Method and apparatus for cooling pretreated biomass prior to mixing with enzymes

Patent metadata

Field	Value
Publication number	US-9528135-B2
Application number	US-201314426817-A
Country	US
Kind code	B2
Filing date	Sep 9, 2013
Priority date	Sep 10, 2012
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A method to treat biomass, e.g., lignocellulosic material, including: performing a pretreatment step on the biomass and discharging the pretreated biomass; in at least a first enzymatic hydrolysis reactor producing a liquefaction material, recirculating at least a portion of the liquefaction material from the at least first reactor to a location upstream of the addition of the enzymes as at least a portion of the coolant for the hot pretreated biomass.

First claim

What is claimed is:

1. A method for treating biomass material, comprising:
subjecting the biomass material to a pretreatment step to produce a pretreated biomass;
transferring the pretreated biomass to a transfer system, wherein the transfer system comprises a mixing vessel;
cooling and adjusting a pH of the pretreated biomass in the transfer system by adding a cooling liquid and a pH controlling material to obtain a cooled and pH controlled pretreated biomass having a temperature and a pH sufficient to allow enzymatic hydrolysis of the cooled and pH controlled pretreated biomass;
transferring the cooled and pH controlled pretreated biomass from the transfer system to a first enzymatic hydrolysis vessel;
subjecting the cooled and pH controlled pretreated biomass to a first enzymatic hydrolysis step to produce a liquefaction material in the first enzymatic hydrolysis vessel, wherein the liquefaction material has a concentration of monomeric sugar relative to polymeric cellulose and hemi-cellulose of less than 30 percent;
extracting a first portion of the liquefaction material from the first enzymatic hydrolysis vessel and cooling the first portion of the liquefaction material to create a cooled first portion of the liquefaction material;
reintroducing the cooled first portion of the liquefaction material to the transfer system, wherein a cooled first portion of the liquefaction material becomes the cooling liquid;
cooling the pretreated biomass in the transfer system with the cooled first portion of the liquefaction material; and
transferring a second portion of the liquefaction material from the first enzymatic hydrolysis vessel to a subsequent enzymatic hydrolysis vessel to undergo further enzymatic hydrolysis.

2. The method of claim 1 , wherein the biomass material is a lignocellulosic material.

3. The method of claim 1 further comprising comminuting the biomass material prior to subjecting the biomass material to the pretreatment step.

4. The method of claim 1 , wherein water or stillage or a recirculated process liquid from a mill is used as a portion of the cooling liquid in the cooling step.

5. The method of claim 1 , further comprising controlling the pH of the cooled pretreated biomass to about 4 to about 6.5 to obtain the cooled and pH controlled pretreated biomass.

6. The method of claim 1 , wherein the transfer system further comprises a first conveyor.

7. The method claim of claim 6 , wherein the transfer system further comprises a second conveyor.

8. The method of claim 7 further comprising contacting the cooled and pH controlled pretreated biomass with a first enzyme solution while discharging the cooled and pH controlled pretreated biomass from the first conveyor or the second conveyor or combination thereof within the transfer system.

9. The method of claim 1 further comprising contacting the cooled and pH controlled pretreated biomass with a first enzyme solution.

10. The method of claim 1 further comprising contacting the cooled and pH controlled pretreated biomass with a first enzyme solution in the transfer system.

11. The method of claim 1 further comprising contacting the cooled and pH controlled pretreated biomass with enzyme solution in the mixing vessel, at an inlet to the mixing vessel, or combination thereof.

12. The method of claim 1 , wherein the cooled and pH controlled pretreated biomass has a total solids concentration of about 10 wt. % to about 35 wt. %.

13. The method of claim 12 , wherein the cooled and pH controlled pretreated biomass has a temperature of about 40° C. to about 60° C.

14. The method of claim 12 , wherein the cooled and pH controlled pretreated biomass has a temperature of between about 45° C. to about 55° C.

15. The method of claim 1 , wherein an apparent viscosity of the liquefaction material is reduced to about 2,000 mPa·s or less.

16. The method of claim 15 , wherein the apparent viscosity of the liquefaction material is reduced to about 1,000 mPa·s or less.

17. The method of claim 16 , wherein the apparent viscosity of the liquefaction material is reduced to about 800 mPa·s or less.

18. The method of claim 1 , wherein the mixing vessel comprises a mixing device rotating within the mixer at a speed of about 400 to about 4,000 revolutions per minute.

19. The method of claim 1 , wherein the cooled and pH controlled pretreated biomass is retained in the mixing vessel for about 0.05 to about 200 seconds.

20. The method of claim 1 further comprising adding the cooled first portion of the liquefaction material to the cooled and pH controlled pretreated biomass.

21. The method of claim 20 , wherein the pH is controlled by adding an alkali compound.

22. The method of claim 20 , wherein the pH is controlled by adding an acidic compound.

23. The method of claim 1 , wherein the pH is controlled by adding an alkali compound.

24. The method of claim 1 , wherein the pH is controlled by adding an acidic compound.

25. The method of claim 1 , wherein the amount of hydrolysis in the liquefaction material is about 20% or less.

26. The method of claim 1 , wherein the amount of hydrolysis in the liquefaction material is about 15% or less.

27. The method of claim 1 , wherein the temperature of the pretreated biomass at the end of the pretreatment step is at least about 100° C.

28. The method of claim 1 , wherein the pretreated biomass is cooled to obtain a temperature of about 80° C. or less.

29. The method of claim 1 , wherein a biological catalyst is used to carry out the enzymatic hydrolysis process to obtain the liquefaction material, and the further enzymatic hydrolysis or any combination thereof.

30. The method of claim 29 , wherein the biological catalyst is a member selected from the group consisting of enzyme, yeast, thermophilic bacteria, and mesophilic bacteria.

31. The method of claim 1 , wherein the pretreatment of the biomass to obtain pretreated biomass is at least one of steam explosion, acidic condition hydrolysis, ammonium hydrolysis or lime hydrolysis or other suitable pretreatment or any combination thereof.

Assignees

• Andritz Inc

Inventors

• Romero Rodolfo
• Stromberg Bertil
• Turner Allen

Classifications

• C12P7/10

  substrate containing cellulosic material · CPC title

• C12P19/02

  Monosaccharides (2-ketogulonic acid C12P7/60) · CPC title

• C12P19/14 Primary

  produced by the action of a carbohydrase {(EC 3.2.x)}, e.g. by alpha-amylase {, e.g. by cellulase, hemicellulase} · CPC title

• C12P2201/00

  Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis · CPC title

• C12M21/18 Primary

  Apparatus specially designed for the use of free, immobilized or carrier-bound enzymes · CPC title