Systems and methods for isolating a particulate product when recycling lead from spent lead-acid batteries

Patent metadata

Field	Value
Publication number	US-9533273-B2
Application number	US-201414498839-A
Country	US
Kind code	B2
Filing date	Sep 26, 2014
Priority date	Jun 20, 2014
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

The present disclosure relates to systems and methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes forming a first mixture in a first vessel, wherein the first mixture includes a lead-bearing material and a carboxylate source, which react to precipitate lead salt particles. The method includes separating a portion of the first mixture from a remainder of the first mixture, wherein the portion includes lead salt particles having specific densities below a specific density threshold value and/or having particle sizes below a particle size threshold value. The method includes forming a second mixture in a second vessel, wherein the second mixture includes the lead salt particles from the separated portion of the first mixture. The method further includes separating the lead salt particles of the second mixture from a liquid component of the second mixture.

First claim

The invention claimed is:

1. A method, comprising:
forming a first mixture in a first vessel, wherein the first mixture comprises a lead-bearing material and a carboxylate source that react to precipitate lead carboxylate particles;
selectively isolating a portion of the first mixture from a remainder of the first mixture, wherein the portion mostly includes lead carboxylate particles having specific densities below a specific density threshold value and having particle sizes below a particle size threshold value;
forming a second mixture in a second vessel, wherein the second mixture comprises the lead carboxylate particles from the portion of the first mixture; and
separating the lead carboxylate particles of the second mixture from a liquid component of the second mixture.

2. The method of claim 1 , wherein the second mixture grows and/or agglomerates the lead carboxylate particles into larger lead carboxylate particles.

3. The method of claim 1 , wherein the specific density threshold value is less than 6 grams per milliliter (g/mL).

4. The method of claim 1 , wherein the specific density threshold value is less than 5 g/mL.

5. The method of claim 1 , wherein the specific density threshold value is less than 4 g/mL.

6. The method of claim 1 , wherein the specific density threshold value is less than 3 g/mL.

7. The method of claim 1 , wherein separating the lead carboxylate particles of the second mixture from the liquid component of the second mixture comprises using a belt dryer, a filter press, a clarifier, a settling tank, a cyclone separator, or a combination thereof.

8. The method of claim 1 , comprising treating the lead carboxylate particles separated from the second mixture to yield leady oxide using a belt dryer, a spray calciner, a stirred pot reactor, a rotary kiln calciner, or a combination thereof.

9. The method of claim 1 , comprising treating the lead carboxylate particles separated from the second mixture with a hydroxide to yield leady oxide.

10. The method of claim 1 , wherein the carboxylate source comprises citric acid, a salt of citric acid, or a combination thereof.

11. The method of claim 1 , wherein the particle size threshold value is between 1 micrometers (μm) and 20 μm.

12. The method of claim 1 , wherein the first mixture comprises a peroxide, a hydroxide, sodium carbonate, or a combination thereof.

13. The method of claim 1 , wherein the second mixture comprises seed crystals, acid, base, or a combination thereof.

14. The method of claim 1 , wherein the selectively isolating the portion of the first mixture comprises using a filter press, a clarifier, a settling tank, a cyclone separator, a centrifuge, or a combination thereof.

15. A method, comprising:
forming a first mixture in a first vessel, wherein the first mixture comprises a carboxylate source and particles, wherein the particles comprise lead-bearing particles and lead carboxylate particles, wherein the lead carboxylate particles are generated as a product of reactions between the lead-bearing particles and the carboxylate source in the first mixture;
selectively isolating a portion of the particles from the first mixture based at least in part on the portion having particle sizes below a particle size threshold value, wherein the portion mostly includes lead carboxylate particles; and
treating the portion of the particles to yield leady oxide.

16. The method of claim 15 , wherein the carboxylate source comprises citric acid, a salt of citric acid, or a combination thereof.

17. The method of claim 15 , wherein the particle size threshold value is between 1 μm and 20 μm.

18. The method of claim 17 , wherein the particle size threshold value is less than 10 μm.

19. The method of claim 15 , wherein selectively isolating further comprises selectively isolating the portion of the particles from the first mixture also based at least in part on the portion having specific densities below a specific density threshold value.

20. The method of claim 19 , wherein the specific density threshold value is less than 6 g/mL.

21. A method, comprising:
forming a first mixture in a first vessel, wherein the first mixture comprises a carboxylate source and particles, wherein the particles comprise lead-bearing particles and lead carboxylate particles, wherein the lead carboxylate particles are generated as a product of reactions between the lead-bearing particles and the carboxylate source in the first mixture;
selectively isolating a portion of the particles from the first mixture based at least in part on the portion of the particles having specific densities below a specific density threshold value, wherein the portion mostly includes lead carboxylate particles; and
treating the isolated lead carboxylate particles to yield leady oxide.

22. The method of claim 21 , wherein the carboxylate source comprises citric acid, a salt of citric acid, or a combination thereof.

23. The method of claim 21 , wherein the specific density threshold value is less than 6 g/mL.

24. The method of claim 23 , wherein the specific density threshold value is between approximately 4 g/mL and approximately 4.5 g/mL.

25. The method of claim 23 , wherein the specific density threshold value is between approximately 2 g/mL and approximately 2.5 g/mL.

26. The method of claim 23 , wherein selectively isolating comprises selectively isolating the portion of the particles from the first mixture based at least in part on the portion having particle sizes below a particle size threshold value, and wherein the particle size threshold value is between 1 μm and 20 μm.

27. The method of claim 26 , wherein the particle size threshold value is less than 10 μm.

28. The method of claim 27 , wherein the particle size threshold value is less than 5 μm.

29. The method of claim 21 , wherein selectively isolating comprises using a clarifier, a settling tank, a cyclone separator, a centrifuge, or a combination thereof.

Assignees

• Johnson Controls Tech Co

Inventors

• Meissner Eberhard
• Spence Matthew A
• Curran Patrick M

Classifications

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• C22B13/045

  Recovery from waste materials · CPC title

• C22B7/006

  Wet processes · CPC title

• B01J6/002

  using rotating drums · CPC title