Fuel cell system with interconnect

Patent metadata

Field	Value
Publication number	US-9525181-B2
Application number	US-201313843422-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Jun 15, 2011
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

The present invention includes an integrated planar, series connected fuel cell system having electrochemical cells electrically connected via interconnects, wherein the anodes of the electrochemical cells are protected against Ni loss and migration via an engineered porous anode barrier layer.

First claim

What is claimed is:

1. A fuel cell system, comprising:
a plurality of electrochemical cells, each electrochemical cell including an Ni-containing anode, a cathode spaced apart from the anode, and an electrolyte disposed between and in contact with both the anode and the cathode, wherein each anode is formed of a material that includes Ni; and
a plurality of interconnects, each interconnect being configured to conduct free electrons between electrochemical cells;
a substrate supporting the electrochemical cells; and
a first porous anode barrier comprising Ni and disposed between each anode and the substrate, wherein the first porous anode barrier is not an active component of the electrochemical cells; and wherein the first porous anode barrier is configured to provide sacrificial Ni during operation of the fuel cell system to prevent Ni migration in the anode.

2. The fuel cell system of claim 1 , wherein the Ni in the anode is in the form of NiO; and Ni in the first porous anode barrier is in the form of NiO.

3. The fuel cell system of claim 2 , wherein the NiO content of the first porous anode barrier is less than approximately 30% by weight.

4. The fuel cell system of claim 1 , wherein the electrochemical cells are configured as a segmented-in-series arrangement.

5. The fuel cell system of claim 1 , wherein each electrochemical cell further comprises a cathode current collector and an anode current collector, wherein at least a portion of the anode current collector is vertically disposed between the anode and the first porous anode barrier and contacts both the anode and the first porous anode barrier.

6. The fuel cell system of claim 5 , further comprising a plurality of ceramic seals, wherein at least one ceramic seal is disposed horizontally adjacent to each of both sides of the at least a portion of each anode current collector.

7. The fuel cell system of claim 6 , wherein the first porous anode barrier is in the form of segments, at least one such segment for each electrochemical cell; further comprising a second porous anode barrier having a different composition than the first porous anode barrier; wherein the second porous anode barrier is also in the form of segments; wherein at least one segment of the second porous anode barrier is disposed horizontally adjacent to each of both sides of each segment of the first porous anode barrier; and wherein only segments of the first porous anode barrier are disposed vertically below the anode of each electrochemical cell.

8. The fuel cell system of claim 5 , wherein the first porous anode barrier is disposed vertically between each ceramic seal and the substrate, and is disposed vertically between each anode current collector and the substrate.

9. The fuel cell system of claim 5 , wherein the first porous anode barrier is in the form of segments, at least one such segment for each electrochemical cell; further comprising a plurality of ceramic seals, wherein at least one ceramic seal is disposed horizontally adjacent to each of both sides of the first porous anode barrier segment of each electrochemical cell.

10. The fuel cell system of claim 9 , further comprising a second porous anode barrier having a different composition than the first porous anode barrier; wherein the second porous anode barrier is disposed vertically between the substrate and electrochemical cells.

11. The fuel cell system of claim 1 , wherein the first porous anode barrier is configured to deliver fuel to the anode.

12. The fuel cell system of claim 11 , further comprising a second porous anode barrier having a different composition in the first porous anode barrier, wherein the second porous anode barrier is configured to deliver fuel to the anode.

13. The fuel cell system of claim 12 , further comprising an anode current collector, wherein the anode current collector is configured to deliver fuel to the anode.

14. The fuel cell system of claim 1 , wherein the fuel cell system is configured for external reforming, and is configured to avoid on-cell reforming.

15. A fuel cell system, comprising:
a plurality of electrochemical cells in the form of solid oxide fuel cells, each electrochemical cell including an anode; and
a plurality of barriers configured to provide sacrificial Ni for preventing and/or reducing Ni migration from the anodes during operation of the fuel cell system, the barriers disposed in a flowpath of a fuel to the anodes.

16. The fuel cell system of claim 15 , wherein the plurality of barriers comprise a mixture of NiO—YSZ.

17. The fuel cell system of claim 16 , wherein the NiO content of the plurality of barriers is less than approximately 30% by weight.

18. The fuel cell system of claim 15 , wherein the plurality of barriers are configured to form Ni hydroxide vapor phase.

19. The fuel cell system of claim 15 , wherein each of the plurality of barriers is a porous layer configured to provide fuel to the anode.

20. A method of making a fuel cell system, comprising:
forming a plurality of electrochemical cells, each electrochemical cell including an anode; and
forming a porous layer configured to supply fuel to the anode and to provide sacrificial Ni to protect the anode from Ni migration during operation of the fuel cell system,
wherein the porous layer is formed such that it is upstream of the electrochemical cells in a flowpath of a fuel to each anode.

21. A fuel cell system, comprising:
a plurality of electrochemical cells, each electrochemical cell including an Ni-containing anode, a cathode spaced apart from the anode, and an electrolyte disposed between and in contact with both the anode and the cathode, wherein each anode is formed of a material that includes Ni; and wherein reactions take place during operation of the fuel cell system that have a propensity to react with Ni in each anode and result in Ni migration in each anode; and
a plurality of interconnects, each interconnect being configured to conduct free electrons between electrochemical cells;
a substrate supporting the electrochemical cells; and
a first porous anode barrier disposed between each anode and the substrate, wherein the first porous anode barrier is not an active component of the electrochemical cells; and wherein the first porous anode barrier is configured to provide sacrificial Ni during operation of the fuel cell system to prevent Ni migration in the anode,
wherein the reactions include Ni reacting with steam to form Ni hydroxide vapor phase.

22. The fuel cell system of claim 21 , wherein the first porous anode barrier is configured to react with steam to form Ni hydroxide vapor phase.

Assignees

• Lg Fuel Cell Systems Inc

Inventors

• Liu Zhien
• Goettler Richard

Classifications

• Y02E60/525

  Cross-Sectional Technologies · mapped topic

• H01M8/0243

  in the form of mixtures · CPC title

• H01M8/1286 Primary

  Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports · CPC title

• H01M8/2425 Primary

  High-temperature cells with solid electrolytes · CPC title

• H01M8/0236

  Glass; Ceramics; Cermets · CPC title