Discharge ionization current detector and method for aging treatment of the same

Patent metadata

Field	Value
Publication number	US-9513257-B2
Application number	US-201214382600-A
Country	US
Kind code	B2
Filing date	Mar 15, 2012
Priority date	Mar 15, 2012
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

An aging treatment is performed by using cleaning gas obtained by mixing inert gas, as an impurity, to plasma gas. Plasma generation by dielectric-barrier discharge is performed until a predetermined period of time has elapsed by applying high AC voltage to an electrode while supplying the cleaning gas to a dielectric tube from a gas inlet.

First claim

What is claimed is:

1. A method for aging treatment of a discharge ionization current detector including: a plasma generation section that is configured of a dielectric tube and a plurality of electrodes attached on an outer circumference of the dielectric tube, the plasma generation section continuously generating dielectric-barrier discharge inside the dielectric tube by applying high AC voltage to the electrodes while causing plasma gas to flow through the dielectric tube; a sample ionization section that is connected to a downstream end of the dielectric tube and that ionizes components in sample gas by light at a time of discharge generation at the plasma generation section; and an ion detection section that detects a sample component ionized by the sample ionization section, the method comprising:
supplying, as cleaning gas, mixed gas obtained by mixing inert gas with greater atomic weight than the plasma gas in the plasma gas, to the dielectric tube; and
continuously generating the dielectric-barrier discharge over a predetermined period of time by the plasma generation section while supplying the cleaning gas.

2. The method for aging treatment according to claim 1 , wherein the inert gas is gas that has no reactivity to a sample component.

3. The method for aging treatment according to claim 1 , wherein the plasma gas is helium, and the inert gas is nitrogen or argon.

4. The method for aging treatment according to claim 1 , wherein a proportion of the inert gas in the cleaning gas is smaller than a proportion of the plasma gas.

5. The method for aging treatment according to claim 2 , wherein the plasma gas is helium, and the inert gas is nitrogen or argon.

6. The method for aging treatment according to claim 2 , wherein a proportion of the inert gas in the cleaning gas is smaller than a proportion of the plasma gas.

7. The method for aging treatment according to claim 3 , wherein a proportion of the inert gas in the cleaning gas is smaller than a proportion of the plasma gas.

8. A discharge ionization current detector comprising:
a plasma generation section that is configured of a dielectric tube and a plurality of electrodes attached on an outer circumference of the dielectric tube, the plasma generation section continuously generating dielectric-barrier discharge inside the dielectric tube by applying high AC voltage to the electrodes while causing plasma gas to flow through the dielectric tube;
a sample ionization section that is connected to a downstream end of the dielectric tube and that ionizes components in sample gas by light at a time of discharge generation at the plasma generation section;
an ion detection section that detects a sample component ionized by the sample ionization section;
a plasma gas supply section for supplying the plasma gas;
a cleaning gas supply section for supplying, as cleaning gas, mixed gas obtained by mixing inert gas with greater atomic weight than the plasma gas in the plasma gas; and
a supply gas switching mechanism that connects the plasma gas supply section or the cleaning gas supply section to the dielectric tube and switches between gases.

9. The discharge ionization current detector according to claim 8 , wherein the inert gas is gas that has no reactivity to a sample component.

10. The discharge ionization current detector according to claim 8 , wherein the plasma gas is helium, and the inert gas is nitrogen or argon.

11. The discharge ionization current detector according to claim 8 , wherein a proportion of the inert gas in the cleaning gas is smaller than a proportion of the plasma gas.

Assignees

• Horiike Shigeyoshi
• Shinada Kei
• Nishimoto Takahiro
• Shimadzu Corp

Inventors

• Horiike Shigeyoshi
• Shinada Kei
• Nishimoto Takahiro

Classifications

• G01N27/70 Primary

  and measuring current or voltage · CPC title

• G01N30/64

  Electrical detectors · CPC title

• G01N27/68 Primary

  using electric discharge to ionise a gas · CPC title

• G01N2030/647

  surface ionisation · CPC title