Partially degradable particulates as time-released tracers for acidized and fractured gas wells
US-2024209729-A1 · Jun 27, 2024 · US
US9528044B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9528044-B2 |
| Application number | US-201313733927-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 4, 2013 |
| Priority date | Jan 4, 2013 |
| Publication date | Dec 27, 2016 |
| Grant date | Dec 27, 2016 |
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Methods comprising providing a drill-in fluid including an aqueous carrier fluid, a surfactant; and a self-degradable filter cake-forming agent which includes a plurality of degradable particulates which are operable to form an acid upon degradation, and a plurality of acid-degradable particulates. Drilling a wellbore through a reservoir section of a subterranean formation with the drill-in fluid, forming a thin internal filter cake within the wellbore from the self-degradable filter cake-forming agent. Releasing an acid derivative from at least a portion of the plurality of degradable particulates, interacting the acid with the filter cake so as to at least partially degrade the acid-degradable particulates therein. Thereby at least partially removing the filter cake allowing quick lift off of the remaining particulates, and producing a hydrocarbon fluid or gas from the subterranean formation.
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The invention claimed is: 1. A method comprising: providing a drill-in fluid consisting of: an aqueous fluid; a microemulsion-forming surfactant consisting of an alkyl propoxy-ethoxysulfate; and a self-degradable filter cake-forming agent, the self-degradable filter cake-forming agent consisting of: a plurality of degradable particulates, the plurality of degradable particulates being operable to form an acid upon degradation; and a plurality of acid-degradable particulates; drilling a wellbore through a reservoir section of a subterranean formation with the drill-in fluid wherein the microemulsion-forming surfactant alters the wettability of a surrounding reservoir and forms a microemulsion in situ with hydrocarbons present in the subterranean formation; forming an internal filter cake within the wellbore from the self-degradable filter cake-forming agent; providing an in situ generated acid from at least a portion of the plurality of degradable particulates; allowing the in situ generated acid to interact with the filter cake so as to at least partially degrade the filter cake such that any non-degraded portion of the filter cake is removed by lift off; and producing a hydrocarbon gas from the subterranean formation. 2. The method of claim 1 , wherein drilling a wellbore comprises drilling a multi-lateral horizontal wellbore system. 3. The method of claim 1 , wherein the plurality of degradable particulates comprises an acid-generating substance selected from the group consisting of a polyester, a polylactide, a polyglycolide, a poly(e-caprolactone), a polyanhydride, a poly(orthoester), a poly(amino acid), and any combination thereof. 4. The method of claim 1 , wherein the plurality of degradable particulates comprises poly(lactic acid). 5. The method of claim 1 , wherein the plurality of acid-degradable particulates comprises calcium carbonate particulates. 6. The method of claim 1 , wherein the drill-in fluid comprises between about 0.01 wt. % and about 20 wt. % of the surfactant. 7. The method of claim 1 , wherein the drill-in fluid comprises between about 1 wt. % and about 10 wt. % of the plurality of degradable particulates being operable to form an acid upon degradation. 8. The method of claim 1 , wherein the drill-in fluid comprises between about 1 wt. % and about 25 wt. % of the plurality of degradable particulates being operable to form an acid upon degradation. 9. A method comprising: providing a completion fluid consisting of: an aqueous carrier fluid; a microemulsion-forming surfactant consisting of an alkyl propoxy-ethoxysulfate; and a self-degradable fluid sealing agent, the self-degradable fluid sealing agent consisting of: a plurality of degradable particulates, the plurality of degradable particulates being operable to release an acid upon degradation; and a plurality of sized acid-degradable particulates; introducing the completion fluid into an uncompleted wellbore penetrating a subterranean formation wherein the microemulsion-forming surfactant alters the wettability of a surrounding reservoir and forms a microemulsion in situ with hydrocarbons present in the subterranean formation; forming a fluid seal within the uncompleted wellbore from the self-degradable fluid sealing agent; performing a completion operation in the uncompleted wellbore; providing an in situ generated acid from at least a portion of the plurality of degradable particulates; allowing the in situ generated acid to interact with the fluid seal so as to at least partially degrade the fluid seal, thereby at least partially removing the fluid seal; and producing a hydrocarbon gas from the subterranean formation. 10. The method of claim 9 , wherein at least a portion of the completion fluid penetrates into the subterranean formation from the uncompleted wellbore. 11. The method of claim 9 , wherein the plurality of degradable particulates comprises an acid-generating substance selected from the group consisting of a polyester, a polylactide, a polyglycolide, a poly(e-caprolactone), a polyanhydride, a poly(orthoester), a poly(amino acid), and any combination thereof. 12. The method of claim 9 , wherein the plurality of degradable particulates comprises poly(lactic acid). 13. The method of claim 9 , wherein the plurality of acid-degradable particulates comprises calcium carbonate particulates. 14. The method of claim 9 , wherein the completion fluid comprises between about 0.01 wt. % and about 20 wt. % of the surfactant. 15. The method of claim 9 , wherein the completion fluid comprises between about 1 wt. % and about 10 wt. % of the plurality of degradable particulates being operable to form an acid upon degradation. 16. The method of claim 9 , wherein the completion fluid comprises between about 1 wt. % and about 25 wt. % of the plurality of degradable particulates being operable to release an acid upon degradation.
containing synthetic organic macromolecular compounds or their precursors · CPC title
Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells (applicable only to water E03B) · CPC title
macromolecular compounds {(C09K8/512 takes precedence)} · CPC title
macromolecular compounds · CPC title
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