Organic electroluminescent element and organic electroluminescent device

Patent metadata

Field	Value
Publication number	US-9525009-B2
Application number	US-201414273992-A
Country	US
Kind code	B2
Filing date	May 9, 2014
Priority date	Nov 11, 2011
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

The objection of invention is to provide an organic electroluminescent element having an excellent current-voltage property. The organic electroluminescent element of the invention comprises an anode, a light emitting layer and a cathode, in this order, wherein a total number of kinds of an electron transport material and a light emitting material contained in the light emitting layer is five or more. Preferably, a total number of kinds of an electron transport material contained in the light emitting layer is four or more, and at least one of an ionization potential and an electron affinity of three kinds or more of the electron transport materials contained in the light emitting layer is different from each other.

First claim

The invention claimed is:

1. An organic electroluminescent element comprising an anode, a light-emitting layer and a cathode, in this order, wherein
a total number of kinds of a charge transport material and a light-emitting material contained in the light-emitting layer is 5 or more, and a total number of kinds of the charge transport material contained in the light-emitting layer is 3 or more,
wherein the charge transport material has a molecular weight of 10,000 or less,
wherein the charge transport material comprises a hole transport material and an electron transport material and wherein the electron transport material comprises at least one of the following ring structures:

wherein each of the rings are with an aromatic ring group at an o-position and a p-position relative to the nitrogen atom in the ring.

2. The organic electroluminescent element according to claim 1 , wherein the total number of kinds of the charge transport material contained in the light-emitting layer is 4 or more.

3. The organic electroluminescent element according to claim 1 , wherein the light-emitting layer contains three or more kinds of charge transport materials that differ in at least one value of ionization potential and electron affinity.

4. The organic electroluminescent element according to claim 1 , which has at least one combination satisfying a relationship where, when two kinds of the charge transport materials contained in the light-emitting layer are arbitrarily selected, at least one of ionization potential difference and electron affinity difference between the charge transport materials is 0.30 eV or less.

5. The organic electroluminescent element according to claim 1 , which has at least two combinations each satisfying a relationship where, when two kinds of the charge transport materials contained in the light-emitting layer are arbitrarily selected, at least one of ionization potential difference and electron affinity difference between the charge transport materials is 0.30 eV or less.

6. The organic electroluminescent element according to claim 1 , which has at least two combinations each satisfying a relationship where, when two kinds of the charge transport materials contained in the light-emitting layer are arbitrarily selected, at least one of ionization potential difference and electron affinity difference between the charge transport materials is 0.20 eV or less.

7. The organic electroluminescent element according to claim 1 , which has at least three combinations each satisfying a relationship where, when two kinds of the charge transport materials and the light-emitting materials contained in the light-emitting layer are arbitrarily selected, at least one of ionization potential difference and electron affinity difference between the selected materials is 0.20 eV or less.

8. An organic electroluminescent device comprising two or more organic electroluminescent elements each emitting light in a different color, which comprises one or more organic electroluminescent elements of claim 1 .

9. An organic electroluminescent device comprising two or more organic electroluminescent elements each emitting light in a different color, wherein the two or more organic electroluminescent elements are composed of only the organic electroluminescent element of claim 1 .

10. An organic EL display using the organic electroluminescent device of claim 8 .

11. An organic EL lighting using the organic electroluminescent device of claim 8 .

12. An organic EL display using the organic electroluminescent device of claim 9 .

13. An organic EL lighting using the organic electroluminescent device of claim 9 .

14. The organic electroluminescent element according to claim 1 , wherein the charge transport material has a molecular weight of 5,000 or less.

15. The organic electroluminescent element according to claim 1 , wherein the charge transport material has a molecular weight of 3,000 or less.

16. The organic electroluminescent element according to claim 1 , wherein the charge transport material has a molecular weight of 100 to 10,000.

17. The organic electroluminescent element according to claim 14 , wherein the charge transport material has a molecular weight of 200 to 5,000.

18. The organic electroluminescent element according to claim 15 , wherein the charge transport material has a molecular weight of 400 to 3,000.

19. The organic electroluminescent element according to claim 1 , wherein the hole transport material comprises a structure containing a hetero atom with an sp 3 orbital, or an aromatic condensed ring having a carbon number of 4n, and the electron transport material is a material including a monocyclic ring or a condensed ring that contains a hetero atom with an sp 2 hybrid orbital.

20. The organic electroluminescent element according to claim 1 , wherein the hole transport material comprises at least one of the following ring structures:

wherein each ring structure is optionally substituted.

21. The organic electroluminescent element according to claim 1 , wherein the hole transport material is a compound of formula (E):

wherein Xe 1 , Xe 2 , Ye 1 , Ye 2 , Ze 1 and Ze 2 each independently represent an aromatic hydrocarbon group having from 6 to 30 carbon atoms and optionally having a substituent, or an aromatic heterocyclic group having from 3 to 30 carbon atoms and optionally having a substituent; Xe 3 , Ye 3 and Ze 3 each independently represent a hydrogen atom, an aromatic hydrocarbon group having from 6 to 30 carbon atoms and optionally having a substituent, or an aromatic heterocyclic group having from 3 to 30 carbon atoms and optionally having a substituent.

22. The organic electroluminescent element according to claim 1 , wherein the light-emitting layer comprises a compound group α comprising two or more compounds each having a basic skeleton of multiple aromatic rings bonding to each other and having a molecular weight of 2000 or less wherein the compound group α comprises a compound α1 in which the number of the aromatic ring groups constituting the basic skeleton is the smallest, and any other compound of which at least 50% of the basic skeleton is the same as that of the compound α1.

Assignees

• Mitsubishi Chem Corp

Inventors

• Tanaka Futoshi
• Imada Ichiro
• Gorohmaru Hideki

Classifications

• H10K59/80

  Constructional details · CPC title

• H10K59/30

  Devices specially adapted for multicolour light emission · CPC title

• H10K50/00 Primary

  Organic light-emitting devices (integrated devices or assemblies of multiple devices H10K59/00, H10K65/00; organic semiconductor lasers H01S5/36) · CPC title

• H01L51/5004

  Electricity · mapped topic

• H01L51/0052

  Electricity · mapped topic