Phosphorous-containing compounds and their preparation process and use

Patent metadata

Field	Value
Publication number	US-9527962-B2
Application number	US-201514685731-A
Country	US
Kind code	B2
Filing date	Apr 14, 2015
Priority date	Jul 2, 2008
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A series of novel phosphorus-containing compounds having the following formula is provided:

in which:
R 1 -R 4 , A, Q and m are as defined in the specification.

A process for the preparation of the compound of formula (I) is also provided. A polymer of formula (PA), and preparation process and use thereof are further provided. A polymer of formula (PI), and preparation process and use thereof are also provided.

First claim

We claim:

1. A phosphorus-containing polyamide of general formula (PA):

wherein,
A is one of —O— and

R 1 -R 4 are each selected from the group consisting of hydrogen atom, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkyl, C 3 -C 7 cycloalkyl, —CF 3 , —OCF 3 , and halogen atom,
m is an integer of 1-4,
Ar′ is selected from the group consisting of

and n is an integer of 30-300.

2. The phosphorus-containing polyamide of formula (PA) according to claim 1 , wherein when A is —O—, R 1 -R 4 are hydrogen atoms, and Ar′ is phenyl, the phosphorus-containing polyamide of formula (PA) is of formula (HPP-PA)

3. A process of preparing the phosphorus-containing polyamide of formula (PA):

wherein,
Ar′ is selected from the group consisting of

and n is an integer of 30-300;
comprising reacting a compound of formula (I) with a diacid compound of formula (IV) in a solvent to produce a phosphorus-containing polyamide of formula (PA),
HOOC—Ar′—COOH   (IV)

wherein Ar′ is defined as above, wherein in the compound of chemical formula (I) formula:

R 1 -R 4 are each selected from the group consisting of hydrogen atom, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkyl, C 3 -C 7 cycloalkyl, —CF 3 , —OCF 3 , and halogen atom;
A is one of —O— and

Q is selected from the group consisting of —NO 2 , —NH 2 ,

and

and m is an integer of 1-4.

4. The process according to claim 3 , wherein the solvent is N-methyl-pyrrolidone (NMP).

5. The process according to claim 3 , wherein calcium chloride is used in the reaction.

6. The process according to claim 3 , wherein triphenyl phosphite (TPP) is used in the reaction.

7. The phosphorus-containing polyamide of formula (PA) according to claim 1 , which is used in a flexible printed circuit board material.

Assignees

• Chang Chun Plastics Co Ltd
• Nat Univ Chung Hsing

Inventors

• Lin Ching-Hsuan
• Lin Tsung Li
• Fang yu-ting
• Hwang Kuen-Yuan
• Tu An-Pang

Classifications

• H05K1/0346

  containing N · CPC title

• C08G69/26

  derived from polyamines and polycarboxylic acids · CPC title

• C08G69/42 Primary

  Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen (C08G69/12, C08G69/32 take precedence) · CPC title

• C08G59/3254

  containing atoms other than carbon, hydrogen, oxygen or nitrogen · CPC title

• H05K1/0393

  Flexible materials (H05K1/038 takes precedence; specific organic compositions are classified in H05K1/0313 and subgroups) · CPC title