Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced optical properties

Patent metadata

Field	Value
Publication number	US-9522517-B2
Application number	US-201414563364-A
Country	US
Kind code	B2
Filing date	Dec 8, 2014
Priority date	Dec 8, 2014
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

Resin compositions, layers, and interlayers comprising two or more thermoplastic polymers and at least one RI balancing agent for adjusting the refractive index of at least one of the resins or layers is provided. Such compositions, layers, and interlayers exhibit enhanced optical properties while retaining other properties, such as impact resistance and acoustic performance.

First claim

What is claimed is:

1. An interlayer comprising:
a first resin layer comprising a first poly(vinyl acetal) resin and a first plasticizer; and
a second resin layer adjacent to said first resin layer, wherein said second resin layer comprises a second poly(vinyl acetal) resin and a second plasticizer,
wherein at least one of said first poly(vinyl acetal) resin and said second poly(vinyl acetal) resin comprises residues of an aldehyde having a refractive index of at least 1.421, and wherein the haze value of said interlayer is less than 5 percent, and
wherein the difference between the residual hydroxyl content of said first poly(vinyl acetal) resin and the residual hydroxyl content of said second poly(vinyl acetal) resin is at least 2 weight percent and wherein at least one of said first and said second resin layers has a glass transition temperature less than 25° C.

2. The interlayer of claim 1 , wherein said residues of an aldehyde having a refractive index of at least 1.421 comprise residues of at least one aromatic compound, wherein said first or said second poly(vinyl acetal) resin comprise at least 0.5 weight percent of said residues having a refractive index of at least 1.421, based on the total weight of aldehyde residues of said first or said second poly(vinyl acetal) resin.

3. The interlayer of claim 1 , wherein said second resin layer further comprises another poly(vinyl acetal) resin blended with said second poly(vinyl acetal) resin to form a blended resin layer, wherein said another poly(vinyl acetal) resin comprises residues of said aldehyde having a refractive index of less than 1.421, wherein said second poly(vinyl acetal) resin is present in said blended resin layer in an amount of at least 0.5 weight percent, based on the total weight of said second poly(vinyl acetal) resin and said another poly(vinyl) acetal resin.

4. The interlayer of claim 1 , wherein said second poly(vinyl acetal) resin further comprises residues of at least one aldehyde having a refractive index of less than 1.421, wherein said second poly(vinyl acetal) resin comprises at least about 0.5 weight percent of said residues of said aldehyde having a refractive index of at least 1.421, based on the total weight of aldehyde residues of said second poly(vinyl acetal) resin.

5. The interlayer of claim 1 , wherein at least one of said first and said second poly(vinyl acetal) resins comprises residues of an aldehyde selected from the group consisting of n-butyraldehyde, iso-butyraldehyde, 2-ethylhexaldehyde, and combinations thereof.

6. The interlayer of claim 1 , wherein at least one of said first and said second poly(vinyl acetal) resins has a residual acetate content of at least 5 weight percent.

7. The interlayer of claim 1 , wherein at least one of said first and said second poly(vinyl acetal) resins has a residual hydroxyl content of at least 16 weight percent and the other of said first and said second poly(vinyl acetal) resins has a residual hydroxyl content of not more than 15 weight percent, wherein the difference between the glass transition temperature of said first resin layer and the glass transition temperature of said second resin layer is at least 3° C., and wherein the absolute value of the difference between the refractive index of said first resin layer and the refractive index of said second resin layer is not more than 0.010.

8. A multiple layer panel comprising the interlayer of claim 1 and at least one rigid substrate.

9. An interlayer comprising:
a first plasticized resin layer comprising a first poly(vinyl acetal) resin;
a second plasticized resin layer comprising a second poly(vinyl acetal) resin, wherein said second plasticized resin layer has a refractive index of at least 1.470; and
a third plasticized polyvinyl resin layer comprising a third poly(vinyl acetal) resin, wherein said second plasticized resin layer is sandwiched between said first plasticized resin layer and said third plasticized resin layer, and
wherein the largest of the absolute value of the difference between the refractive index of said first plasticized resin layer and the refractive index of said second plasticized resin layer and the absolute value of the difference between the refractive index of said second plasticized resin layer and the refractive index of said third plasticized resin layer is not more than 0.010.

10. The interlayer of claim 9 , wherein the refractive index of said second poly(vinyl acetal) resin is at least 1.492 and wherein said second poly(vinyl acetal) resin comprises residues of at least one aldehyde having a refractive index of less than 1.421.

11. The interlayer of claim 9 , wherein said second poly(vinyl acetal) resin comprises residues of at least one aldehyde having a refractive index of at least 1.421.

12. The interlayer of claim 9 , wherein the refractive index of said second resin layer is lower than the refractive index of said first resin layer.

13. The interlayer of claim 9 , wherein said second resin layer has a glass transition temperature that is at least 3° C. higher or lower than the glass transition temperature of said first resin layer and/or said third resin layer, wherein said second poly(vinyl acetal) resin has a residual hydroxyl content that is at least 2 weight percent higher or lower than the residual hydroxyl content of said first poly(vinyl acetal) resin and said third poly(vinyl acetal) resin, and wherein said interlayer has a haze value of less than 5 percent.

14. An interlayer comprising:
a first resin layer comprising a first poly(vinyl acetal) resin and a first plasticizer; and
a second resin layer adjacent to said first resin layer, wherein said second resin layer comprises a second poly(vinyl acetal) resin and a second plasticizer,
wherein at least one of said first poly(vinyl acetal) resin and said second poly(vinyl acetal) resin comprises residues of an aldehyde having a refractive index of at least 1.421, and wherein the haze value of said interlayer is less than 5 percent,
wherein at least one of said first and said second poly(vinyl acetal) resins has a residual hydroxyl content of at least 16 weight percent and the other of said first and said second poly(vinyl acetal) resins has a residual hydroxyl content of not more than 15 weight percent, wherein the difference between the glass transition temperature of said first resin layer and the glass transition temperature of said second resin layer is at least 3° C., and wherein the absolute value of the difference between the refractive index of said first resin layer and the refractive index of said second resin layer is not more than 0.010.

15. The interlayer of claim 14 , wherein at least one of said first and said second poly(vinyl acetal) resins comprises residues of an aldehyde selected from the group consisting of n-butyraldehyde, iso-butyraldehyde, 2-ethylhexaldehyde, and combinations thereof.

16. The interlayer of claim 14 , wherein the difference between the residual hydroxyl content of said first poly(vinyl acetal) resin and the residual hydroxyl content of said second poly(vinyl acetal) resin is at least 2 weight percent and wherein at least one of said first and said second resin layers has a glass transition temperature less than 25° C.

17. The interlayer of claim 14 , wherein said residues of an aldehyde having a refractive index of at least 1.421 comprise residues of at least one aromatic compound, wherein said first or said second poly(vinyl acetal) resin comprise at least 0.5 weight percent of said residues having a refractive index of at least 1.421, based on the total wei

Assignees

• Solutia Inc

Inventors

• Lu Jun
• Li Zhou

Classifications

• B29C47/065

  Operations & Transport · mapped topic

• B32B2250/24

  All layers being polymeric · CPC title

• B32B17/10761

  containing vinyl acetal · CPC title

• B32B17/1055

  characterized by the resin layer, i.e. interlayer · CPC title

• B29K2105/0038

  Plasticisers · CPC title