Enhanced nitrogen removal in an LNG facility

Patent metadata

Field	Value
Publication number	US-9528759-B2
Application number	US-11736408-A
Country	US
Kind code	B2
Filing date	May 8, 2008
Priority date	May 8, 2008
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

An LNG facility employing an enhanced nitrogen removal system that concentrates the amount of nitrogen in the feed stream to a nitrogen removal unit (NRU) to thereby increase the separation efficiency of the NRU. In one embodiment, the nitrogen removal system comprises a multistage separation vessel operable to separate nitrogen from a cooled natural gas stream. At least a portion of the resulting nitrogen-containing stream exiting the multistage separation vessel can be used as a refrigerant, processed to a nitrogen removal unit, and/or utilized as fuel gas for the LNG facility.

First claim

The invention claimed is:

1. A process for liquefying a natural gas stream in an LNG facility, the process comprising:
(a) cooling at least a portion of the natural gas stream in a plurality of upstream mechanical refrigeration cycles to form a predominantly natural gas stream wherein each upstream mechanical refrigeration cycle comprises a heat exchanger for providing indirect heat exchange with a pure component refrigerant for cooling the natural gas stream;
(b) introducing the predominantly natural gas stream to a heavies removal unit to remove a portion of the heavies from the predominantly natural gas stream to form a predominantly methane stream;
(c) after step (b) and downstream of the heavies removal unit, introducing the predominantly methane stream to an open-loop methane refrigeration cycle wherein the open-loop methane refrigeration cycle comprises an open-loop methatne refrigeration cycle heat exchanger, a refrigeration compressor, and a refrigerant chiller downstream of the refrigerant compressor;
(d) after (c) and downstream of the heavies removal unit, cooling the predominantly methane stream in the open-loop methane refrigeration heat exchanger;
(e) after (d) and downstream of the open-loop methane refrigeration cycle heat exchanger, separating at least a portion of the predominantly methane stream in a multistage separation vessel, wherein the multistage separation vessel comprises a plurality of mass transfer surfaces and a reboiler, to provide a predominantly vapor stream and a predominantly liquid stream, wherein at least a portion of the predominantly vapor stream is routed to a nitrogen removal unit; and
(f) using the predominantly vapor stream as a refrigerant in the open-loop methane refrigeration cycle by introducing the predominantly vapor stream to a warming pass of the open-loop methane refrigeration cycle heat exchanger for cooling the predominantly methane stream in step (d);
(g) after step (f)and downstream of the warming pass of the open-loop methane
refrigeration cycle heat exchanger, compressing the refrigerant in the refrigeration compressor; (h) cooling the refrigerant in the refrigeration chiller;
(i) after step (h), introducing the refrigerant to a cooling pass of at least one of the plurality of heat exchangers of the upstream mechanical refrigeration cycles to form a reboiler duty stream;
(j) introducing the reboiler duty stream to a warming pass of the reboiler to provide a reboiler duty for the multistage separation vessel to form a cold reflux stream;
(k) introducing the cold reflux stream to the multistage separation vessel to provide reflux to the multi stage separation vessel; and
(l) withdrawing at least a portion of the predominantly liquid product stream as a liquefied natural gas product.

2. The process of claim 1 , wherein (i) comprises introducing the chilled compressed refrigerant to a cooling pass of at least two of the plurality of heat exchangers of the upstream mechanical refrigeration cycles to form a reboiler duty stream.

3. The process of claim 1 , further comprising introducing at least a portion of the predominantly vapor stream into a nitrogen removal unit.

4. The process of claim 1 , wherein the heavies removal unit comprises a heavies removal column located upstream of the open-loop methane refrigeration cycle to separate the predominantly methane stream into a heavies-depleted stream and a heavies-rich stream, wherein the at least a portion of the predominantly methane stream introduced into the open-loop methane refrigeration cycle heat exchanger comprises at least a portion of the heavies-depleted stream.

5. The process of claim 4 , wherein the nitrogen mole fraction of the predominantly vapor stream is at least about 1.25 times greater than the nitrogen mole fraction of the predominantly methane stream introduced to the multistage separation vessel.

6. The process of claim 4 , wherein the nitrogen mole fraction of the predominately vapor stream is at least 2 times greater than the nitrogen mole fraction of the cooled predominately methane stream introduced into the multistage separation vessel.

7. The process of claim 1 , wherein the predominately methane stream introduced into the multistage separation vessel has a nitrogen concentration of less than about 15 mole percent, wherein the predominately vapor stream has a nitrogen concentration of at least 20 mole percent.

8. The process of claim 7 , wherein the predominately vapor stream has a nitrogen concentration of at least 30 mole percent.

9. The process of claim 1 , further comprising flashing at least a portion of the predominately liquid stream to provide a two-phase stream and using at least a portion of the two-phase stream to at least partially perform the cooling of step (f).

10. The process of claim 1 , further comprising flashing the predominately methane stream prior to introduction into the multistage separation vessel.

11. The process of claim 1 , wherein the multistage separation vessel comprises at least three theoretical stages.

12. The process of claim 1 , further comprising withdrawing a portion of the predominantly vapor stream to form a nitrogen rejection unit feed and introducing the nitrogen rejection unit feed to a nitrogen rejection unit.

13. The process of claim 1 , further comprising withdrawing a liquid stream from the lower portion of the multistage separation vessel and warming at least a portion of the withdrawn liquid stream via indirect heat exchange with a reflux stream prior to introducing the reflux stream into the multistage separation vessel.

14. The process of claim 1 , wherein the pure-component refrigerant is propane, propylene, ethane, or ethylene.

Assignees

• Ransbarger Weldon L
• Ortego Jr J Dale
• Conocophillips Co

Inventors

• Ransbarger Weldon L
• Ortego Jr J Dale

Classifications

• F25J1/0265

  comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer · CPC title

• F25J3/0209 Primary

  Natural gas or substitute natural gas · CPC title

• F25J2200/40

  Features relating to the provision of boil-up in the bottom of a column · CPC title

• F25J3/0257

  separation of nitrogen (from air F25J3/04, production of nitrogen in general C01B21/00) · CPC title

• F25J2200/70

  Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified · CPC title