Preparation of rubber composition containing graphite platelets and tire with component

Patent metadata

Field	Value
Publication number	US-9518157-B2
Application number	US-201314062099-A
Country	US
Kind code	B2
Filing date	Oct 24, 2013
Priority date	Oct 24, 2013
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

Preparation of a rubber composition containing a dispersion of aligned exfoliated graphite platelets. Such rubber composition is prepared by a method comprised of a sequential combination of concentrated solvent or dry masterbatching of elastomer and exfoliated graphite platelets, followed by blending the masterbatch (after removing the solvent from the solvent based masterbatch) with additional elastomer(s) and then followed by processing the resulting rubber composition to align the dispersed exfoliated graphite platelets in a substantially parallel relation to each other. Such processing may comprise as least one of extrusion and calendaring the rubber composition. The invention further relates to a tire containing a component comprised of such rubber composition containing a dispersion of aligned exfoliated graphite platelets prepared by the aforesaid method.

First claim

What is claimed is:

1. A method of preparing a sulfur curable rubber composition is comprised of:
(A) preparing a masterbatch comprised of
blending from about 3 to about 20 parts by weight of graphite platelets consisting of exfoliated graphite platelets with an organic solvent solution containing 100 parts by weight of at least one conjugated diene-based elastomer to form the masterbatch after which the masterbatch is dried by removing the organic solvent, wherein said diene-based elastomer consists of at least one of cis 1,4-polyisoprene, cis 1,4-polybutadiene and styrene/butadiene elastomer,
(B) preparing a subsequent sulfur curable rubber composition comprised of blending with said masterbatch up to about 40 parts by weight of at least one additional conjugated diene-based elastomer, where said additional diene-based elastomer consists of at least one of cis 1,4-polyisoprene, cis 1,4-polybutadiene and styrene/butadiene elastomer, and from about 20 to about 120 parts by weight of reinforcing filler per 100 parts by weight of the total of said conjugated diene-based elastomer(s) comprised of a combination of rubber reinforcing carbon black and precipitated silica together with a coupling agent for said precipitated silica having a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said conjugated diene-based elastomer(s), and
(C) processing said prepared sulfur curable rubber composition by at least one of extrusion, calendaring, and milling to provide a rubber composition containing a dispersion of said graphite platelets in parallel alignment with each other.

2. The method of claim 1 wherein said rubber composition is sulfur cured.

3. The method of claim 1 wherein said rubber composition is used for a tire having a component.

Assignees

• Goodyear Tire & Rubber

Inventors

• Zhao Junling
• Yang Xiaoping
• Pulford Carl Trevor Ross

Classifications

• C08J3/212

  and solid additives · CPC title

• C08J3/24 Primary

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• C08J2309/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title