Process, method, and system for removing heavy metals from fluids

Patent metadata

Field	Value
Publication number	US-9523043-B2
Application number	US-201414481265-A
Country	US
Kind code	B2
Filing date	Sep 9, 2014
Priority date	Sep 16, 2013
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

Mercury in distilled products from a distillation column is removed and extracted as soluble mercury compounds with the injection of a complexing agent into the overhead sections of the column. Examples of complexing agents include polysulfides such as sodium polysulfide or ammonium polysulfide. In one embodiment, the complexing agent is injected into the inlet pipe just before the overhead condenser, converting the volatile elemental mercury into a species that is soluble in the sour water stream that collected in the overhead sections.

First claim

The invention claimed is:

1. A process for reducing mercury content from a crude distillation unit comprising a distillation column and an overhead condenser, the process comprising:
fractionally distilling a crude product containing at least 50 ppbw mercury to form overhead vapor fractions comprising light naphtha having a first concentration of mercury;
adding a sufficient amount of at least one of an ammonium hydroxide and an amine to the overhead fractions for a pH level of at least 7;
contacting the overhead vapor fractions with a complexing agent to convert at least a portion of the mercury into water soluble mercury in solution, for a light naphtha product having a reduced concentration of mercury; and
removing the solution containing water soluble mercury from the crude distillation unit; recovering the light naphtha product from an upper section of the distillation column.

2. The process according to claim 1 wherein the complexing agent is selected from inorganic polysulfides and organic polysulfides.

3. The process according to claim 2 , wherein the complexing agent is selected from sodium polysulfide and ammonium polysulfide.

4. The process according to claim 2 , wherein the overhead vapor fractions is brought into contact with a complexing agent at a sulfur-to-mercury stoichiometric ratio of from 1 to 100,000.

5. The process according to claim 4 , wherein the overhead vapor fractions is brought into contact with a complexing agent at a sulfur-to-mercury stoichiometric ratio is from 10 to 10.000.

6. The process according to claim 5 , wherein the overhead vapor fractions is brought into contact with a complexing agent at a sulfur-to-mercury ratio is from 50 to 5,000.

7. The process according to claim 1 , wherein the overhead vapor fractions is brought into contact with the complexing agent by injecting the complexing agent into an inlet pipe before the overhead condenser.

8. The process according to claim 1 , wherein the overhead vapor fractions is brought into contact with the complexing agent by injecting the complexing agent into any of: directly into the overhead condenser; an overhead vapor line near the distillation column.

9. The process of claim 1 , wherein the overhead vapor fractions is brought into contact with the complexing agent in a contactor located in between the distillation column and the overhead condenser.

10. The process of claim 1 , wherein the reduced concentration of mercury in the light naphtha product is less than 10 ppbw.

11. The process of claim 1 , wherein the reduced concentration of mercury in the light naphtha product is at least 10% less than the first concentration of mercury.

12. The process of claim 11 , wherein the reduced concentration of mercury in the light naphtha product is at least 25% less than the first concentration of mercury.

13. The process of claim 12 , wherein the reduced concentration of mercury in the light naphtha product is at least 50% less than the first concentration of mercury.

14. The process of claim 1 , wherein the complexing agent is injected into at least one of: a) an inlet pipe before the overhead condenser; and b) directly into the overhead condenser, for the solution containing water soluble mercury to be withdrawn as a sour water stream containing at least 10% of the mercury in the crude product.

15. The process of claim 14 , wherein sour water stream contains at least 25% of the mercury in the crude product.

16. The process of claim 15 , wherein the sour stream contains at least 50% of the mercury in the crude product.

17. The process of claim 14 , further comprising removing mercury from the sour water by at least one of adsorption, complexation with biological organisms, precipitation and combinations thereof.

18. The process of claim 1 , wherein the mercury in the crude product is predominantly non-volatile.

19. The process of claim 1 , wherein the mercury in the crude product is particulate.

Assignees

• O'Rear Dennis John
• Cooper Russell Evan
• Chevron Usa Inc

Inventors

• O'Rear Dennis John
• Cooper Russell Evan

Classifications

• C10G29/28

  containing sulfur as the only hetero atom, e.g. mercaptans, or sulfur and oxygen as the only hetero atoms · CPC title

• C10G29/10

  Sulfides · CPC title

• C10G29/02 Primary

  Non-metals · CPC title

• C10G7/00 Primary

  Distillation of hydrocarbon oils · CPC title

• C10G2300/205

  Metal content · CPC title