Single phase lead-free cubic pyrochlore bismuth zinc niobate-based dielectric materials and processes for manufacture

Patent metadata

Field	Value
Publication number	US-9520207-B2
Application number	US-201514708392-A
Country	US
Kind code	B2
Filing date	May 11, 2015
Priority date	May 9, 2014
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

Both single phase lead-free cubic pyrochlore bismuth zinc niobate (BZN)-based dielectric materials with a chemical composition of Bi 1.5 Zn (0.5+y) Nb (1.5−x) Ta (x) O (6.5+y) , with 0≦x<0.23 and 0≦y<0.9 and films with these average compositions with Bi 2 O 3 particles in an amorphous matrix and a process of manufacture thereof. The crystalline BZNT-based dielectric material has a relative permittivity of at least 120, a maximum applied electric field of at least 4.0 MV/cm at 10 kHz, a maximum energy storage at 25° C. and 10 kHz of at least 50 J/cm 3 and a maximum energy storage at 200° C. and 10 kHz of at least 22 J/cm 3 . The process is a wet chemical process that produces thin films of Bi 1.5 Zn (0.5+y) Nb (1.5−x) Ta (x) O (6.5+y) without the use of 2-methoxyethanol and pyridine.

First claim

We claim:

1. A dielectric material comprising:
a single phase lead-free cubic pyrochlore bismuth zinc niobate (BZN)-based dielectric material with a chemical composition of Bi 1.5 Zn (0.5+y) Nb (1.5−x) Ta (x) O (6.5+y) , with 0.10≦x≦0.20 and 0.2≦y≦0.6;
said BZN-based dielectric material having at least one of a maximum applied electric field of at least 5.0 MV/cm at 10 kHz, a maximum energy storage at 25° C and 10 kHz of at least 60 J/cm 3 and a maximum energy storage at 200° C and 10 kHz of at least 30 J/cm 3 .

2. The dielectric material of claim 1 , wherein said BZN-based dielectric material has at least one of a maximum applied electric field of at least 4.5 MV/cm at 1 kHz, a maximum applied electric field of at least 4.7 MV/cm at 100 Hz, and a maximum electric field of at least 5.25 MV/cm at 10 kHz.

3. The dielectric material of claim 2 , wherein said BZN-based dielectric material has at least one of a maximum applied electric field of at least 5.0 MV/cm at 1 kHz, a maximum applied electric field of at least 5.2 MV/cm at 100 Hz, and a maximum electric field of at least 5.5 MV/cm at 10 kHz.

4. The dielectric material of claim 1 , wherein said BZN-based dielectric material has at least one of a maximum energy storage of at least 50 J/cm 3 at 1 kHz and 25° C., a maximum energy storage electric storage of at least 63 J/cm 3 at 10 kHz and 25° C, a maximum energy storage of at least 25 J/cm 3 at 1 kHz and 200° C., and a maximum energy storage electric storage of at least 30 J/cm 3 at 10 kHz and 200° C.

5. The dielectric material of claim 4 , wherein said BZN-based dielectric material has at least one of a maximum energy storage of at least 54 J/cm 3 at 1 kHz and 25° C., a maximum energy storage electric storage of at least 66 J/cm 3 at 10 kHz and 25° C., a maximum energy storage of at least 33 J/cm 3 at 1 kHz and 200° C., and a maximum energy storage electric storage of at least 37 J/cm 3 at 10 kHz and 200° C.

Assignees

• Penn State Res Found
• The Penn State Univ
• Nat Science Found

Inventors

• Michael Elizabeth K
• Trolier-Mckinstry Susan

Classifications

• H01B3/12 Primary

  ceramics · CPC title

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title

• C04B35/495

  based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates · CPC title

• C04B2235/3255

  Niobates or tantalates, e.g. silver niobate · CPC title

• C04B2235/3284

  Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof · CPC title