Actinic-radiation-curable resin composition, primer containing the same, and shaped article

Patent metadata

Field	Value
Publication number	US-9512330-B2
Application number	US-201414760013-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jul 2, 2013
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

Provided are an actinic-radiation-curable resin composition that has high storage stability and that combines high levels of ease of application and adhesion to various substrates and high levels of coating appearance and heat resistance after curing, an actinic-radiation-curable primer for metallization that contains such an actinic-radiation-curable resin composition, and a shaped article including an undercoat layer for metallization that has good adhesion to various substrates. Specifically, an actinic-radiation-curable resin composition is provided that contains an oil-modified alkyd resin and a (meth)acryloyl-containing compound. The oil-modified alkyd resin is prepared using two or more oils having iodine values of 100 or more and has an oil length of 30 to 60, a mass average molecular weight of 200,000 to 1,000,000, and a molecular weight distribution (Mw/Mn) of 50 or more. Also provided is an actinic-radiation-curable primer for metallization that contains the actinic-radiation-curable resin composition.

First claim

The invention claimed is:

1. An actinic-radiation-curable resin composition comprising an oil-modified alkyd resin (A) and a compound (B) having two or more (meth)acryloyl groups in a molecule thereof,
the oil-modified alkyd resin (A) being prepared using two or more oils (a1) having iodine values of 100 or more, the oil-modified alkyd resin (A) having an oil length of 30 to 60, a mass average molecular weight of 200,000 to 1,000,000, and a molecular weight distribution (Mw/Mn) of 50 or more,
the oil-modified alkyd resin (A) and the (meth)acryloyl-containing compound (B) being present in a mass ratio ((A)/(B)) of 20/80 to 80/20.

2. The actinic-radiation-curable resin composition according to claim 1 , wherein the oils (a1) having an iodine value of 100 or more are selected from the group consisting of linseed oil, soybean oil, safflower oil, and tall oil.

3. The actinic-radiation-curable resin composition according to claim 1 , wherein the oil-modified alkyd resin (A) is prepared further using a branched alkane polyol (a2) having three or more hydroxyl groups in a molecule thereof and a polybasic acid (a3) having a cyclic unsaturated group in a molecule thereof.

4. The actinic-radiation-curable resin composition according to claim 1 , wherein the (meth)acryloyl-containing compound (B) is at least one compound selected from the group consisting of (meth)acrylate monomers, urethane (meth)acrylates, epoxy (meth)acrylates, polyester (meth)acrylates, and acrylic acrylates.

5. The actinic-radiation-curable resin composition according to claim 1 , further comprising an amino resin.

6. The actinic-radiation-curable resin composition according to claim 5 , wherein the amino resin is present in an amount of 5 to 20 parts by mass per 100 total parts by mass of the oil-modified alkyd resin (A) and the (meth)acryloyl-containing compound (B).

7. The actinic-radiation-curable resin composition according to claim 1 , further comprising a photoinitiator (C).

8. An actinic-radiation-curable primer for metallization comprising the actinic-radiation-curable resin composition according to claim 1 .

9. A shaped article comprising an undercoat layer comprising the primer according to claim 8 .

Assignees

• Dainippon Ink & Chemicals

Inventors

• Umino Akio
• Uno Seiichi

Classifications

• C08F222/104

  of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate · CPC title

• C08F220/343

  in the form of urethane links · CPC title

• C08F222/105

  of pentaalcohols · CPC title

• C08F222/103

  of trialcohols, e.g. trimethylolpropane tri(meth)acrylate · CPC title

• C08F220/283

  and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate · CPC title