Radiation curable liquid composition for low gloss coatings

Patent metadata

Field	Value
Publication number	US-9512322-B2
Application number	US-201113578040-A
Country	US
Kind code	B2
Filing date	Feb 10, 2011
Priority date	Feb 11, 2010
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

A radiation curable liquid coating composition comprising 1 to 90 wt % of at least one multifunctional (meth)acrylated oligomer; 10 to 80 wt % of at least one C 8 to C 20 monofunctional aliphatic alkyl (meth)acrylate; 0 to 40 wt % of at least one monomeric reactive diluent wherein (a)+(b)+(c)=100%; and additionally comprising 0.1 to 15 wt % of matting agent by weight of the coating composition.

First claim

The invention claimed is:

1. A radiation curable liquid coating composition comprising:
(a) 10 to 66 wt % of at least one multifunctional (meth)acrylated oligomer selected from the group consisting of polyester (meth)acrylate, urethane (meth)acrylate, epoxy (meth)acrylate, polyether (meth)acrylates, amine modified polyether(meth)acrylates, acrylic (meth)acrylates and mixtures thereof;
(b) 10 to 60 wt % of at least one C 8 to C 20 monofunctional aliphatic alkyl (meth)acrylate;
(c) 5 to 40 wt % of at least one monomeric reactive diluent not comprising (a) or (b);
wherein (a)+(b)+(c)=100%;
the coating composition additionally comprising 0.1 to 15 wt % of matting agent by weight of the coating composition.

2. A coating composition according to claim 1 wherein the coating composition is UV radiation curable.

3. A coating composition according to claim 1 additionally comprising <5 wt % of solvent.

4. A coating composition according to claim 1 wherein the composition has a viscosity ≦1000 mPa·s.

5. A coating composition according to claim 1 wherein the (meth)acrylated oligomer (a) has a Mn≧300 g/mol.

6. A coating composition according to claim 1 wherein the (meth)acrylated oligomer (a) is present in an amount from 5 to 80% by weight of (a)+(b)+(c).

7. A coating composition according to claim 1 wherein the alkyl (meth)acrylated material (b) is branched or linear.

8. A coating composition according to claim 1 wherein the alkyl (meth)acrylated material (b) has a Mn≦450 g/mol.

9. A coating composition according to claim 1 wherein the alkyl (meth)acrylated material (b) is selected from the group consisting of octyl (meth)acrylate, decyl (meth)acrylate, lauryl (meth)acrylate, stearyl (meth)acrylate and mixtures thereof.

10. A coating composition according to claim 1 wherein the alkyl (meth)acrylated material (b) is present in an amount from 15 to 70% by weight of (a)+(b)+(c).

11. A coating composition according to claim 1 wherein the reactive diluent (c) is selected from the group consisting of trimethylolpropane tri(meth)acrylate (TMPTA), pentaerythritol acrylate (PETA), 1,6-hexane diol diacrylate (HDDA), neopentyl glycol di(meth)acrylate (NPGDA), glycerol propoxylate triacrylate (GPTA), ethoxylated trimethylolpropane tri(meth)acrylate (TMPTA3EO, TMPTA6EO), and mixtures thereof.

12. A coating composition according to claim 1 wherein the reactive diluent (c) is present in an amount from 1 to 40% by weight of (a)+(b)+(c).

13. A coating composition according to claim 1 wherein the matting agent is selected from the group consisting of silica, diatomaceous earth, heavy metal soaps, talcum, chalk and mixtures thereof.

14. A coated substrate comprising:
a substrate which is at least one selected from the group consisting of wood, board, metal, stone, concrete, cloth, leather, paper, plastic or foam, and
a matt coating on the substrate, wherein the matt coating is comprised of a radiation curable liquid coating composition comprised of:
(a) 10 to 66 wt % of at least one multifunctional (meth)acrylated oligomer selected from the group consisting of polyester (meth)acrylate, urethane (meth)acrylate, epoxy (meth)acrylate, polyether (meth)acrylates, amine modified polyether(meth)acrylates, acrylic (meth)acrylates and mixtures thereof;
(b) 10 to 60 wt % of at least one C 8 to C 20 monofunctional aliphatic alkyl (meth)acrylate;
(c) 5 to 40 wt % of at least one monomeric reactive diluent not comprising (a) or (b);
wherein (a)+(b)+(c)=100%; and wherein

the coating composition additionally comprises 0.1 to 15 wt % of a matting agent by weight of the coating composition.

15. The coated substrate according to claim 14 , wherein the matt coating has a gloss measurement of ≦15 at 60° and ≦80 at 85° at a cured film thickness of 12 μm measured using BYK Gardner micro-TRI-gloss 20-60-85 glossmeter in accordance with DIN-67530.

16. A method of coating a substrate comprising the steps of:
(a) applying the coating composition according to claim 1 onto a surface of the substrate to form a coating, followed by
(b) radiation curing the coating to yield a matt coating having a gloss measurement of ≦15 at 60° and ≦80 at 85° at a cured film thickness of 12 μm measured using BYK Gardner micro-TRI-gloss 20-60-85 glossmeter in accordance with DIN-67530.

Assignees

• Bückmann Alfred Jean Paul
• Visser Danny
• Van Den Biggelaar Johannes Jacobus Julius
• Dsm Ip Assets Bv

Inventors

• Bückmann Alfred Jean Paul
• Visser Danny
• Van Den Biggelaar Johannes Jacobus Julius

Classifications

• C09D175/14

  Polyurethanes having carbon-to-carbon unsaturated bonds · CPC title

• C09D4/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title

• C08L33/04

  Homopolymers or copolymers of esters {(C08L43/04 takes precedence)} · CPC title

• C08L75/16

  having terminal carbon-to-carbon unsaturated bonds · CPC title

• C09D175/16

  having terminal carbon-to-carbon unsaturated bonds · CPC title