Toner, developer and image forming apparatus

Patent metadata

Field	Value
Publication number	US-9523931-B2
Application number	US-201414168172-A
Country	US
Kind code	B2
Filing date	Jan 30, 2014
Priority date	Feb 5, 2013
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

To provide a toner, which contains silica particles containing first silica particles, and second silica particles, wherein the toner is a toner produced by depositing the silica particles on surfaces of base particles, the first silica particles have an average primary particle diameter of 75 nm to 250 nm, the second silica particles have an average primary particle diameter of 10 nm to 50 nm, a mass ratio of the first silica particles to the base particles is 0.010 to 0.040, a mass ratio of the second silica particles to the base particles is 0.005 to 0.030, a liberation ratio of the silica particles from the toner by a ultrasonic vibration method is 5% by mass to 20% by mass, and an amount of particles having primary particle diameters of 30 nm or smaller in the silica particles librated from the toner by the ultrasonic vibration method is 20% by number or less.

First claim

What is claimed is:

1. A toner, comprising:
toner base particles; and
silica particles comprising first silica particles, and second silica particles,
wherein the base particles comprise a crystalline polyester,
wherein the first silica particles have an average primary particle diameter of 78 nm to 250 nm,
wherein the second silica particles have an average primary particle diameter of 19 nm to 50 nm,
wherein a mass ratio of the first silica particles to the base particles is 0.011 to 0.038,
wherein a mass ratio of the second silica particles to the base particles is 0.006 to 0.028,
wherein a liberation ratio of the silica particles from the toner by an ultrasonic vibration method is 5% by mass to 15% by mass, relative to the total mass of the silica on the toner base particles, and
wherein an amount of particles having primary particle diameters of 30 nm or smaller in the silica particles liberated from the toner by the ultrasonic vibration method is 6% by number to 20% by number, relative to the total number of liberated silica particles from the toner.

2. The toner according to claim 1 , wherein the amount of particles having primary particle diameters of 30 nm or smaller in the silica particles liberated from the toner by the ultrasonic vibration method is from 6% by number to 15% by number, relative to the total number of liberated silica particles from the toner.

3. The toner according to claim 1 , wherein the first silica particles have the average primary particle diameter of 120 nm to 200 nm.

4. The toner according to claim 1 , wherein the second silica particles have the average primary particle diameter of 20 nm to 40 nm.

5. The toner according to claim 1 , wherein the base particles are produced by granulating in an aqueous medium.

6. The toner according to claim 1 , wherein the base particles comprise a urea-modified polyester.

7. The toner according to claim 1 , wherein the second silica particles have an average primary particle diameter of 40 nm to 50 nm.

8. The toner according to claim 1 , wherein a mass ratio of the second silica particles to the base particles is 0.010 to 0.020.

9. A developer, comprising:
a toner according to claim 1 ; and
a carrier.

10. The developer according to claim 9 , wherein the amount of particles having primary particle diameters of 30 nm or smaller in the silica particles liberated from the toner by the ultrasonic vibration method is from 6% by number to 15% by number, relative to the total number of liberated silica particles from the toner.

11. The developer according to claim 9 , wherein the first silica particles have the average primary particle diameter of 120 nm to 200 nm.

12. The developer according to claim 9 , wherein the second silica particles have the average primary particle diameter of 20 nm to 40 nm.

13. The developer according to claim 9 , wherein the base particles are produced by granulating in an aqueous medium.

14. The developer according to claim 9 , wherein the base particles comprise a urea-modified polyester.

Assignees

• Kojima Satoshi
• Awamura Junichi
• Nagatomo Tsuneyasu
• Sakashita Shingo
• Murayama Tomoki
• Fukuda Masaya
• Ricoh Co Ltd

Inventors

• Kojima Satoshi
• Awamura Junichi
• Nagatomo Tsuneyasu
• Sakashita Shingo
• Murayama Tomoki
• Fukuda Masaya

Classifications

• G03G9/08755

  Polyesters · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/0804 Primary

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/09725

  Silicon-oxides; Silicates · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title