Cathode material, interconnector material and solid oxide fuel cell

Patent metadata

Field	Value
Publication number	US-9520597-B2
Application number	US-201213616905-A
Country	US
Kind code	B2
Filing date	Sep 14, 2012
Priority date	Dec 19, 2011
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

A cathode material for a solid oxide fuel cell comprises a complex oxide having a perovskite structure expressed by the general formula ABO3, a content amount of P included in the complex oxide being at least 1 ppm and no more than 50 ppm, a content amount of Cr in the complex oxide being at least 1 ppm and no more than 500 ppm, and a content amount of B in the complex oxide being at least 1 ppm and no more than 50 ppm in a weight ratio relative to a total weight of the complex oxide.

First claim

What is claimed is:

1. A cathode material for a solid oxide fuel cell, comprising:
a complex oxide having a perovskite structure expressed by the general formula ABO 3 , where A is at least one of lanthanum and strontium, and where B is at least one of cobalt, iron and nickel, a content amount of phosphorus included in the complex oxide being at least 10 ppm and no more than 50 ppm, a content amount of chromium in the complex oxide being at least 50 ppm and no more than 500 ppm, and a content amount of boron in the complex oxide being at least 5 ppm and no more than 50 ppm in a weight ratio relative to a total weight of the complex oxide, the cathode material having a uniform composition distribution throughout the cathode material including an outer surface and an inner body of the cathode material.

2. The cathode material for a solid oxide fuel cell according to claim 1 , wherein
the content amount of phosphorus included in the complex oxide is no more than 30 ppm in the weight ratio relative to the total weight of the complex oxide.

3. The cathode material for a solid oxide fuel cell according to claim 1 , wherein
the content amount of chromium included in the complex oxide is no more than 100 ppm in the weight ratio relative to the total weight of the complex oxide.

4. The cathode material for a solid oxide fuel cell according to claim 1 , wherein
the content amount of boron included in the complex oxide is more preferably no more than 10 ppm in the weight ratio relative to the total weight of the complex oxide.

5. The cathode material for a solid oxide fuel cell according to claim 2 , wherein
the content amount of chromium included in the complex oxide is no more than 100 ppm in the weight ratio relative to the total weight of the complex oxide.

6. The cathode material for a solid oxide fuel cell according to claim 2 , wherein
the content amount of boron included in the complex oxide is more preferably no more than 10 ppm in the weight ratio relative to the total weight of the complex oxide.

7. The cathode material for a solid oxide fuel cell according to claim 3 , wherein
the content amount of boron included in the complex oxide is more preferably no more than 10 ppm in the weight ratio relative to the total weight of the complex oxide.

8. A solid oxide fuel cell comprising the cathode made of the cathode material according to claim 1 , the solid oxide fuel cell further comprising:
an anode; and
a solid electrolyte layer disposed between the cathode and the anode.

9. A solid oxide fuel cell comprising the cathode made of the cathode material according to claim 2 , the solid oxide fuel cell further comprising:
an anode; and
a solid electrolyte layer disposed between the cathode and the anode.

10. A solid oxide fuel cell comprising the cathode made of the cathode material according to claim 3 , the solid oxide fuel cell further comprising:
an anode; and
a solid electrolyte layer disposed between the cathode and the anode.

11. A solid oxide fuel cell comprising the cathode made of the cathode material according to claim 4 , the solid oxide fuel cell further comprising:
an anode; and
a solid electrolyte layer disposed between the cathode and the anode.

12. A cathode material for a solid oxide fuel cell, comprising:
a complex oxide having a perovskite structure expressed by the general formula ABO 3 , where A is at least one of lanthanum and strontium, and where B is at least one of cobalt, iron and nickel, a content amount of phosphorus included in the complex oxide being at least 10 ppm and no more than 50 ppm, a content amount of chromium in the complex oxide being at least 20 ppm and no more than 500 ppm, and a content amount of boron in the complex oxide being at least 3 ppm and no more than 50 ppm in a weight ratio relative to a total weight of the complex oxide, the cathode material having a uniform composition distribution throughout the cathode material including an outer surface and an inner body of the cathode material.

13. The cathode material for a solid oxide fuel cell according to claim 12 , wherein
the content amount of phosphorus included in the complex oxide is no more than 30 ppm in the weight ratio relative to the total weight of the complex oxide.

14. The cathode material for a solid oxide fuel cell according to claim 12 , wherein
the content amount of chromium included in the complex oxide is no more than 100 ppm in the weight ratio relative to the total weight of the complex oxide.

15. The cathode material for a solid oxide fuel cell according to claim 12 , wherein
the content amount of boron included in the complex oxide is more preferably no more than 10 ppm in the weight ratio relative to the total weight of the complex oxide.

16. A solid oxide fuel cell comprising the cathode made of the cathode material according to claim 12 , the solid oxide fuel cell further comprising:
an anode; and
a solid electrolyte layer disposed between the cathode and the anode.

Assignees

• Ohmori Makoto
• Kobayashi Ayano
• Fujisaki Shinji
• Ngk Insulators Ltd

Inventors

• Ohmori Makoto
• Kobayashi Ayano
• Fujisaki Shinji

Classifications

• C04B2235/5445

  submicron sized, i.e. from 0,1 to 1 micron · CPC title

• C04B2235/727

  Phosphorus or phosphorus compound content · CPC title

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M4/9033

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title