Asphaltene stabilization in petroleum feedstocks by blending with biological source oil and/or chemical additive

Patent metadata

Field	Value
Publication number	US-9523054-B2
Application number	US-201414464210-A
Country	US
Kind code	B2
Filing date	Aug 20, 2014
Priority date	Aug 21, 2013
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent problematic issues caused by the asphaltenes, such as sludges, plugging, deposits, fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.

First claim

What is claimed is:

1. A method for stabilizing asphaltenes in a petroleum feedstock comprising:
adding to the petroleum feedstock containing asphaltenes an effective amount to improve the stability of asphaltenes in the petroleum feedstock of:
at least one biological source oil, where the biological source oil is selected from the group consisting of algae oils, fish oils, krill oils, flaxseed oils, biocrude, and mixtures thereof; and
at least one chemical additive to improve the stability of asphaltenes in the petroleum feedstock, where the chemical additive is selected from the group consisting of:
alkylphenol-based resins, where the alkyl group is selected from the group consisting of octyl, nonyl, and dodecyl, where an alkylphenol is reacted with an aldehyde in the presence of a sulphonic acid, where the alkyl-phenol based resins are used alone or in conjunction with amines,
long chain alpha-olefins having more than 20 carbon atoms reacted with an aldehyde,
long chain alkyl phenate sulfides having from 8 to 40 carbon atoms reacted with polyolefins,
metal oxide-based colloidal hydrocarbon-based nanodispersions, and
combinations of these chemical additives;

where the asphaltenes are synergistically stabilized in the petroleum feedstock which is defined as to an extent that is greater than the additive of:
the stabilizing achieved with only the same amount of the biological source oil used separately, added to
the stabilizing achieved with only the same amount of the chemical additive used separately.

2. The method of claim 1 where the petroleum feedstock is selected from the group consisting of crude oils, heavy oils, coker feedstocks, visbreaker feedstocks, vacuum tower bottoms, fuel oils, diesel oils, bunker fuel oils, and mixtures thereof.

3. The method of claim 1 where the effective amount of biological source oil ranges from about 0.01 wt % to about 99 wt %, and the effective amount of the chemical additive ranges from about 0.05 wt % to about 99 wt %, both based on the amount of petroleum feedstock.

4. The method of claim 1 where the biological source oil is algae oil.

5. A method for stabilizing asphaltenes in a petroleum feedstock comprising:
evaluating the petroleum feedstock for asphaltene stability;
when the petroleum feedstock exhibits asphaltene instability, preparing a plurality of blends, where each blend has a different proportion ratio of the petroleum feedstock to at least one biological source oil and at least one chemical additive, where the biological source oil and a chemical additive is the same in each blend; and
evaluating each blend for asphaltene stability by selecting the blend that best improves the asphaltene stability of the petroleum feedstock in the blend;

where the biological source oil is selected from the group consisting of algae oils, fish oils, krill oils, flaxseed oils, biocrude and mixtures thereof; and
where the chemical additive is selected from the group consisting of:
alkylphenol-based resins, where the alkyl group is selected from the group consisting of octyl, nonyl, and dodecyl, where an alkylphenol is reacted with an aldehyde in the presence of a sulphonic acid, where the alkyl-phenol based resins are used alone or in conjunction with amines,
long chain alpha-olefins having more than 20 carbon atoms reacted with an aldehyde,
long chain alkyl phenate sulfides having from 8 to 40 carbon atoms reacted with polyolefins,
metal oxide-based colloidal hydrocarbon-based nanodispersions.

6. The method of claim 5 where the method further comprises a method for specifying a minimum amount of biological source oil required to decrease process equipment fouling due to asphaltene destabilization.

7. The method of claim 5 where the petroleum feedstock is selected from the group consisting of crude oils, heavy oils, coker feedstocks, visbreaker feedstocks, vacuum tower bottoms, fuel oils, diesel oils, bunker fuel oils, and mixtures thereof.

8. The method of claim 5 where the amount of biological source oil and the amount of chemical additive in each blend ranges from about 0.01 wt % to about 99 wt %, based on the amount of petroleum feedstock.

9. The method of claim 5 where the blends comprise both a biological source oil and a chemical additive, and where the asphaltenes are synergistically stabilized in the petroleum feedstock which is defined as to an extent that is greater than the additive of:
the stabilizing achieved with only the same amount of the biological source oil used separately, added to
the stabilizing achieved with only the same amount of the chemical additive used separately.

10. The method of claim 9 where:
the biological source oil is algae oil; and
the at least one chemical additive is an alkylphenol-based resins, where the alkyl group is selected from the group consisting of octyl, nonyl, and dodecyl, and derivatives of these alkylphenol-based resins, where an alkylphenol is reacted with an aldehyde in the presence of a sulphonic acid, where the alkyl-phenol based resins are used in conjunction with triethylenetetramine (TETA).

11. A method for stabilizing asphaltenes in a petroleum feedstock comprising:
adding to the petroleum feedstock containing asphaltenes an effective amount to improve the stability of asphaltenes in the petroleum feedstock of:
at least one biological source oil that is an algae oil; and
at least one chemical additive to improve the stability of asphaltenes in the petroleum feedstock, where the chemical additive is an alkylphenol-based resins, where the alkyl group is selected from the group consisting of octyl, nonyl, and dodecyl, where an alkylphenol is reacted with an aldehyde in the presence of a sulphonic acid, where the alkyl-phenol based resins are used alone or in conjunction with amines;

where the asphaltenes are synergistically stabilized in the petroleum feedstock which is defined as to an extent that is greater than the additive of:
the stabilizing achieved with only the same amount of the biological source oil used separately, added to
the stabilizing achieved with only the same amount of the chemical additive used separately.

12. The method of claim 11 where the petroleum feedstock is selected from the group consisting of crude oils, heavy oils, coker feedstocks, visbreaker feedstocks, vacuum tower bottoms, fuel oils, diesel oils, bunker fuel oils, and mixtures thereof.

13. The method of claim 11 where the effective amount of biological source oil ranges from about 0.01 wt % to about 99 wt %, and the effective amount of the chemical additive ranges from about 0.05 wt % to about 99 wt %, both based on the amount of petroleum feedstock.

14. A method for stabilizing asphaltenes in a petroleum feedstock comprising:
adding to the petroleum feedstock containing asphaltenes an effective amount to improve the stability of asphaltenes in the petroleum feedstock of:
at least one biological source oil that is an algae oil; and
at least one chemical additive to improve the stability of asphaltenes in the petroleum feedstock, where the chemical additive is an alkylphenol-based resins, where the alkyl group is selected from the group consisting of octyl, nonyl, and dodecyl, where an alkylphenol is reacted with an aldehyde in the presence of a sulphonic acid, where the alkyl-phenol based resins are used in conjunction with triethylenetetramine (TETA).

15. The method of claim 14 where the asphaltenes are synergistically stabilized in the petroleum feedstock which is defined as to an extent that is greater than the additive of:
the stabilizing achieved with only

Assignees

• Baker Hughes Inc

Inventors

• Pinappu Sai Reddy
• Kremer Lawrence N
• Sandu Corina L

Classifications

• C10L1/1802 Primary

  natural products, e.g. waxes, extracts, fatty oils · CPC title

• C10G2300/1055

  Diesel having a boiling range of about 230 - 330 °C · CPC title

• C10G29/22 Primary

  containing oxygen as the only hetero atom · CPC title

• C10G75/04

  by addition of antifouling agents · CPC title

• C10G2300/206

  Asphaltenes · CPC title