Energy store and method of charging or discharging an energy store

Patent metadata

Field	Value
Publication number	US-9515354-B2
Application number	US-201214128597-A
Country	US
Kind code	B2
Filing date	Jun 13, 2012
Priority date	Jun 27, 2011
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

An energy store is provided having a first electrode, a second electrode, an electrolyte in between, a first redox pair having a first oxidation reactant and a first oxidation product, and a housing, wherein a fluidic redox pair is present in the housing and comprises a fluidic oxidation reactant and a fluidic oxidation product, wherein during the discharge of the energy store, the fluidic oxidation product is reduced, and wherein during the charging of the energy store, the fluidic oxidation reactant is oxidized, wherein the fluidic redox pair in the housing is gaseous, and a pump or a compressor is adapted such that the fluidic redox pair within the housing is held at a pressure which is above the ambient pressure outside the housing. A method for charging or discharging an energy store is also provided.

First claim

The invention claimed is:

1. A method for charging or discharging an energy store having a first electrode, which, by donating electrons to a component of a process fluid, can produce anions from said component or, by accepting electrons from anions, can consume said anions by neutralization of the charge thereof and release to the process fluid, a second electrode, which, by releasing electrons, can produce anions or, by accepting electrons, can consume anions, an electrolyte, which is arranged between the first electrode and the second electrode and conducts anions, and a first redox pair, which comprises a first oxidation reactant and a first oxidation product, in which the first oxidation product is reduced in order to charge the energy store, and the first oxidation reactant is oxidized in order to discharge the energy store, wherein
use is made of a fluidic redox pair which comprises a fluidic oxidation reactant and a fluidic oxidation product and is in contact with the first redox pair and the second electrode,
during the discharge of the energy store, the fluidic oxidation product is reduced to the fluidic oxidation reactant at the first oxidation reactant, producing the first oxidation product in the process, and the fluidic oxidation reactant is oxidized to the fluidic oxidation product at the second electrode by means of the anions, donating electrons to the second electrode in the process, and
during the charging of the energy store, the fluidic oxidation reactant is oxidized to the fluidic oxidation product at the first oxidation product, producing the first oxidation reactant in the process, and the fluidic oxidation product is reduced to the fluidic oxidation reactant at the second electrode, wherein anions are generated at the second electrode by accepting electrons from the second electrode,
wherein the fluidic redox pair is gaseous during the oxidation and reduction, and
wherein a pressure above the ambient pressure of the medium surrounding the energy store is maintained in the fluidic redox pair.

2. The method as claimed in claim 1 , wherein the first redox pair comprises a metal and the oxide thereof or two different oxidation stages of a metal, and the fluidic redox pair comprises steam as an oxidation product.

3. The method as claimed in claim 1 , wherein the fluidic redox pair is passed along the first redox pair.

4. The method as claimed in claim 3 , wherein the fluidic redox pair is circulated in a circuit and, as it circulates, is passed along the first redox pair.

5. The method as claimed in claim 3 , wherein the oxidation product and/or the oxidation reactant of the fluidic redox pair is/are liquid and is/are evaporated before it/they is/are passed to the first redox pair.

6. The method as claimed in claim 5 , wherein the energy store is held at a high temperature, and the energy required for evaporating the oxidation product and/or the oxidation reactant of the fluidic redox pair is obtained from waste heat of the process fluid.

7. The method as claimed in claim 6 , wherein the process fluid fed to the energy store is heated before being fed to the energy store, wherein the heating is accomplished by means of waste heat contained in the process fluid after discharge from the energy store, and wherein the energy required for evaporating the oxidation product and/or the oxidation reactant of the fluidic redox pair is obtained from residual heat still contained in the discharged process fluid after the heating of the process fluid fed to the energy store.

8. The method as claimed in claim 5 , wherein the oxidation product and/or the oxidation reactant of the fluidic redox pair is/are condensed after it/they has/have been passed along the first redox pair.

9. An energy store comprising:
a first electrode, which is arranged in such a way that a process fluid can be guided along it and which comprises a material which, by donating electrons to a component of the process fluid, can produce anions from said component or, by accepting electrons from anions, can consume said anions by neutralization of the charge thereof and release to the process fluid;
a second electrode comprising a material which, by releasing electrons, can produce anions or, by accepting electrons, can consume anions;
an electrolyte, which is arranged between the first electrode and the second electrode and conducts anions;
a first redox pair, which comprises a first oxidation reactant and a first oxidation product; and
a housing, which is sealed against the entry of the medium surrounding the housing but allows the supply of process fluid to the first electrode, wherein
a fluidic redox pair is present in the interior of the housing between the second electrode, on the one hand, and the first redox pair, on the other hand, and comprises a fluidic oxidation reactant and a fluidic oxidation product, and in which
during the discharge of the energy store, the fluidic oxidation product is reduced to the fluidic oxidation reactant at the first oxidation reactant, producing the first oxidation product in the process, and the fluidic oxidation reactant is oxidized to the fluidic oxidation product at the second electrode by means of the anions, donating electrons to the second electrode in the process, and
during the charging of the energy store, the fluidic oxidation reactant is oxidized to the fluidic oxidation product at the first oxidation product, producing the first oxidation reactant in the process, and the fluidic oxidation product is reduced to the fluidic oxidation reactant at the second electrode, wherein anions are generated at the second electrode by accepting electrons from the second electrode,
wherein the fluidic redox pair in the housing is gaseous, and
further comprising a pump or a compressor, adapted such that the fluidic redox pair within the housing is held at a pressure which is above the ambient pressure outside the housing.

10. The energy store as claimed in claim 9 , wherein the housing has at least one feed line for feeding in the fluidic redox pair.

11. The energy store as claimed in claim 9 , further comprising an evaporator, which converts the fluidic redox pair from a liquid state to the gaseous state and which has a steam outlet connected via the feed line to the housing.

12. The energy store as claimed in claim 11 , further comprising a high temperature of the energy store and a heat exchanger, through which the liquid oxidation product and/or the liquid oxidation reactant of the fluidic redox pair flow/flows and to which process fluid that has emerged from the energy store is fed by means of a process fluid branch line in order to transfer waste heat to the liquid oxidation product and/or the liquid oxidation reactant.

Assignees

• Hanebuth Marc
• Kosse Sylvio
• Lenk Uwe
• Siemens Ag

Inventors

• Hanebuth Marc
• Kosse Sylvio
• Lenk Uwe

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M10/44 Primary

  Methods for charging or discharging (circuits for charging H02J7/00) · CPC title

• H01M8/04014 Primary

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title

• Y02E60/528

  Cross-Sectional Technologies · mapped topic