Nematic liquid crystal composition and liquid crystal display device using the same

Patent metadata

Field	Value
Publication number	US-9518221-B2
Application number	US-201314435318-A
Country	US
Kind code	B2
Filing date	Jul 22, 2013
Priority date	Jul 22, 2013
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

The inventor of the present invention has investigated various liquid crystal compounds and various chemical substances and found that the object can be achieved by using a combination of particular liquid crystal compounds, thereby making the present invention.
In other words, provided are a liquid crystal composition having positive dielectric anisotropy, comprising compounds represented by formula (26.2) and formula (2.5) and one or more compounds represented by general formula (IV), an active matrix driving-liquid crystal display device using the liquid crystal composition, and a liquid crystal display using the active matrix-driving liquid crystal display device:

(In the formula, R 41 and R 42 each independently represent an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 4 or 5 carbon atoms and X 41 and X 42 each independently represent a hydrogen atom or a fluorine atom.)

First claim

The invention claimed is:

1. A liquid crystal composition having positive dielectric anisotropy, comprising compounds represented by formula (26.2) and formula (2.5):

 and
one or more compounds represented by general formula (IV):

(In the formula, R 41 and R 42 each independently represent an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 4 or 5 carbon atoms and X 41 and X 42 each independently represent a hydrogen atom or a fluorine atom),
13% by mass or more of one or more selected from compounds represented by formula (11.1) and formula (11.2):

 and
a compound represented by general formula (V-2)

wherein R 51 and R 52 each independently represent an alkyl group having 1 to 5 carbon atoms, and X 51 and X 52 each independently represent a fluorine atom or a hydrogen atom.

2. The liquid crystal composition according to claim 1 , further comprising one or more compounds represented by general formula (L):
R L1 -B L1 -L L1 -B L2 L L2 -B L3 OL R L2   (L)

(In the formula, R L1 and R L2 each independently represent an alkyl group having 1 to 8 carbon atoms where one —CH 2 — or two or more non-adjacent —CH 2 — in the alkyl group may each independently be substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—,
OL represents 0, 1, 2, or 3,
B L1 , B L2 , and B L3 each independently represent a group selected from the group consisting of

(a) a 1,4-cyclohexylene group (one —CH 2 — or two or more non-adjacent —CH 2 — in this group may each be substituted with —O—) and
(b) a 1,4-phenylene group (one —CH═ or two or more non-adjacent —CH═ in this group may each be substituted with —N═)
where the group (a) and the group (b) may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom,
L L1 and L L2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —COO—, —OCO—, —OCF 2 —, —CF 2 O—, —CH═N—N═CH—, —CH═CH—, —CF═CF—, or —C≡C—, and
when OL represents 2 or 3 and a plurality of L L2 are present, they may be the same or different; when OL represents 2 or 3 and a plurality of B L3 are present, they may be the same or different; however, the compounds represented by formula (2.5) and general formula (IV), general formula (V-2), and compounds represented by formula (11.1) and formula (11.2) are excluded).

3. The liquid crystal composition according to claim 1 , comprising one or more compounds represented by general formula (M):

(In the formula, R M1 represents an alkyl group having 1 to 8 carbon atoms where one —CH 2 — or two or more non-adjacent —CH 2 — in the alkyl group may each independently be substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—,
PM represents 0, 1, 2, 3, or 4,
C M1 and C M2 each independently represent a group selected from the group consisting of

(d) a 1,4-cyclohexylene group (one —CH 2 — or two or more non-adjacent —CH 2 — in this group may each be substituted with —O— or —S—) and
(e) a 1,4-phenylene group (one —CH═ or two or more non-adjacent —CH═ in this group may each be substituted with —N═)
where the group (d) and the group (e) may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom,
K M1 and K M2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CF 2 O—, —COO—, —OCO—, or —C≡C—,
when PM represents 2, 3, or 4 and a plurality of K M1 are present, they may be the same or different; and when PM represents 2, 3, or 4 and a plurality of C M2 are present, they may be the same or different,
X M1 and X M3 each independently represent a hydrogen atom, a chlorine atom, or a fluorine atom, and
X M2 represents a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a fluoromethoxy group, a difluoromethoxy group, a trifluoromethoxy group, or a 2,2,2-trifluoroethyl group; however, the compound represented by formula (26.2) is excluded).

4. An active matrix-driving liquid crystal display device using the liquid crystal composition according to claim 1 .

5. A liquid crystal display using the active matrix-driving liquid crystal display device according to claim 4 .

Assignees

• Dainippon Ink & Chemicals

Inventors

• Kawamura Joji

Classifications

• C09K2019/3078

  Cy-Cy-COO-Ph-Cy · CPC title

• C09K19/3068 Primary

  chain containing -COO- or -OCO- groups · CPC title

• C09K2019/0466

  the linking chain being a -CF2O- chain · CPC title

• C09K19/3066

  in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers · CPC title

• C09K19/065

  containing one non-condensed unsaturated non-aromatic ring, e.g. cyclohexene ring · CPC title