Non-PGM catalyst for burning carbon soot, and filtration filter and exhaust gas post-processing apparatus using the same

Patent metadata

Field	Value
Publication number	US-9527032-B2
Application number	US-201514862999-A
Country	US
Kind code	B2
Filing date	Sep 23, 2015
Priority date	Oct 10, 2011
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

The present invention provides a non-PGM catalyst for burning carbon soot without using a noble metal, the non-PGM catalyst comprising: a cerium-praseodymium complex oxide and an iron oxide, the cerium-praseodymium complex oxide impregnated with silver (Ag). The cerium-praseodymium complex oxide illustratively consists of 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 1.5 to 3.0 parts by weight of the total weight of the complex oxide. The iron oxide may be an oxide in a form of particles separate from the cerium-praseodymium complex oxide in which silver is impregnated, and may be 0.5 to 2 parts by weight of the total weight of the cerium praseodymium complex oxide.

First claim

What is claimed is:

1. A filtration filter comprising:
a plurality of through-cells formed regularly along an axial direction thereof and partitioned by cell walls,
wherein each through-cell has an inlet port and an outlet port opened in opposite directions at opposite end sides thereof, and a carbon soot burning non-PGM catalyst comprising a cerium-praseodymium complex oxide impregnated with silver (Ag) is coated on an upper surface and a lower surface of the cell wall,
wherein the cerium-praseodymium complex oxide comprises 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 0.5 to 10.0 parts by weight of the total weight of the complex oxide.

2. The filtration filter of claim 1 , wherein an iron oxide mixed with cerium-praseodymium complex oxide impregnated with silver (Ag) is together coated on the upper surface and the lower surface of the cell wall of the through-cell.

3. The filtration filter of claim 1 , wherein the through-cell further comprises a CO oxidizing catalyst for preventing generation of CO and slippage, the CO oxidizing catalyst being coated on a lower surface or an upper surface of the cell wall on which the carbon soot burning non-PGM catalyst or on an entire region of the lower surface or the upper surface of the cell wall.

4. The filtration filter of claim 1 , wherein each through-cell further comprises a CO oxidizing catalyst coated on a portion of the cell wall on a side of the outlet port.

5. The filtration filter of claim 3 , wherein a honeycombed CO oxidizing catalyst module on which the CO oxidizing catalyst is coated is further mounted to a side of the outlet port of the filtration filter.

6. An exhaust gas post-processing apparatus wherein one of a DOC (Diesel Oxidation Catalyst) module, an LNT (Lean Nox Trap) module, or a TWC (Three Way Catalyst) module is mounted to an inlet port of a filtration filter coated with a carbon soot burning non-PGM catalyst comprising a cerium-praseodymium complex oxide impregnated with silver (Ag),
wherein the cerium-praseodymium complex oxide comprises 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 0.5 to 10.0 parts by weight of the total weight of the complex oxide.

7. The exhaust gas post-processing apparatus of claim 6 , wherein the carbon soot burning non-PGM catalyst comprises an iron oxide mixed with the cerium-praseodymium complex oxide impregnated with silver (Ag).

Assignees

• Hyundai Motor Co Ltd
• Heesung Catalysts Corp

Inventors

• Choi Sung Mu
• Seo Jung Min
• Han Hyun Sik
• Kim Eun Seok
• Lee Jeong Bae

Classifications

• F01N3/035

  with catalytic reactors · CPC title

• B01D53/944 Primary

  Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts (three-way-catalysts [TWC] B01D53/9445) · CPC title

• B01D53/9477

  with catalysts positioned on separate bricks, e.g. exhaust systems · CPC title

• B01D2255/20738

  Iron · CPC title

• B01J37/0215

  Coating · CPC title