Method and device for determining a sample stream concentration value of an analyte in a sample stream
US-2024053234-A1 · Feb 15, 2024 · US
US9518906B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9518906-B2 |
| Application number | US-201113809622-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 20, 2011 |
| Priority date | Jul 21, 2010 |
| Publication date | Dec 13, 2016 |
| Grant date | Dec 13, 2016 |
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A method for measuring the properties of a fluid that uses a torsionally resonant structure having a base structure; at least two parallel tines affixed to the base structure and projecting in the same direction from the base structure; and wherein the base structure is sufficiently compliant as to mutually couple the tines so that they behave as a single resonator when the tines are driven in synchronized manner. The torsionally resonant structure is immersed in the fluid to be measured and a tine driving mechanism is used to drive the tines torsionally. A tine movement sensing mechanism form measurements of tine movement response to the driving mechanism and the measurements of tine movement to form measurements of fluid properties.
Opening claim text (preview).
The invention claimed is: 1. A method for measuring the properties of a fluid, comprising: a. providing a torsionally resonant structure, including: i. a base structure; ii. at least two parallel tines affixed to said base structure and projecting in the same direction from said base structure; and iii. wherein said base structure is sufficiently compliant as to mutually couple said tines so that they behave as a single resonator when said tines are driven in synchronized manner, wherein said tines are driven in phase with one another and wherein said tines include magnets; b. providing a tine driving mechanism and tine movement sensing mechanism; c. immersing said resonant structure in said fluid; d. causing said tine driving mechanism to drive said tines torsionally; e. using said sensing mechanism to form measurements of tine movement response to said driving mechanism; and f. using said measurements of tine movement to form measurements of fluid properties. 2. The method of claim 1 , wherein said magnets are permanent magnets. 3. The method of claim 1 , wherein said magnets are electromagnets. 4. The method of claim 1 , wherein said magnets are soft magnetic materials that can be magnetized by the presence of a superimposed magnetic bias field. 5. The method of claim 4 , wherein said magnetic bias field is provided by permanent magnets. 6. The method of claim 4 , wherein said magnetic bias field is provided by at least one electromagnet. 7. The method of claim 1 , wherein the magnets are acted upon by an applied oscillating magnetic field, produced by said tine driving mechanism so as to cause the resonator to vibrate at a frequency in the proximity of its torsional resonant frequency. 8. The method of claim 7 , wherein said oscillating magnetic field is provided by an electromagnet that is a component of said tine driving mechanism. 9. The method of claim 7 , wherein said oscillating magnetic field is periodically interrupted in order to provide a sensing period in which said tine movement sensing mechanism is used to measure tine movement, without interference from said applied oscillating magnetic field. 10. The method of claim 7 , wherein said oscillating magnetic field has at least a component perpendicular to the polarizations of said magnets. 11. The method of claim 1 wherein said tine movement sensing mechanism includes at least a sensing coil and an electronic amplification and analysis unit. 12. The method of claim 1 , wherein said tines are substantially circular in cross section, whereby torsional movement of said tines shears said fluid. 13. The method of claim 12 , further including the step of using said measurements of tine movement to form measurements of tine damping, which are used to form measurements of fluid viscosity. 14. The method of claim 1 , further including: a. additionally to causing said driving mechanism to drive said tines torsionally, causing said driving mechanism to drive said tines to move flexurally through said fluid, displacing said fluid, which displaced fluid adds to the apparent mass of said tines, thereby causing its resonant frequency to change in response to fluid density, altering its resonant frequency; and b. causing said tine movement sensing mechanism to form measurements of tine movement in response to said driving said tines to move flexurally through said fluid. 15. The method of claim 14 , wherein said driving of said tines alternates between torsional driving and flexural driving. 16. The method of claim 14 , wherein said flexural driving and said torsional driving are simultaneous. 17. The method of claim 1 , wherein said torsional driving of said tines is performed by applying a first oscillating magnetic field, oriented to drive said tines torsionally and oscillating at a frequency that causes the resonator to torsionally vibrate at a frequency in the proximity of its torsional resonant frequency, and applying a second magnetic field, oriented to cause said tines to vibrate in bending, and oscillating at a frequency that causes said tines to flexurally vibrate at a frequency in the proximity of one of their bending modes. 18. The method of claim 17 , wherein said first oscillating magnetic field is provided by a first electromagnet, said first electromagnet so disposed as to drive said tines in at least in one of their torsional modes, said first electromagnet consisting of at least one coil. 19. The method of claim 17 , wherein a second oscillating magnetic field is provided by a second electromagnet, said second electromagnet consisting of at least one coil. 20. The method of claim 17 , wherein the oscillating magnetic fields are periodically interrupted in order to provide sensing periods in which sensing means can be used to monitor the response of the resonator without interference from the applied oscillating magnetic fields. 21. The method of claim 1 , wherein the motion of the tines is sensed by sensing means that includes at least one sensing coil and an electronic amplification and monitoring unit. 22. The method of claim 1 , wherein a first electromagnet is positioned to create a magnetic field having at least a component perpendicular to the polarizations of said magnets, said component acting to exert a torque on said magnets. 23. The method of claim 1 , wherein said at least two parallel tines, includes: a. a pair of tines that are substantially circular in cross-section; and b. a pair of tines that are not circular in cross-section. 24. The method of claim 23 , wherein said not-circular tines are rectangular in cross-section. 25. The method of claim 24 , wherein said rectangular tines are square in cross-section. 26. A coupled resonator, comprising: a. a base structure having: a base stem having a base stem flexural elasticity per unit length; a base bridge; and a base neck connecting said bridge to said base stem, and having a flexural elasticity per unit length that is greater than that of said base stem; b. a plurality of tines having longitudinal axes, said axes being parallel to one another, all attached to and extending from said base structure in the same direction, each tine including: i. a narrow in transverse dimension tine stem portion; ii. a tine end wider in at least one transverse dimension than said tine stem portion, and having a tine end cross section; iii. a magnet held in said tine end. 27. The resonator of claim 26 , wherein said base neck is sufficiently compliant to cause said tines to function as a single resonant unit. 28. The resonator of claim 26 , wherein said base neck is sufficiently compliant to ensure decoupling said tines from said base stem. 29. The resonator of claim 26 wherein said tine stems have a circular cross section. 30. The resonator of claim 26 wherein said end portions of said tines are circular in cross section. 31. The resonator of claim 26 , including driver means adapted to cause said tines to vibrate torsionally in the vicinity of one of their torsional resonances, and a sensing means to sense said torsional vibration of said tines. 32. A resonator assembly, comprising: a. a base structure; b. a first set of tines extending from said base structure in the same direction, each tine of the first set of tines having a port
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