Sinter resistant catalytic material and process of producing the same

Patent metadata

Field	Value
Publication number	US-9533286-B2
Application number	US-201313839416-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Aug 21, 2012
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A catalytic material including particles formed of a catalytic core material having a thermally resistant porous shell coated over the catalytic core material. An oxygen storage material is dispersed within the thermally resistant porous shell. In an example, the oxygen storage material is ceria. The catalytic material can further include a catalytic support, wherein the particles are deposited on the catalytic support. The catalytic support can be a powdered oxide including a material selected from the group consisting of alumina, silica, zirconia, niobia, ceria, titania, and combinations thereof. The catalytic core can include an element selected from the group consisting of Pt, Pd, Rh, Co, Ni, Mn, Cu, Fe, Au, Ag, and combinations thereof. The porous shell can be selected from materials consisting of alumina, baria, ceria, magnesia, niobia, silica, titania, yttria, and combinations thereof.

First claim

What is claimed:

1. A catalytic material comprising:
(a). particles formed of a catalytic core material wherein the catalytic core includes Pt;
(b). a thermally resistant porous shell different from the catalytic core material and coated over the catalytic core material; and
(c). a separate oxygen storage material relative to the porous shell, the oxygen storage material dispersed within the thermally resistant porous shell.

2. The catalytic material of claim 1 wherein the oxygen storage material is ceria.

3. The catalytic material of claim 1 , further comprising a catalytic support, wherein the catalytic material is deposited on the catalytic support.

4. The catalytic material of claim 3 wherein the particles deposited on the catalytic support are washcoated onto a monolith substrate.

5. The catalytic material of claim 3 wherein the catalytic support is a substrate including a material selected from the group consisting of alumina, silica, zirconia, niobia, ceria, titania, and combinations thereof.

6. The catalytic material of claim 1 wherein the catalytic core includes an element selected from the group consisting Pd, Rh, Ir, Co, Ni, Mn, Cu, Fe, Au, Ag, and combinations thereof.

7. The catalytic material of claim 1 wherein the porous shell is selected from materials consisting of alumina, baria, ceria, magnesia, niobia, silica, titania, yttria, and combinations thereof.

8. The catalytic material of claim 1 wherein the porous shell is silica.

9. The catalytic material of claim 1 wherein the porous shell is a mixture of silica and alumina.

10. The catalytic material of claim 1 wherein the particles are nanoparticles defining an average particle diameter of less than 1 micron.

11. The catalytic material of claim 1 wherein the porous shell is formed by removing a surfactant cap from a catalytic core coated with an oxygen storage-doped shell by applying heat.

12. The catalytic material of claim 1 wherein the thermally resistant porous shell resists sintering among particles of the catalytic material as compared to a catalytic material defining catalytic particles absent a thermally resistant porous shell.

13. The catalytic material of claim 12 wherein the thermally resistant shell resists sintering at temperatures of greater than at least 800 degrees centigrade as compared to the catalytic material defining catalytic particles absent a thermally resistant porous shell.

14. A method of making a catalytic material doped with an oxygen storage material comprising the steps of:
providing particles formed of a catalytic core material including Pt and having a surfactant cap;
surrounding the particles with an thermal resistant porous shell material different from the catalytic core material and coated over the catalytic core material;
adding an oxygen storage material separate relative to the porous shell to disperse into the thermal resistant porous shell material;
depositing the particles surrounded by the shell material and oxygen storage material onto a catalytic support; and
applying heat for a time and a temperature sufficient to remove the surfactant layer.

15. The method of claim 14 wherein the oxygen storage material is ceria.

16. The method of claim 14 wherein the particles deposited on the catalytic support are washcoated onto a monolith substrate.

17. The method of claim 14 wherein the catalytic support is a substrate including a material selected from the group consisting of alumina, silica, zirconia, niobia, ceria, titania, and combinations thereof.

18. The method of claim 14 wherein the porous shell is selected from materials consisting of alumina, baria, ceria, magnesia, niobia, silica, titania, yttria, and combinations thereof.

19. The method of claim 14 wherein the catalytic core includes an element selected from the group consisting of, Pd, Rh, Ir, Co, Ni, Mn, Cu, Fe, Au, Ag, and combinations thereof.

20. A catalytic material comprising:
a) particles formed of a catalytic core material;
b) a thermally resistant porous shell different from the catalytic core material and coated over the catalytic core material wherein the porous shell is a mixture of silica and alumina; and
c) a separate oxygen storage material relative to the porous shell, the oxygen storage material dispersed within the thermally resistant porous shell.

Assignees

• Toyota Motor Eng & Mfg North America Inc

Inventors

• Stamm Masias Kimber L
• Fanson Paul T

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/23

  in a colloidal state · CPC title

• B01J37/031 Primary

  Precipitation · CPC title

• B01J37/16

  Reducing · CPC title