Stainless steel for fuel cell separators

Patent metadata

Field	Value
Publication number	US-9531014-B2
Application number	US-201214355661-A
Country	US
Kind code	B2
Filing date	Nov 28, 2012
Priority date	Nov 30, 2011
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A stainless steel having a low surface contact resistance for fuel cell separators is provided. The stainless steel has a Cr content of 16 to 40 mass % or more. The stainless steel includes a region having a fine textured structure on its surface, and the area percentage of the region is 50% or more, preferably 80% or more. The region having a fine textured structure is a region which has a structure having depressed portions and raised portions at an average interval between depressed portions or raised portions of 20 nm or more and 150 nm or less when observed with a scanning electron microscope.

First claim

The invention claimed is:

1. A stainless steel having a low surface contact resistance for fuel cell separators and a Cr content in the range of 16 to 40 mass %, wherein
the stainless steel includes a region having a fine textured structure on its surface, the area percentage of the region being 50% or more, and
the region having a fine textured structure is a region which has a structure having depressed portions and raised portions at an average interval between the depressed portions or the raised portions of 20 nm or more and 150 nm or less when observed with a scanning electron microscope,
wherein the raised portions of the fine textured structure have a triangular pyramidal top having an average angle of 80 degrees or more and 100 degrees or less, and
the stainless steel includes trapezoidal projection structures having an average height of 0.15 μm or more and 2 μm or less and an average diameter of 3 μm or more and 50 μm or less, the area percentage of the dispersed trapezoidal projection structures being 5% or more and 30% or less.

2. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the area percentage is 80% or more.

3. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the triangular pyramidal tops of the raised portions are disposed at an average interval of 100 nm or less.

4. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the trapezoidal projection structures correspond to crystal grains of the stainless steel.

5. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the area percentage is 80% or more, and
the triangular pyramidal tops of the raised portions are disposed at an average interval of 100 nm or less.

6. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the area percentage is 80% or more, and
the trapezoidal projection structures correspond to crystal grains of the stainless steel.

7. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the triangular pyramidal tops of the raised portions are disposed at an average interval of 100 nm or less, and
the trapezoidal projection structures correspond to crystal grains of the stainless steel.

8. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the area percentage is 80% or more,
the triangular pyramidal tops of the raised portions are disposed at an average interval of 100 nm or less, and
the trapezoidal projection structures correspond to crystal grains of the stainless steel.

9. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein the stainless steel has a surface contact resistance of 10 mΩ·cm 2 or less.

10. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein after the stainless steel is immersed in a sulfuric acid solution containing 0.1 ppm fluoride ions at pH 3 and at 80° C. for 24 hours at 0.6 V versus a Ag—AgCl reference electrode, the stainless steel has a surface contact resistance of 10 mΩ·cm 2 or less.

11. The stainless steel having a low surface contact resistance for fuel cell separators according to claim 1 , wherein after the stainless steel is immersed in a sulfuric acid solution containing 0.1 ppm fluoride ions at pH 3 and at 80° C. for 500 hours at 0.6 V versus a Ag—AgCl reference electrode, the stainless steel has a surface contact resistance of 10 mΩ·cm 2 or less.

Assignees

• Jfe Steel Corp

Inventors

• Nagoshi Masayasu
• Ide Shinsuke
• Ishikawa Shin
• Makiishi Noriko

Classifications

• C22C38/50

  with titanium or zirconium · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• C21D6/004 Primary

  containing Cr and Ni · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/021 Primary

  Alloys based on iron · CPC title