Process for recovering soda values from underground soda deposits

Patent metadata

Field	Value
Publication number	US-9528361-B2
Application number	US-201314651338-A
Country	US
Kind code	B2
Filing date	Dec 12, 2013
Priority date	Dec 13, 2012
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

Process for recovering soda values from first and second soda deposits situated respectively in first and second underground cavities containing respectively first and second soda solutions, the second soda solution containing a higher concentration in sodium chloride and/or sodium sulfate than the first soda solution, the process comprising: extracting a stream of first soda solution from the first cavity; introducing the stream of first soda solution in a first process which produces first soda crystals and a first waste purge stream containing a higher concentration in sodium chloride and/or in sodium sulfate than the first soda solution; introducing at least part of the first waste purge stream in the second cavity; extracting a stream of second soda solution from the second cavity; and introducing the stream of second soda solution in a second process which produces second soda crystals which have a higher concentration in sodium chloride and/or sodium sulfate than the first soda crystals.

First claim

The invention claimed is:

1. A process for recovering soda values from a first soda deposit and a second soda deposit situated respectively in a first underground cavity and a second underground cavity containing respectively a first soda solution and a second soda solution, the second soda solution containing a higher concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, than the first soda solution, the process comprising:
extracting a stream of said first soda solution from the first underground cavity;
introducing the stream of said first soda solution in a first process which produces, out of the first soda solution, first soda crystals and a first waste purge stream containing a higher concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, than the first soda solution;
introducing at least a part of the first waste purge stream in the second underground cavity;
extracting a stream of said second soda solution from the second underground cavity; and
introducing the stream of said second soda solution in a second process which produces, out of the second soda solution, second soda crystals which have a higher concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, than the first soda crystals.

2. The process according to claim 1 , wherein a second waste purge stream is extracted from the second process, wherein a substream of said second waste purge is introduced into a pond, and wherein a remaining substream of said second waste purge is reintroduced into the second underground cavity.

3. The process according to claim 1 , wherein the first soda solution has a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of less than 1.5% by weight.

4. The process according to claim 1 , wherein the second soda solution has a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of more than 1.75% by weight.

5. The process according to claim 1 , wherein the second soda solution has a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of more than 2% by weight.

6. The process according to claim 1 , wherein the first process is selected from the group consisting of: an anhydrous sodium carbonate process, a sodium carbonate monohydrate process, a sodium carbonate heptahydrate process, a sodium carbonate decahydrate process, a sodium sesquicarbonate process, a wegscheiderite process, a sodium bicarbonate process, and any combinations thereof.

7. The process according to claim 6 , wherein at least one of the first process and the second process is a monohydrate process.

8. The process according to claim 7 , wherein one or both monohydrate processes comprise a multiple effect crystallizer.

9. The process according to claim 1 , wherein the second process is selected from the group consisting of: an anhydrous sodium carbonate process, a sodium carbonate monohydrate process, a sodium carbonate heptahydrate process, a sodium carbonate decahydrate process, a sodium sesquicarbonate process, a wegscheiderite process, a sodium bicarbonate process, and any combinations thereof.

10. The process according to claim 1 , wherein at least 40% in weight of the first waste purge stream is introduced in the second underground cavity.

11. The process according to claim 1 , wherein at least 70% by weight of the first waste purge stream is introduced in the second underground cavity.

12. The process according to claim 1 , wherein the second soda crystals have a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of more than 0.2% by weight.

13. The process according to claim 1 , wherein the first soda crystals have a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of less than 0.2% by weight.

14. The process according to claim 1 , wherein the first soda crystals and the second soda crystals are mixed to form a mixture, and wherein the mixture has a total concentration in sodium chloride, in sodium sulfate, or in sodium chloride and in sodium sulfate, of at most 0.2% by weight.

15. The process according to claim 1 , wherein at least of one of the first and second soda deposits is a Nahcolite deposit, a Wegscheiderite deposit, a Decemite deposit, or a Trona deposit.

16. The process according to claim 1 , wherein at least of one of the first and second soda deposits is a Trona deposit.

17. The process according to claim 1 , wherein the first and second soda crystals are alkaline sodium carbonated compound crystals selected from the group consisting of: sodium carbonate crystals, sodium carbonate monohydrate crystals, sodium carbonate heptahydrate crystals, sodium carbonate decahydrate crystals, sodium sesquicarbonate crystals, wegscheiderite crystals, sodium bicarbonate crystals, and any combinations thereof.

Assignees

• Solvay

Inventors

• Gilliard Pierre
• Vandendoren Alain

Classifications

• C01D7/126

  Multi-step processes, e.g. from trona to soda ash · CPC title

• E21B43/28 Primary

  Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent (E21B43/241 takes precedence) · CPC title

• E21B43/40 Primary

  Separation associated with re-injection of separated materials {(E21B43/385 takes precedence)} · CPC title