Printed energy storage device

Patent metadata

Field	Value
Publication number	US-9520598-B2
Application number	US-201314050145-A
Country	US
Kind code	B2
Filing date	Oct 9, 2013
Priority date	Oct 10, 2012
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C 2 mimBF 4 ). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF 4 ) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C 2 mimBF 4 ). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

First claim

What is claimed is:

1. A printed energy storage device comprising:
a first electrode;
a second electrode; and
a separator positioned between the first electrode and the second electrode, at least one of the first electrode and the second electrode comprising an ionic liquid,
wherein the ionic liquid includes a cation selected from the group consisting of 1-ethyl-3-methylimidazolium, butyltrimethylammonium, 1-butyl-3-methylimidazolium, 1-methyl-3-propylimidazolium, 1-hexyl-3-methylimidazolium, choline, ethylammonium, tributylmethylphosphonium, tributyl(tetradecyl)phosphonium, trihexyl(tetradecyl)phosphonium, 1-ethyl-2,3-methylimidazolium, 1-butyl-1-methylpiperidinium, diethylmethylsulfonium, 1-methyl-3-propylimidazolium, 1-methyl-1-propylpiperidinium, 1-butyl-2-methylpyridinium, 1-butyl-4-methylpyridinium, 1-butyl-1-methylpyrrolidinium, and diethylmethylsulfonium,
wherein the ionic liquid includes an anion selected from the group consisting of tetrafluoroborate, tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, dimethyl phosphate, methansulfonate, triflate, tricyanomethanide, dibutylphosphate, bis(trifluoromethylsulfonyl)imide, bis-2,4,4-(trimethylpentyl) phosphinate, iodide, chloride, bromide, and nitrate,
wherein the at least one of the first electrode and the second electrode comprises a zinc salt, and
wherein an anion of the zinc salt is the same as the anion of the ionic liquid.

2. The printed energy storage device of claim 1 , wherein at least one of the first electrode and the second electrode further comprises carbon nanotubes.

3. The printed energy storage device of claim 2 , wherein the carbon nanotubes comprise single-wall carbon nanotubes.

4. The printed energy storage device of claim 2 , wherein the carbon nanotubes comprise multi-wall carbon nanotubes.

5. The printed energy storage device of claim 1 , further comprising a current collector coupled to at least one of the first electrode and the second electrode, the current collector comprising carbon nanotubes.

6. The printed energy storage device of claim 5 , wherein the current collector further comprises at least one of nickel flakes, graphene flakes, and graphite powder.

7. The printed energy storage device of claim 1 , wherein both the first electrode and the second electrode include the ionic liquid.

8. The printed energy storage device of claim 1 , wherein the separator comprises microspheres.

9. An electrode of a printed energy storage device, the electrode comprising:
an ionic liquid,
wherein the ionic liquid includes a cation selected from the group consisting of 1-ethyl-3-methylimidazolium, butyltrimethylammonium, 1-butyl-3-methylimidazolium, 1-methyl-3-propylimidazolium, 1-hexyl-3-methylimidazolium, choline, ethylammonium, tributylmethylphosphonium, tributyl(tetradecyl)phosphonium, trihexyl(tetradecyl)phosphonium, 1-ethyl-2,3-methylimidazolium, 1-butyl-1-methylpiperidinium, diethylmethylsulfonium, 1-methyl-3-propylimidazolium, 1-methyl-1-propylpiperidinium, 1-butyl-2-methylpyridinium, 1-butyl-4-methylpyridinium, 1-butyl-1-methylpyrrolidinium, and diethylmethylsulfonium,
wherein the ionic liquid includes an anion selected from the group consisting of tetrafluoroborate, tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, dimethyl phosphate, methansulfonate, triflate, tricyanomethanide, dibutylphosphate, bis(trifluoromethylsulfonyl)imide, bis-2,4,4-(trimethylpentyl) phosphinate, iodide, chloride, bromide, and nitrate; and
a zinc salt, wherein an anion of the zinc salt is the same as the anion of the ionic liquid.

10. The electrode of claim 9 , wherein the electrode further comprises carbon nanotubes.

11. The electrode of claim 10 , wherein the carbon nanotubes comprise single-wall carbon nanotubes.

12. The electrode of claim 10 , wherein the carbon nanotubes comprise multi-wall carbon nanotubes.

13. The electrode of claim 9 , wherein the printed energy storage device comprises a printed zinc manganese dioxide battery.

14. A conductive paste for a layer of a printed energy storage device, the conductive paste comprising:
a solvent;
ground carbon nanotubes;
an ionic liquid,
wherein the ionic liquid comprises a cation selected from the group consisting of 1-ethyl-3-methylimidazolium, butyltrimethylammonium, 1-butyl-3-methylimidazolium, 1-methyl-3-propylimidazolium, 1-hexyl-3-methylimidazolium, choline, ethylammonium, tributylmethylphosphonium, tributyl(tetradecyl)phosphonium, trihexyl(tetradecyl)phosphonium, 1-ethyl-2,3-methylimidazolium, 1-butyl-1-methylpiperidinium, diethylmethylsulfonium, 1-methyl-3-propylimidazolium, 1-ethyl-3-methylimidazolium, 1-methyl-1-propylpiperidinium, 1-butyl-2-methylpyridinium, 1-butyl-4-methylpyridinium, 1-butyl-1-methylpyrrolidinium, and diethylmethylsulfonium, and
wherein the ionic liquid comprises an anion selected from the group consisting of tetrafluoroborate, tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, dimethyl phosphate, methansulfonate, triflate, tricyanomethanide, dibutylphosphate, bis(trifluoromethylsulfonyl)imide, bis-2,4,4-(trimethylpentyl) phosphinate, iodide, chloride, bromide, and nitrate; and
a zinc salt,
wherein the anion of the zinc salt is the same as the anion of the ionic liquid.

15. The conductive paste of claim 14 , wherein the ionic liquid comprises 1-ethyl-3-methylimidazolium tetrafluoroborate (C 2 mimBF 4 ).

16. The conductive paste of claim 14 , wherein the carbon nanotubes comprise single-wall carbon nanotubes.

17. The conductive paste of claim 14 , wherein the carbon nanotubes comprise multi-wall carbon nanotubes.

18. The conductive paste of claim 14 , wherein the solvent, the carbon nanotubes, and the ionic liquid form a homogeneous mixture.

19. The conductive paste of claim 14 , further comprising manganese dioxide and a conductive carbon, wherein the layer is for forming a cathode of the printed energy storage device.

20. The printed energy storage device of claim 7 , wherein the separator comprises the ionic liquid.

21. The printed energy storage device of claim 1 , wherein the separator comprises the ionic liquid.

22. The printed energy storage device of claim 21 , wherein the separator comprises a zinc salt, wherein an anion of the zinc salt is the same as the anion of the ionic liquid.

Assignees

• Nthdegree Tech Worldwide Inc
• Nthdegree Tech Worldwide Inc

Inventors

• Lockett Vera N
• Gustafson John G
• Hartman Alexandra E
• Lowenthal Mark D
• Ray William J

Classifications

• H01M4/06 Primary

  Electrodes for primary cells · CPC title

• H01G11/36

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01G11/30

  characterised by their material · CPC title

• H01M6/40 Primary

  Printed batteries {, e.g. thin film batteries} · CPC title