Process of making a continuous dielectric film comprising dispersed nanoparticles

Patent metadata

Field	Value
Publication number	US-9518162-B2
Application number	US-201314413458-A
Country	US
Kind code	B2
Filing date	Jul 12, 2013
Priority date	Jul 13, 2012
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

The invention provides a process of making a continuous freeform thermoplastic dielectric film ( 25 ) that is evenly loaded with dispersed nanoparticles comprising the steps of; feeding thermoplastic granules ( 21 ) into an extruder ( 23 ), injecting a secondary feed ( 27 ) comprising a suspension of nanoparticles in a liquid carrier to create a nanocomposite, and extruding said composite onto cooled rollers ( 26 ) at a preset rate thereby enabling the crystalline structure of the nanocomposite film ( 25 ) to be controlled wherein the secondary feed ( 27 ) is mixed continuously by an ultrasonicator ( 29 ) whilst being injected into the extruder ( 23 ). By selecting the size of the nano particles based on their de Broglie wavelength in the crystalline polymer the dielectric can be produced in bulk to make high capacitance high energy density storage capacitors

First claim

The invention claimed is:

1. A process of making a continuous freeform thermoplastic dielectric film for use at high voltage that is evenly loaded with dispersed nanoparticles comprising the steps of:
feeding thermoplastic granules into an extruder;
injecting a secondary feed comprising a suspension of nanoparticles in a liquid carrier to create a nanocomposite;
continuously mixing the secondary feed by an ultrasonicator whilst injecting it into the extruder;
and extruding the nanocomposite onto cooled rollers at a preset rate thereby enabling the crystalline structure of the dielectric film to be controlled;
wherein the nanoparticles are geometrically controlled to each have no diameter that is greater than the De Broglie wavelength of an electron in the thermoplastic granules.

2. A process according to claim 1 in which the secondary feed is further ultrasonicated by a flow cell.

3. A process according to claim 1 in which the nanoparticles comprise titanium dioxide.

4. A process according to claim 1 where the liquid carrier is toluene.

5. A process according to claim 1 where the liquid carrier is ethyl acetate.

6. A process according to claim 1 that further comprises the step of injecting an additional feed of nanoparticles that are selected to provide extra electrons.

7. A process according to claim 6 in which the nanoparticles in the additional feed comprise silver.

Assignees

• Secr Defence

Inventors

• Brown Matthew Adrian
• Lang Michelle Silverstone

Classifications

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• C08J2325/06

  Polystyrene · CPC title

• H01G4/14

  Organic dielectrics · CPC title

• H01G4/18

  of synthetic material, e.g. derivatives of cellulose (H01G4/16 takes precedence) · CPC title

• B29K2995/006

  Bio-degradable, e.g. bioabsorbable, bioresorbable or bioerodible · CPC title