System for cooling pretreated biomass prior to mixing with enzymes

Patent metadata

Field	Value
Publication number	US-9528084-B2
Application number	US-201314426889-A
Country	US
Kind code	B2
Filing date	Sep 10, 2013
Priority date	Sep 10, 2012
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A method to treat biomass, e.g., lignocellulosic material, including: performing a pretreatment step on the biomass and discharging the pretreated biomass; in at least a first enzymatic hydrolysis reactor producing a liquefaction material, recirculating at least a portion of the liquefaction material from the at least first reactor to a location upstream of the addition of the enzymes as at least a portion of the coolant for the hot pretreated biomass.

First claim

What is claimed is:

1. A enzymatic hydrolysis system for biomass material comprising:
a pretreatment reactor for receiving a biomass material;
a transfer system, in fluid communication with a discharge of the pretreatment reactor, capable of receiving a cooling liquid and a pH adjusting material, wherein the cooling liquid and the pH adjusting material mix with the biomass material to produce a cooled and pH controlled pretreated biomass, wherein the cooled and pH controlled pretreated biomass has a first apparent viscosity;
an enzyme addition system in fluid communication with the transfer system for the addition of an enzyme solution, wherein the enzyme solution is introduced to the cooled and pH controlled pretreated biomass in the transfer system at an enzyme solution inlet;
a first enzymatic hydrolysis vessel in fluid communication with the transfer system, wherein the first enzymatic hydrolysis vessel and the transfer system are disposed downstream of the discharge of the pretreatment reactor, wherein the enzyme solution reacts with the cooled and pH controlled pretreated biomass to produce a liquefaction material having a second apparent viscosity and and a concentration of monomeric glucose relative to polymeric cellulose of less than 30 percent;
a recirculation conduit fluidly communicating with the first enzymatic hydrolysis vessel and transfer system, wherein the transfer system is disposed upstream of the first enzymatic hydrolysis vessel;
a first portion of the liquefaction material, wherein the first portion of the liquefaction material moves from the first enzymatic hydrolysis vessel through the recirculation conduit to the pretreated biomass in the transfer system; and
a cooling device in communication with the recirculation conduit, wherein the cooling device cools the first portion of the liquefaction material in the recirculation conduit before the first portion of the liquefaction material enters the transfer system, and wherein a second portion of the liquefaction material exits an outlet of the first enzymatic hydrolysis vessel to move downstream to a subsequent enzymatic hydrolysis reactor vessel, after the first portion of the liquefaction material enters the recirculation conduit, wherein the subsequent enzymatic hydrolysis reactor vessel produces a further hydrolyzed biomass.

2. The system of claim 1 , wherein the transfer system includes a first conveyor, wherein the first conveyor passes the pretreated biomass from the discharge of the pretreatment reactor, and wherein the first conveyor further comprises an inlet configured to introduce a cooling liquid or pH controlling material or combination thereof to the pretreated biomass.

3. The system of claim 2 , wherein the transfer system further comprises a second conveyor, or mixer, or combination thereof, and wherein the transfer system includes the enzyme solution inlet for introducing the enzyme solution to the cooled and pH controlled pretreated biomass.

4. The system of claim 3 , wherein the mixer is in fluid communication with a discharge of the first conveyor or the second conveyor, wherein the mixer includes a mixing device rotating at a speed of about 400 rpm to about 4,000 rpm, and wherein the mixer retains the cooled and pH controlled pretreated biomass and the enzyme solution for about 0.05 seconds to about 200 seconds, and wherein the mixer includes the enzyme solution inlet configured to introduce the enzyme solution to the cooled and pH controlled pretreated biomass during mixing.

5. The system of claim 3 , further comprising the mixer downstream of the first conveyor and fluidly communicating with the first conveyor, wherein the mixer has an enzyme solution inlet configured to receive the enzyme solution.

6. The system of claim 3 further comprising a second conveyor and a buffer tank for temporarily retaining the cooled and pH controlled pretreatment biomass from the second conveyor and discharging the cooled and pH controlled pretreated biomass to a transport device.

7. The system of claim 1 , wherein the recirculation conduit fluidly communicates with the transfer system upstream of enzyme solution inlet and thereby introduces liquefaction material to the pretreated biomass in the transfer system upstream of the enzyme solution inlet.

8. The system of claim 1 , wherein the subsequent enzymatic hydrolysis reactor vessel further comprises a plurality of subsequent reactor vessels, wherein each subsequent enzymatic hydrolysis reactor vessel is configured to receive the second portion of liquefaction material being transferred from the first enzymatic hydrolysis vessel.

9. The system of claim 1 , wherein the first apparent viscosity of the cooled and pH controlled pretreated biomass is greater than 5,000 mPa·s.

10. The system of claim 1 , wherein the second apparent viscosity the liquefaction material is less than 2,000 mPa·s.

11. The system of claim 1 , wherein the further hydrolyzed biomass has a monomeric glucose content of 30 percent or more relative to the polymeric cellulose.

12. A process flow system, comprising:
a pretreating reactor vessel configured to pretreat biomass at a temperature of at least about 100° C.;
a cooling conduit configured to introduce cooling liquid to cool a continuous flow of the pretreated biomass to a temperature no greater than 80° C. in a transfer system in fluid communication with the pretreating reactor vessel and downstream of the pretreating reactor vessel;
a pH controlling device configured to add pH controlling material to the pretreated biomass in the transfer system;
a first enzymatic hydrolysis vessel configured to enzymatically hydrolyze the cooled and pH controlled pretreated biomass using an enzyme, yeast, thermophilic bacteria, mesophilic bacteria or other biological catalyst to produce a liquefaction material, wherein the liquefaction material has a concentration of monomeric glucose relative to polymeric cellulose of less than 30 percent;
a subsequent enzymatic hydrolyzing reactor vessel configured to enzymatically hydrolyze a second portion of the liquefaction material produced in the first enzymatic hydrolysis vessel, wherein the enzyme, yeast, thermophilic bacteria, mesophilic bacteria or other biological catalyst enzymatically hydrolyzes the second portion of the liquefaction material, wherein the subsequent enzymatic hydrolyzing reactor vessel is coupled to receive the second portion of the liquefaction material discharged from the first enzymatic hydrolysis vessel; and
a pump configured to transfer the first portion of the liquefaction material to a cooling device communicating with the pump, wherein the pump is in fluid communication with the first enzymatic hydrolysis vessel and the transfer system, wherein the transfer system is disposed upstream of the first enzymatic hydrolysis vessel, wherein the first portion of the liquefaction material enters the pump, and wherein the cooling device cools the first portion of the liquefaction material before the first portion of the liquefaction material enters the transfer system.

Assignees

• Andritz Inc

Inventors

• Romero Rodolfo
• Stromberg Bertil
• Turner Allen

Classifications

• C12P19/14

  produced by the action of a carbohydrase {(EC 3.2.x)}, e.g. by alpha-amylase {, e.g. by cellulase, hemicellulase} · CPC title

• C12M45/06

  by chemical means or hydrolysis · CPC title

• Y02E50/16

  Cross-Sectional Technologies · mapped topic

• C12M33/04

  by injection or suction, e.g. using pipettes, syringes, needles (pipettes in general B01L3/02) · CPC title

• C12M41/26

  of pH · CPC title