Self-Aligned Patterning using Directed Self-Assembly of Block Copolymers
US-2016104628-A1 · Apr 14, 2016 · US
US9530663B1 · US · B1
| Field | Value |
|---|---|
| Publication number | US-9530663-B1 |
| Application number | US-201514746849-A |
| Country | US |
| Kind code | B1 |
| Filing date | Jun 23, 2015 |
| Priority date | Jun 23, 2015 |
| Publication date | Dec 27, 2016 |
| Grant date | Dec 27, 2016 |
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A method for forming a pattern includes steps of forming a patterned core layer on a substrate, conformally forming a spacer layer on the patterned core layer to form first concave portions, performing an etch back process to expose the patterned core layer, removing the exposed patterned core layer to form second concave portions, filling up the first concave portions and the second concave portions with a directed self-assembly material, and activating a directed self-assembly process, so that the directed self-assembly material is diffused to the perimeter of the concave portions to form a hole surrounding by the directed self-assembly material in each concave portions.
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What is claimed is: 1. A method for forming a pattern, comprising: forming an array of circular pillars on a substrate, wherein the circular pillars are arranged in a staggered manner; conformally forming a spacer layer on the circular pillars and the substrate to form a plurality of first concave portions surrounded by the spacer layer; etching the spacer layer to form an annular spacer surrounding each of the circular pillars and expose the circular pillars; removing the circular pillars to form a plurality of second concave portions surrounded by the annular spacer; filling up the first concave portions and the second concave portions with a directed self-assembly material; and activating a directed self-assembly process so that the directed self-assembly material filling up the first concave portions and the second concave portions diffuse to the boundaries of the first concave portions and the second concave portions to form a hole surrounding by the directed self-assembly material in each of the first concave portions and the second concave portions. 2. The method for forming a pattern of claim 1 , further comprising: using the annular spacer and the remaining directed self-assembly material as an etch mask to etch the substrate, thereby transferring the pattern of the holes to the substrate. 3. The method for forming a pattern of claim 2 , wherein the substrate further comprises a topmost hard mask layer, and the pattern of the holes is transferred to the topmost hard mask layer to form a patterned hard mask layer. 4. The method for forming a pattern of claim 3 , further comprising using the patterned hard mask layer as an etch mask to etch the substrate. 5. The method for forming a pattern of claim 1 , wherein the first concave portions are evenly distributed in the array with the circular pillars and surrounded by the spacer layer, and wherein each of the first concave portions is surrounded by four of the circular pillars. 6. The method for forming a pattern of claim 1 , wherein the second concave portions are evenly distributed on the substrate and surrounded by the annular spacer, and wherein each of the first concave portions is surrounded by four of the second concave portions. 7. The method for forming a pattern of claim 1 , wherein the pattern of the holes is an array of contact holes. 8. The method for forming a pattern of claim 7 , wherein the pattern of the holes comprises identical shape and size of the contact holes after the directed self-assembly process. 9. The method for forming a pattern of claim 1 , wherein the spacer layer is formed by an atomic layer deposition process. 10. The method for forming a pattern of claim 1 , wherein the directed self-assembly process comprises a baking process or an annealing process. 11. The method for forming a pattern of claim 1 , wherein the directed self-assembly material comprises polystyrene, polymethylmethacrylate, polydienes, poly(ethylene oxide), poly(propylene oxide), poly(butylene oxide), poly((meth)acrylates), polyesters, poly-organosiloxanes, or polyorganogermanes.
characterised by the processes involved to create the masks · CPC title
of masks comprising organic materials · CPC title
Process specially adapted to improve the resolution of the mask · CPC title
using masks for insulating materials · CPC title
using processes for implementing desired shapes or dispositions of the openings, e.g. double patterning · CPC title
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