Process for continuous recovering (meth)acrylic acid and apparatus for the process

Patent metadata

Field	Value
Publication number	US-9517997-B2
Application number	US-201314415113-A
Country	US
Kind code	B2
Filing date	Jul 9, 2013
Priority date	Aug 3, 2012
Publication date	Dec 13, 2016
Grant date	Dec 13, 2016

Abstract

This disclosure relates to a method of continuous recovery of (meth)acrylic acid and an apparatus used for the continuous recovery method. The continuous recovery method of (meth)acrylic acid according to the present invention may maintain a recovery rate of (meth)acrylic acid equivalent to that of the previous recovery method, and yet may significantly reduce energy consumption, and may minimize polymerization of (meth)acrylic acid in the recovery process, thus providing more improved operation stability.

First claim

The invention claimed is:

1. A method of continuous recovery of (meth)acrylic acid, comprising:
contacting a mixed gas comprising (meth)acrylic acid, organic by-products, and vapor, which is produced by a synthesis reaction of (meth)acrylic acid, with water in a (meth)acrylic acid absorption tower ( 100 ) to obtain a (meth)acrylic acid aqueous solution;
dividing and feeding the (meth)acrylic acid aqueous solution to a (meth)acrylic acid extraction tower ( 200 ) and a water separation tower ( 300 );
obtaining a (meth)acrylic acid extract with reduced water content from the (meth)acrylic acid aqueous solution that is fed to the (meth)acrylic acid extraction tower ( 200 ), and feeding it to a water separation tower ( 300 ); and
distilling the (meth)acrylic acid aqueous solution and the (meth)acrylic acid extract that are fed to the water separation tower ( 300 ) to obtain (meth)acrylic acid.

2. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein 5˜70 wt % of the (meth)acrylic acid aqueous solution obtained in the (meth)acrylic acid absorption tower ( 100 ) is fed to the (meth)acrylic acid extraction tower ( 200 ), and the remainder is fed to the water separation tower ( 300 ).

3. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the synthesis reaction of (meth)acrylic acid is an oxidation reaction of at least one compound selected from the group consisting of propane, propylene, butane, isobutylene, t-butylene, and (meth)acrolein in the presence of a gas phase catalyst.

4. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the internal temperature of the (meth)acrylic acid absorption tower ( 100 ) is maintained at 50 to 100° C.

5. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein in the step of obtaining the (meth)acrylic acid aqueous solution, a (meth)acrylic acid aqueous solution is discharged to the lower part of the (meth)acrylic acid absorption tower ( 100 ), and (meth)acrylic acid-stripped non-condensable gas is discharged to the upper part of the (meth)acrylic acid absorption tower ( 100 ).

6. The method for continuous recovery of (meth)acrylic acid according to claim 5 , further comprising contacting the non-condensable gas with water to recover acetic acid that is included in the non-condensable gas.

7. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the water fed to the (meth)acrylic acid absorption tower ( 100 ) includes organic by-products at a concentration of 3 to 20 wt %.

8. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the (meth)acrylic acid aqueous solution obtained in the (meth)acrylic acid absorption tower ( 100 ) includes (meth)acrylic acid at a concentration of 40 to 90 wt %.

9. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the (meth)acrylic acid extract is obtained by contacting the (meth)acrylic acid aqueous solution that is fed to the (meth)acrylic acid extraction tower ( 200 ) with a hydrophobic extraction solvent to remove water included in the aqueous solution.

10. The method for continuous recovery of (meth)acrylic acid according to claim 9 , wherein the hydrophobic extraction solvent is at least one selected from the group consisting of benzene, toluene, xylene, n-heptane, cycloheptane, cycloheptene, 1-heptene, ethyl-benzene, methyl-cyclohexane, n-butyl acetate, isobutyl acetate, isobutyl acrylate, n-propyl acetate, isopropyl acetate, methyl isobutyl ketone, 2-methyl-1-heptene, 6-methyl-1-heptene, 4-methyl-1-heptene, 2-ethyl-1-hexene, ethylcyclopentane, 2-methyl-1-hexene, 2,3-dimethylpentane, 5-methyl-1-hexene, and isopropyl-butyl-ether.

11. The method for continuous recovery of (meth)acrylic acid according to claim 9 , wherein the (meth)acrylic acid extract is obtained from the upper part of the (meth)acrylic acid extraction tower ( 200 ) and fed to the water separation tower ( 300 ), and
at least a part of the lower discharged liquid of the (meth)acrylic acid extraction tower ( 200 ) is fed to the upper end of the (meth)acrylic acid absorption tower ( 100 ) and used as an absorption solvent of (meth)acrylic acid.

12. The method for continuous recovery of (meth)acrylic acid according to claim 11 , wherein the lower discharged liquid of the (meth)acrylic acid extraction tower ( 200 ) includes (meth)acrylic acid at a concentration of 5 wt % or less.

13. The method for continuous recovery of (meth)acrylic acid according to claim 11 , wherein the upper end of the (meth)acrylic acid absorption tower ( 100 ) to which at least a part of the lower discharged liquid of the (meth)acrylic acid absorption tower ( 200 ) is fed is at least one point corresponding to a height of 70% or more from the lowest part of the absorption tower.

14. The method for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the distillation in the water separation tower ( 300 ) is conducted in the presence of a hydrophobic azeotropic solvent.

15. The method for continuous recovery of (meth)acrylic acid according to claim 14 , wherein the hydrophobic azeotropic solvent is at least one selected from the group consisting of benzene, toluene, xylene, n-heptane, cycloheptane, cycloheptene, 1-heptene, ethyl-benzene, methyl-cyclohexane, n-butyl acetate, isobutyl acetate, isobutyl acrylate, n-propyl acetate, isopropyl acetate, methyl isobutyl ketone, 2-methyl-1-heptene, 6-methyl-1-heptene, 4-methyl-1-heptene, 2-ethyl-1-hexene, ethylcyclopentane, 2-methyl-1-hexene, 2,3-dimethylpentane, 5-methyl-1-hexene, and isopropyl-butyl-ether.

16. The method for continuous recovery of (meth)acrylic acid according to claim 15 , wherein the hydrophobic azeotropic solvent includes the same compound as the hydrophobic extraction solvent in the (meth)acrylic acid extraction tower ( 200 ).

17. The method for continuous recovery of (meth)acrylic acid according to claim 14 , wherein discharged liquid including (meth)acrylic acid is recovered from the lower part of the water separation tower ( 300 ), and discharged liquid including a hydrophobic azeotropic solvent, water, and acetic acid is recovered from the upper part of the water separation tower ( 300 ), by distillation in the water separation tower ( 300 ).

18. The method for continuous recovery of (meth)acrylic acid according to claim 17 , wherein the upper discharged liquid of the water separation tower ( 300 ) is separated into an organic layer including the hydrophobic azeotropic solvent and an aqueous layer including acetic acid, at least a part of the organic layer is fed to the upper end of the water separation tower ( 300 ) as an azeotropic solvent, and at least a part of the aqueous layer is fed to the upper end of the (meth)acrylic acid absorption tower ( 100 ) as an absorption solvent.

Assignees

• Lg Chemical Ltd

Inventors

• Baek Se-Won
• Song Jong-Hun
• Yoo Sul-Hee

Classifications

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/44 Primary

  by distillation · CPC title

• C07C51/43

  by change of the physical state, e.g. crystallisation · CPC title

• B01D2257/70

  Organic compounds not provided for in groups B01D2257/00 - B01D2257/602 · CPC title

• B01D11/043

  with stationary contacting elements, sieve plates or loose contacting elements · CPC title