Polyamide 12 composition containing carbon nanotubes

Patent metadata

Field	Value
Publication number	US-9524807-B2
Application number	US-201113882799-A
Country	US
Kind code	B2
Filing date	Oct 31, 2011
Priority date	Nov 5, 2010
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

A polyamide composition contains the following components: (a) at least 40 parts by weight PA12; (b) 0.1-15 parts by weight of at least one salt with a non-metallic cation; (c) 0.1-25% by weight of at least one dispersant based on esters or amides; (d) a quantity of carbon nanotubes that produces in the molding compound a specific surface resistance according to IEC standard 60167 of maximum 10 −1 -10 10 Ω; (e) 0-5 parts by weight of at least one metal salt; and optionally (f) conventional auxiliary substances and additives, the sum of the parts by weight of components (a) to (f) amounting to 100. The polyamide composition can be used for manufacturing moldings with improved electrical conductivity and improved surface quality.

First claim

The invention claimed is:

1. A polyamide composition, comprising:
a) at least 40 parts by weight of PA12;
b) from 0.1 to 15 parts by weight of at least one salt comprising a nonmetallic cation;
c) from 0.1 to 25 parts by weight of at least one dispersant based on esters or amides;
d) carbon nanotubes in an amount sufficient to give a specific surface resistance in accordance with IEC 60167 of from 10 −1 to 10 10 Ω;
e) from 0 to 5 parts by weight of at least one metal salt; and
f) optionally customary auxiliaries and additives,
with respect to a total of 100 parts by weight of a) to f),
wherein the nonmetallic cation of the at least one salt b) consists of a quaternary nitrogen compound.

2. The polyamide composition according to claim 1 , wherein the polyamide composition comprises from 1 to 10 parts by weight of the carbon nanotubes.

3. The polyamide composition according to claim 1 ,
wherein a specific volume resistance of the polyamide composition in accordance with IEC 60093 is not more than 10 9 Ωm.

4. The polyamide composition according to claim 1 ,
wherein the non-metallic cation has formula (1) or (2):
R 1 R 2 R 3 R 4 N +   (1)

R 1 R 2 N + ═CR 3 R 4   (2)

where
R 1 , R 2 , R 3 , and R 4 are independently selected from the group consisting of hydrogen, a linear or branched or double bond-containing aliphatic hydrocarbon radical having from 1 to 30 carbon atoms or a saturated or unsaturated cycloaliphatic hydrocarbon radical having from 5 to 40 carbon atoms, an aromatic hydrocarbon radical having from 6 to 40 carbon atoms, an alkylaryl radical having from 7 to 40 carbon atoms, a linear or branched and optionally unsaturated aliphatic hydrocarbon radical which has from 2 to 30 carbon atoms and is interrupted by a radical containing one or more heteroatoms, a linear or branched or double bond-containing aliphatic hydrocarbon radical which has from 2 to 30 carbon atoms and is interrupted by one or more functions selected from the group consisting of —O—C(O)—, —(O)C—O—, —NH—C(O)—, —(O)C—NH, —(CH 3 )N—C(O)—, —(O)C—N(CH 3 )—, —S(O 2 )—O—, —O—S(O 2 )—, —S(O 2 )—NH—, —NH—S(O 2 )—, —S(O 2 )—N(CH 3 )—, —N(CH 3 )—S(O 2 )—, and a linear or branched or double bond-containing aliphatic or cycloaliphatic hydrocarbon radical which has from 1 to 30 carbon atoms and is terminally functionalized by —OH, —OR′, —NH 2 , —N(H)R′, —N(R′) 2 or a polyether —(R 5 —O) n —R 6 having a block or random structure,
where
R′ is a saturated or unsaturated C 1 -C 30 -alkyl radical,
R 5 is a linear or branched hydrocarbon radical comprising from 2 to 4 carbon atoms,
n is from 1 to 100, and
R 6 is hydrogen, a linear or branched or double bond-containing aliphatic hydrocarbon radical having from 1 to 30 carbon atoms, or a saturated or double bond-containing cycloaliphatic hydrocarbon radical having from 5 to 40 carbon atoms, an aromatic hydrocarbon radical having from 6 to 40 carbon atoms or an alkylaryl radical having from 7 to 40 carbon atoms or a radical —C(O)—R 7 ,
where
R 7 is a linear or branched or double bond-containing aliphatic hydrocarbon radical having from 1 to 30 carbon atoms, a double bond-containing cycloaliphatic hydrocarbon radical having from 5 to 40 carbon atoms, an aromatic hydrocarbon radical having from 6 to 40 carbon atoms, or an alkylaryl radical having from 7 to 40 carbon atoms.

5. The polyamide composition according to claim 1 ,
wherein the at least one dispersant c) is selected from the group consisting of
c1) a polyacrylic ester, which is prepared by a process comprising: esterifying an alkyl polyacrylate comprising an alkyl radical comprising from 1 to 3 carbon atoms, with
at least one of a saturated and an unsaturated aliphatic alcohol comprising from 4 to 50 carbon atoms in such an amount that from 30 to 100% of ester groups are transesterified; and
c2) a polyester-polyamine condensation product, which is obtained by a process comprising: partially or completely reacting one or more amino-functional polymers comprising at least four amino groups with one or more polyesters of formula (I) or (Ia)
T-C(O)—[O-A-C(O)] x —OH  (I)

T-O—[C(O)-A-O—] y —Z  (Ia)

and one or more polyethers of formula (II) or (IIa)
T-C(O)—B—Z  (II)

T-O—B—Z  (IIa)

wherein
T is at least one of a hydrogen radical and an optionally substituted, linear or branched aryl, arylalkyl, alkyl or alkenyl radical comprising from 1 to 24 carbon atoms;
A is at least one divalent radical selected from the group consisting of a linear, a branched, a cyclic and an aromatic hydrocarbon;
Z is at least one radical selected from the group consisting of a sulphonic acid, a sulphuric acid, a phosphonic acid, a phosphoric acid, a carboxylic acid, an isocyanate, and an epoxide;
B is a radical of formula (III)
—(C l H 2l O) a —(C m H 2m O) b —(C n H 2n O) c —(SO) d —  (III)

wherein
SO is —CH 2 —CH(Ph)-O—, wherein Ph is a phenyl radical,
a,b,c each is independently a number of from 0 to 100,
d is ≧0, with the proviso that a+b+c+d is >0, and
l,m,n each is independently a number ≧2; and
x,y each is independently a number ≧2.

6. The polyamide composition according to claim 1 , wherein
the at least one metal salt e) is an alkali metal salt, an alkaline earth metal salt or a zinc salt.

7. A moulding, comprising:
the polyamide composition according to claim 1 .

8. The polyamide composition according to claim 1 , wherein the non-metallic cation of the at least one salt b) consists of acyclic quaternary ammonium.

9. The polyamide composition according to claim 1 , wherein the carbon nanotubes comprise tubes formed by a plurality of graphic layers.

10. The polyamide composition according to claim 1 , wherein the carbon nanotubes have a diameter of from 0.003 to 0.5 μm.

11. The polyamide composition according to claim 1 , wherein the carbon nanotubes have a length of from 0.5 to 1000 μm.

12. The polyamide composition according to claim 1 , wherein the polyamide composition comprises the customary auxiliaries and additives of f), and the customary auxiliaries and additives of f) comprises a plasticizer.

13. The polyamide composition according to claim 1 , wherein the polyamide composition comprises from 2 to 8 parts by weight of the carbon nanotubes.

14. The polyamide composition according to claim 1 , wherein the polyamide composition comprises from 2.5 to 6 parts by weight of the carbon nanotubes.

Assignees

• Hermasch Sylvia Anita
• Wursche Roland
• Haeger Harald
• Poetschke Petra
• Krause Beate
• Socher Robert
• Evonik Degussa Gmbh

Inventors

• Hermasch Sylvia Anita
• Wursche Roland
• Haeger Harald
• Poetschke Petra
• Krause Beate
• Socher Robert

Classifications

• C08K7/24

  inorganic · CPC title

• C08L71/02

  Polyalkylene oxides · CPC title

• C08L77/02 Primary

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L33/08

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title