 MPa.

6. The method according to claim 1 , wherein the temperature in the ketonization reaction zone is from 350 to 450° C.

7. The method according to claim 1 , wherein the ratio of hydrogen to feedstock is from 100 to 600 Nl/I in the ketonization reaction zone.

8. The method according to claim 1 , wherein said hydrotreatment catalyst is a metal catalyst wherein the metal is selected from the group consisting of Fe, Pd, Pt, Ni, Mo, Co, Ru, Rh, W and any combination thereof.

9. The method according to claim 8 , wherein said hydrotreatment catalyst is NiMo or CoMo.

10. The method according to claim 1 , wherein said hydrotreatment catalyst is a sulfided hydrotreatment catalyst.

11. The method according to claim 1 , wherein said hydrotreatment catalyst is on a support.

12. A method for simultaneous production of base oil components and fuel components, the method comprising:
(i) introducing a feedstock comprising fatty acids and/or fatty acid esters into a reaction zone,
(ii) subjecting said feedstock to ketonization and hydrotreatment reactions in the presence of a hydrotreatment catalyst under hydrogen pressure to produce ketones,
(iii) hydrodeoxygenating said ketones to form linear hydrocarbons, wherein the ketonization reaction and the hydrodeoxygenating are performed in the same reaction zone or separate reaction zones,
(iv) isomerizing the linear hydrocarbons in an isomerization unit to produce a mixture of branched hydrocarbons, and
(v) separating from said mixture of branched hydrocarbons a base oil fraction comprising hydrocarbons having carbon numbers in a range of C24-C43 and a fuel components fraction having carbon numbers in a range of C5 to C20.

13. The method of claim 11 , wherein the hydrotreatment catalyst is on a support of activated carbon, alumina, or silica.

Assignees

• Neste Oil Oyj
• Neste Oyj

Inventors

• Myllyoja Jukka
• Aalto Pekka
• Piilola Rami

Classifications

• B01J23/04

  Alkali metals · CPC title

• B01J23/883

  and nickel · CPC title

• B01J37/20

  Sulfiding · CPC title

• C10G3/44

  characterised by the catalyst used · CPC title

• C07C5/2737

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title