Resin composition, prepreg, and laminate

Patent metadata

Field	Value
Publication number	US-9527979-B2
Application number	US-201214355674-A
Country	US
Kind code	B2
Filing date	Oct 30, 2012
Priority date	Nov 2, 2011
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A resin composition of the present invention contains a mixture (A) of at least two of cyanate ester compounds selected from the group consisting of cyanate ester compounds (A1) to (A3) having a specific structural unit, an epoxy resin (B), and an inorganic filler (C). A prepreg of the present invention is obtained by impregnating a base material with the resin composition or applying the resin composition to a base material. Furthermore, a metal foil-clad laminate of the present invention is the laminate comprising the prepreg. Furthermore, a printed wiring board of the present invention contains an insulating layer and a conductor layer formed on a surface of the insulating layer, in which the insulating layer contains the resin composition.

First claim

The invention claimed is:

1. A resin composition comprising:
a mixture (A) of at least two cyanate ester compounds selected from the group consisting of a cyanate ester compound (A1) having a structural unit represented by the following general formula (1), a cyanate ester compound (A2) having a structural unit represented by the following general formula (2), and a cyanate ester compound (A3) having a structural unit represented by the following general formula (3);
an epoxy resin (B); and
an inorganic filler (C):

wherein n is each independently an integer of 1 or more, and R 1 and R 2 are each independently a hydrogen atom, an alkyl group, or an aryl group.

2. The resin composition according to claim 1 , wherein a mixing ratio of the cyanate ester compound (A1) is 30 to 70 mol %, a mixing ratio of the cyanate ester compound (A2) is 15 to 45 mol %, and a mixing ratio of the cyanate ester compound (A3) is 5 to 35 mol %, based on 100 mol % of the total of the mixture (A) of the cyanate ester compounds.

3. The resin composition according to claim 2 , wherein n in the general formulae (1) to (3) is each independently an integer of 1 to 50.

4. The resin composition according to claim 2 , wherein the inorganic filler (C) is silica.

5. The resin composition according to claim 2 , wherein a content of the mixture (A) of the cyanate ester compounds is 10 to 90 parts by mass based on 100 parts by mass of the total of the mixture (A) of the cyanate ester compounds and the epoxy resin (B).

6. The resin composition according to claim 2 , wherein a content of the inorganic filler (C) is 10 to 1000 parts by mass based on 100 parts by mass of the total amount of the mixture (A) of the cyanate ester compounds and the epoxy resin (B).

7. A printed wiring board comprising an insulating layer, and a conductor layer formed on a surface of the insulating layer, wherein the insulating layer comprises the resin composition according to claim 2 .

8. The resin composition according to claim 1 , wherein n in the general formulae (1) to (3) is each independently an integer of 1 to 50.

9. The resin composition according to claim 1 , wherein the epoxy resin (B) is an aralkyl-based epoxy resin.

10. The resin composition according to claim 9 , wherein the aralkyl-based epoxy resin is at least one selected from the group consisting of a phenol phenyl aralkyl-based epoxy resin represented by the following general formula (4), a phenol biphenyl aralkyl-based epoxy resin represented by the following general formula (5), and a naphthol aralkyl-based epoxy resin represented by the following general formula (6):

wherein m is each independently an integer of 1 to 50; R 3 to R 14 are each independently a hydrogen atom, a methyl group, an ethyl group, or an aryl group.

11. The resin composition according to claim 1 , wherein the inorganic filler (C) is silica.

12. The resin composition according to claim 1 , wherein a content of the mixture (A) of the cyanate ester compounds is 10 to 90 parts by mass based on 100 parts by mass of the total of the mixture (A) of the cyanate ester compounds and the epoxy resin (B).

13. The resin composition according to claim 1 , wherein a content of the inorganic filler (C) is 10 to 1000 parts by mass based on 100 parts by mass of the total amount of the mixture (A) of the cyanate ester compounds and the epoxy resin (B).

14. A prepreg obtained by impregnating a base material with the resin composition according to claim 1 or applying the resin composition to a base material.

15. A metal foil-clad laminate comprising the prepreg according to claim 14 .

16. A printed wiring board comprising an insulating layer, and a conductor layer formed on a surface of the insulating layer, wherein the insulating layer comprises the resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Kobayashi Hiroaki
• Sogame Masanobu
• Kato Yoshihiro

Classifications

• C08G59/3218

  Carbocyclic compounds · CPC title

• Y10T428/31511

  Of epoxy ether · CPC title

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title

• C08K3/36 Primary

  Silica · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title