Compositions and methods for treatment of well bore tar

Patent metadata

Field	Value
Publication number	US-9528043-B2
Application number	US-201414203030-A
Country	US
Kind code	B2
Filing date	Mar 10, 2014
Priority date	Dec 16, 2011
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

Of the many compositions and methods, one method includes contacting tar resident in a well bore with a tar stabilizer comprising an acrylonitrile-butadiene copolymer; and allowing the tar stabilizer to interact with the tar to at least partially reduce the tendency of the tar to adhere to a surface.

First claim

What is claimed is:

1. A well bore drilling fluid comprising:
an aqueous fluid;
a weighting agent; and
an acrylonitrile-butadiene copolymer,
wherein the acrylonitrile content of the copolymer is about 1% to about 99% by weight of the copolymer, and the butadiene content is about 1% to about 99% by weight of the copolymer,
wherein the acrylonitrile is substituted with at least one group selected from the group consisting of a chloro group, a bromo group, a fluoro group, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, and an aryl group, and
wherein the well bore drilling fluid has a density of from about 7.5 pounds per gallon to about 18 pounds per gallon.

2. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer is carboxylated.

3. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer further comprises a styrene.

4. The fluid of claim 3 , wherein the acrylonitrile-butadiene copolymer comprises an additional monomer in an amount of less than about 1% by weight.

5. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer comprises acrylonitrile in an amount of about 50% to about 95% by weight of the copolymer, butadiene in an amount of about 5% to about 50% by weight of the copolymer, and styrene in an amount up to about 25% by weight of the copolymer.

6. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer is an emulsion-polymerized acrylonitrile-butadiene copolymer.

7. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer is anionic.

8. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer is present in the well bore drilling fluid in an amount of about 1% to about 70% by volume of the well bore drilling fluid.

9. The fluid of claim 1 , wherein the acrylonitrile-butadiene copolymer is present in the well bore drilling fluid in an amount of about 1% to about 10% by volume of the well bore drilling fluid.

10. The fluid of claim 1 , wherein the well bore drilling fluid further comprises a viscosifier selected from the group consisting of a colloidal agent, a clay, a polymer, guar gum, an emulsion-forming agent, diatomaceous earth, a biopolymer, a synthetic polymer, chitosan, a starch, a gelatin, and any mixture thereof.

11. The fluid of claim 1 , wherein the well bore drilling fluid further comprises at least one additive selected from the group consisting of a salt, a surfactant, a fluid-loss-control additive, a gas, nitrogen, carbon dioxide, a surface-modifying agent, a tackifying agent, a foamer, a corrosion inhibitor, a scale inhibitor, a catalyst, a clay-control agent, a biocide, a friction reducer, an antifoam agent, a bridging agent, a dispersant, a flocculant, hydrogen sulfide scavenger, carbon dioxide scavenger, an oxygen scavenger, a lubricant, a viscosifier, a breaker, barite, a relative-permeability modifier, a resin, a particulate material, a proppant particulate, a wetting agent, a coating-enhancement agent, and any combination thereof.

12. A well bore drilling fluid comprising:
an aqueous fluid;
a weighting agent; and
an acrylonitrile-butadiene copolymer,
wherein the acrylonitrile content of the copolymer is about 1% to about 99% by weight of the copolymer, and the butadiene content is about 1% to about 99% by weight of the copolymer,
wherein the well bore drilling fluid has a density of from about 7.5 pounds per gallon to about 18 pounds per gallon,

wherein the well bore drilling fluid further comprises well bore tar that is not emulsified, wherein the acrylonitrile-butadiene copolymer coats or encapsulates the well bore tar such that the well bore tar is less tacky.

13. A well bore drilling fluid comprising:
an aqueous fluid;
a weighting agent; and
an acrylonitrile-butadiene copolymer,
wherein the acrylonitrile content of the copolymer is about 1% to about 99% by weight of the copolymer, and the butadiene content is about 1% to about 99% by weight of the copolymer,
wherein the butadiene is substituted with at least one group selected from the group consisting of a chloro group, a bromo group, a fluoro group, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, and an aryl group, and
wherein the well bore drilling fluid has a density of from about 7.5 pounds per gallon to about 18 pounds per gallon.

14. The fluid of claim 13 , wherein the acrylonitrile-butadiene copolymer is carboxylated.

15. The fluid of claim 13 , wherein the acrylonitrile-butadiene copolymer further comprises a styrene.

16. The fluid of claim 15 , wherein the acrylonitrile-butadiene copolymer comprises an additional monomer in an amount of less than about 1% by weight.

17. The fluid of claim 13 , wherein the acrylonitrile-butadiene copolymer comprises acrylonitrile in an amount of about 50% to about 95% by weight of the copolymer, butadiene in an amount of about 5% to about 50% by weight of the copolymer, and styrene in an amount up to about 25% by weight of the copolymer.

18. The fluid of claim 13 , wherein the acrylonitrile-butadiene copolymer is an emulsion-polymerized acrylonitrile-butadiene copolymer.

Assignees

• Halliburton Energy Services Inc

Inventors

• Livanec Philip Wayne
• Perez Gregory Paul

Classifications

• C09K8/04

  Aqueous well-drilling compositions · CPC title

• C09K8/524 Primary

  organic depositions, e.g. paraffins or asphaltenes · CPC title