Adhesives derived from agricultural proteins

Patent metadata

Field	Value
Publication number	US-9522515-B2
Application number	US-201214126321-A
Country	US
Kind code	B2
Filing date	Jun 18, 2012
Priority date	Jun 17, 2011
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

The invention is directed to adhesives derived from animal or plant proteins, particularly canola and spent hen proteins. The adhesives are prepared by extracting the proteins by pH shifting; and either treating the extracted proteins with urea or sodium dodecyl sulfate, or polymerizing the proteins to form a protein-polymer conjugate. The invention is also directed to a wood based product comprising pieces of wood based material joined or consolidated with the adhesives.

First claim

What is claimed is:

1. A method for preparing an adhesive derived from animal or plant product, comprising the steps of:
a) extracting a protein fraction comprising intact proteins from an animal or plant product by pH shifting; and
b) denaturing the extracted protein fraction or forming a protein-polymer conjugate with the extracted protein fraction and a polymerizable monomer, or both denaturing the extracted protein fraction and forming a conjugate with the denatured protein fraction and a polymerizable monomer.

2. The method of claim 1 , wherein the animal product comprises spent hen meat.

3. The method of claim 2 , wherein step (a) comprises diluting spent hen meat, followed by filtration and centrifugation to obtain a myofibrillar layer.

4. The method of claim 3 , wherein the pH of the myofibrillar layer is adjusted to alkaline.

5. The method of claim 4 , wherein a protein fraction is precipitated by adjusting the pH of the myofibrillar layer to an acidic pH following an incubation period at the alkaline pH.

6. The method of claim 5 , further comprising the step of centrifuging to recover the precipitated protein fraction, followed by freeze-drying.

7. The method of claim 1 , wherein the plant product is canola meal.

8. The method of claim 7 , wherein step (a) comprises adjusting the pH of diluted defatted canola meal to acidic.

9. The method of claim 8 , wherein the solution is centrifuged to obtain a first precipitate.

10. The method of claim 9 , further comprising the step of adjusting the pH of diluted precipitate to alkaline, followed by centrifugation to obtain a supernatant.

11. The method of claim 10 , further comprising the step of adjusting the pH of the supernatant to acidic, followed by centrifugation to obtain a second precipitate.

12. The method of claim 11 wherein the second precipitate comprising canola protein is freeze-dried.

13. The method of claim 1 , wherein in step (b), the extracted protein fraction is denatured with sodium hydroxide, urea, or sodium hydroxide sulphate.

14. The method of claim 13 , wherein the extracted protein fraction is denatured with urea, having a concentration of about 1 M to about 8 M.

15. The method of claim 1 , wherein the extracted protein fraction is reacted with a polymerizable monomer to form a protein-polymer conjugate.

16. The method of claim 15 , wherein the monomer is glycidyl methacrylate.

17. The method of claim 16 , comprising the use of an initiator comprising an azonitrile, a persulphate or a peroxide.

Assignees

• Wu Jianping
• Wang Chanchan
• Univ Alberta

Inventors

• Wu Jianping
• Wang Chanchan

Classifications

• Y10T428/31515

  As intermediate layer · CPC title

• C08H1/00

  Macromolecular products derived from proteins (food proteins A23; glue, gelatine C09H) · CPC title

• C09J151/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09J189/04

  Products derived from waste materials, e.g. horn, hoof or hair · CPC title

• C09H3/00

  Isolation of glue or gelatine from raw materials, e.g. by extracting, by heating (gelatine for foodstuffs A23J1/10) · CPC title