Process for the preparation of alkylene carbonate and/or alkylene glycol

Patent metadata

Field	Value
Publication number	US-9527787-B2
Application number	US-201213462490-A
Country	US
Kind code	B2
Filing date	May 2, 2012
Priority date	May 15, 2008
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.

First claim

The invention claimed is:

1. A reaction system for producing an alkylene carbonate and/or an alkylene glycol comprising:
a recycle gas loop fluidly connected to a source of alkene and oxygen, the recycle gas loop comprising an inlet and an outlet;
an epoxidation reactor comprising an epoxidation catalyst, an inlet, and an outlet, wherein the outlet of the recycle gas loop is fluidly connected to the inlet of the epoxidation reactor;
an alkylene oxide absorber comprising an iodide-containing carboxylation catalyst, an inlet, and an outlet,
wherein the outlet of the epoxidation reactor is fluidly connected to the inlet of the alkylene oxide absorber,
wherein the outlet of the alkylene oxide absorber is fluidly connected to the inlet of the recycle gas loop, and
wherein the alkylene oxide absorber is configured to produce an epoxidation recycle gas comprising iodide-containing impurities at the outlet; and

a purification vessel located in the recycle gas loop, the purification vessel comprising a purification absorbent that comprises silver, an alkali or alkaline earth metal component, and a support material having a surface area of more than 20 m 2 /g,
wherein the purification vessel is configured to reduce a quantity of iodide-containing impurities in at least a portion of the epoxidation recycle gas.

2. The reaction system of claim 1 wherein the epoxidation reactor is a shell-and-tube heat exchanger comprising a plurality of reactor tubes positioned substantially parallel to the central longitudinal axis of the epoxidation reactor;
wherein upper ends of the reactor tubes are connected to a substantially horizontal upper tube plate and lower ends of the reactor tubes are connected to a substantially horizontal lower tube plate; and
wherein the epoxidation catalyst is in the form of a packed bed positioned within the reactor tubes.

3. The reaction system of claim 1 wherein the purification absorbent is present in a packed bed and is configured to withstand a temperature in the range of from 25 to 325° C.

4. The reaction system of claim 1 wherein the alkylene oxide absorber further comprises a hydrolysis catalyst.

5. The reaction system of claim 1 further comprising:
a finishing reactor fluidly connected to the alkylene oxide absorber.

6. The reaction system of claim 5 further comprising:
a dehydrator fluidly connected to the finishing reactor.

7. The reaction system of claim 6 further comprising:
an alkylene glycol purification column fluidly connected to the dehydrator.

8. The reaction system of claim 1 further comprising:
a dehydrator fluidly connected to the alkylene oxide absorber.

9. The reaction system of claim 8 further comprising:
an alkylene glycol purification column fluidly connected to the dehydrator.

10. The reaction system of claim 1 further comprising a carbon dioxide absorber located in the recycle gas loop.

11. The reaction system of claim 10 wherein the purification vessel located in the recycle gas loop is positioned between the outlet of the alkylene oxide absorber and an inlet of the carbon dioxide absorber.

12. The reaction system of claim 1 further comprising a heat exchanger located in the recycle gas loop.

13. The reaction system of claim 12 wherein the purification vessel located in the recycle gas loop is positioned between the heat exchanger and the inlet of the epoxidation reactor.

14. The reaction system of claim 1 further comprising a water removal vessel located in the recycle gas loop.

Assignees

• Evans Wayne Errol
• Matusz Marek
• Van Kruchten Eugene Marie Godfried Andre
• Hess Martin Lysle
• Shell Oil Co

Inventors

• Evans Wayne Errol
• Matusz Marek
• Van Kruchten Eugene Marie Godfried Andre
• Hess Martin Lysle

Classifications

• B01D2253/112

  Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106 · CPC title

• B01D53/70

  Organic halogen compounds · CPC title

• C07C29/106

  of oxiranes · CPC title

• B01D2255/104

  Silver · CPC title

• C07C29/12 Primary

  of esters of mineral acids · CPC title